TY  - JOUR
AU  - Pešić, Jelena
AU  - Šolajić, Andrijana
AU  - Mitrić, Jelena
AU  - Gilić, Martina
AU  - Pešić, Ivan
AU  - Paunović, Novica
AU  - Romčević, Nebojša
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5139
AB  - The rich chemistries and unique morphologies of titanium carbide MXenes, made them strong candidates for many applications like sensors and electronic device materials. During the synthesis procedure, chemical etching, oxidation occurs and residual materials, like titanium-dioxide nanocrystals and nanosheets are often present in resulting material. As titanium-carbide MXenes are suggested to be used as additive in organic polymer matrices for production of nanocomposites, it is essential to consider the presence of the oxides and other residuals together with MXene flakes in synthesis results, and consequently in produced nanocomposite. In this study we present structural and optical characterization of such polymer nanocomposite titanium carbide/PMMA (Polymethyl methacrylate) consisting of Ti3C2, TiC2 MXenes and TiC, and TiO2 residues of synthesis in PMMA matrix, as a multicomponent nanocomposite. Using XRD, infra-red and Raman spectroscopy, followed by comparative study on the vibrational properties using density functional theory calculations, we characterize this nanocomposite. Further, the SEM measurements are performed, demonstrating the produced titanium-carbide-based flakes in nanocomposite are well defined and separated to nanosized grains, allowing us to use Maxwell–Garnet model to analyse infrared spectrum. This enables us to determine the presence of the optical modification of polymer matrices corresponding to a volume fraction of 0.25.
PB  - Springer
T2  - Optical and Quantum Electronics
T1  - Structural and optical characterization of titanium–carbide and polymethyl methacrylate based nanocomposite
IS  - 6
SP  - 354
VL  - 54
DO  - 10.1007/s11082-022-03674-z
ER  - 

@article{
author = "Pešić, Jelena and Šolajić, Andrijana and Mitrić, Jelena and Gilić, Martina and Pešić, Ivan and Paunović, Novica and Romčević, Nebojša",
year = "2022",
abstract = "The rich chemistries and unique morphologies of titanium carbide MXenes, made them strong candidates for many applications like sensors and electronic device materials. During the synthesis procedure, chemical etching, oxidation occurs and residual materials, like titanium-dioxide nanocrystals and nanosheets are often present in resulting material. As titanium-carbide MXenes are suggested to be used as additive in organic polymer matrices for production of nanocomposites, it is essential to consider the presence of the oxides and other residuals together with MXene flakes in synthesis results, and consequently in produced nanocomposite. In this study we present structural and optical characterization of such polymer nanocomposite titanium carbide/PMMA (Polymethyl methacrylate) consisting of Ti3C2, TiC2 MXenes and TiC, and TiO2 residues of synthesis in PMMA matrix, as a multicomponent nanocomposite. Using XRD, infra-red and Raman spectroscopy, followed by comparative study on the vibrational properties using density functional theory calculations, we characterize this nanocomposite. Further, the SEM measurements are performed, demonstrating the produced titanium-carbide-based flakes in nanocomposite are well defined and separated to nanosized grains, allowing us to use Maxwell–Garnet model to analyse infrared spectrum. This enables us to determine the presence of the optical modification of polymer matrices corresponding to a volume fraction of 0.25.",
publisher = "Springer",
journal = "Optical and Quantum Electronics",
title = "Structural and optical characterization of titanium–carbide and polymethyl methacrylate based nanocomposite",
number = "6",
pages = "354",
volume = "54",
doi = "10.1007/s11082-022-03674-z"
}

Pešić, J., Šolajić, A., Mitrić, J., Gilić, M., Pešić, I., Paunović, N.,& Romčević, N.. (2022). Structural and optical characterization of titanium–carbide and polymethyl methacrylate based nanocomposite. in Optical and Quantum Electronics
Springer., 54(6), 354.
https://doi.org/10.1007/s11082-022-03674-z

Pešić J, Šolajić A, Mitrić J, Gilić M, Pešić I, Paunović N, Romčević N. Structural and optical characterization of titanium–carbide and polymethyl methacrylate based nanocomposite. in Optical and Quantum Electronics. 2022;54(6):354.
doi:10.1007/s11082-022-03674-z .

Pešić, Jelena, Šolajić, Andrijana, Mitrić, Jelena, Gilić, Martina, Pešić, Ivan, Paunović, Novica, Romčević, Nebojša, "Structural and optical characterization of titanium–carbide and polymethyl methacrylate based nanocomposite" in Optical and Quantum Electronics, 54, no. 6 (2022):354,
https://doi.org/10.1007/s11082-022-03674-z . .