TY  - JOUR
AU  - Živančev, Nevena V.
AU  - Kovačević, Srđan R.
AU  - Radović, Tanja T.
AU  - Radišić, Marina M.
AU  - Dimkić, Milan A.
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5908
AB  - The objective of the paper was to use transport model of selected pesticides (carbendazim, acetamiprid and imidacloprid) in determination of linear sorption coefficients in alluvial aquifer. For constructing transport model, results of a field experiment at the location of Kovin-Dubovac drainage system in Serbia were used in order to set hydraulic parameters (hydraulic conductivity, aquifer layer thickness of the observed area, effective porosity etc.). The field experiment consisted of a tracer test during which concentrations of non-reactive tracer (Cl−) and selected pesticides (carbendazim, acetamiprid and imidacloprid) were monitored. For better characterization of hydraulic parameters, a pumping test was conducted at the observed well and results were used in designing transport model. Simulation model was constructed with Lizza groundwater flow software and W.O.D.A. (Well Outline and Design Aid) solver. Obtained linear sorption coefficients in the sand and gravel water-bearing layer were 0.14 mL g−1 for carbendazim and 0.11 mL g−1 for acetamiprid and imidacloprid. Results from this study are a unique insight into mobility of observed pesticides in the alluvial groundwater in natural conditions and can be used in contamination assessment for drinking water wells.
PB  - Springer Verlag
T2  - Environmental Science and Pollution Research
T1  - Mobility and sorption assessment of selected pesticides in alluvial aquifer
EP  - 28736
IS  - 28
SP  - 28725
VL  - 26
DO  - 10.1007/s11356-019-06055-4
ER  - 

@article{
author = "Živančev, Nevena V. and Kovačević, Srđan R. and Radović, Tanja T. and Radišić, Marina M. and Dimkić, Milan A.",
year = "2019",
abstract = "The objective of the paper was to use transport model of selected pesticides (carbendazim, acetamiprid and imidacloprid) in determination of linear sorption coefficients in alluvial aquifer. For constructing transport model, results of a field experiment at the location of Kovin-Dubovac drainage system in Serbia were used in order to set hydraulic parameters (hydraulic conductivity, aquifer layer thickness of the observed area, effective porosity etc.). The field experiment consisted of a tracer test during which concentrations of non-reactive tracer (Cl−) and selected pesticides (carbendazim, acetamiprid and imidacloprid) were monitored. For better characterization of hydraulic parameters, a pumping test was conducted at the observed well and results were used in designing transport model. Simulation model was constructed with Lizza groundwater flow software and W.O.D.A. (Well Outline and Design Aid) solver. Obtained linear sorption coefficients in the sand and gravel water-bearing layer were 0.14 mL g−1 for carbendazim and 0.11 mL g−1 for acetamiprid and imidacloprid. Results from this study are a unique insight into mobility of observed pesticides in the alluvial groundwater in natural conditions and can be used in contamination assessment for drinking water wells.",
publisher = "Springer Verlag",
journal = "Environmental Science and Pollution Research",
title = "Mobility and sorption assessment of selected pesticides in alluvial aquifer",
pages = "28736-28725",
number = "28",
volume = "26",
doi = "10.1007/s11356-019-06055-4"
}

Živančev, N. V., Kovačević, S. R., Radović, T. T., Radišić, M. M.,& Dimkić, M. A.. (2019). Mobility and sorption assessment of selected pesticides in alluvial aquifer. in Environmental Science and Pollution Research
Springer Verlag., 26(28), 28725-28736.
https://doi.org/10.1007/s11356-019-06055-4

Živančev NV, Kovačević SR, Radović TT, Radišić MM, Dimkić MA. Mobility and sorption assessment of selected pesticides in alluvial aquifer. in Environmental Science and Pollution Research. 2019;26(28):28725-28736.
doi:10.1007/s11356-019-06055-4 .

Živančev, Nevena V., Kovačević, Srđan R., Radović, Tanja T., Radišić, Marina M., Dimkić, Milan A., "Mobility and sorption assessment of selected pesticides in alluvial aquifer" in Environmental Science and Pollution Research, 26, no. 28 (2019):28725-28736,
https://doi.org/10.1007/s11356-019-06055-4 . .

TY  - JOUR
AU  - Radović, Tanja
AU  - Grujić, Svetlana
AU  - Kovacević, Srdan R.
AU  - Laušević, Mila
AU  - Dimkić, Milan
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3316
AB  - In the present work, the sorption ability of 17 pharmaceutical compounds, two metabolites, and 15 pesticides (34 target compounds in total) onto four different river sediments was investigated separately. Selected compounds present the most frequently prescribed pharmaceuticals in human and animal medicine and the most frequently used pesticides in agriculture. Their presence into the surface, ground, and waste waters was confirmed into the numerous papers in literature, as well as their presence into the river sediments (for some of them). However, investigations of their sorption onto the river sediments, as major natural protection from potential pollution of ground water by them is missing. Sorption in this study was investigated onto river sediments taken from rivers in the Republic of Serbia, where only less than 10 % of total generated waste water passes through mainly basic treatment processes. Experiments were based on batch equilibrium procedures and obtained solutions were analyzed by previously developed and validated sensitive high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) analytical methods. All results were modeled by Freundlich isotherms. Obtained results have shown that Kf coefficient values are in correlation with organic carbon content. Kd sorption coefficient values were relatively low and ranged in wide ranges for almost all compounds and sediments. That implicates on the conclusion that capacities of the investigated sorbents are not large for those compounds.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental Science and Pollution Research
T1  - Sorption of selected pharmaceuticals and pesticides on different river sediments
EP  - 25244
IS  - 24
SP  - 25232
VL  - 23
DO  - 10.1007/s11356-016-7752-4
ER  - 

@article{
author = "Radović, Tanja and Grujić, Svetlana and Kovacević, Srdan R. and Laušević, Mila and Dimkić, Milan",
year = "2016",
abstract = "In the present work, the sorption ability of 17 pharmaceutical compounds, two metabolites, and 15 pesticides (34 target compounds in total) onto four different river sediments was investigated separately. Selected compounds present the most frequently prescribed pharmaceuticals in human and animal medicine and the most frequently used pesticides in agriculture. Their presence into the surface, ground, and waste waters was confirmed into the numerous papers in literature, as well as their presence into the river sediments (for some of them). However, investigations of their sorption onto the river sediments, as major natural protection from potential pollution of ground water by them is missing. Sorption in this study was investigated onto river sediments taken from rivers in the Republic of Serbia, where only less than 10 % of total generated waste water passes through mainly basic treatment processes. Experiments were based on batch equilibrium procedures and obtained solutions were analyzed by previously developed and validated sensitive high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) analytical methods. All results were modeled by Freundlich isotherms. Obtained results have shown that Kf coefficient values are in correlation with organic carbon content. Kd sorption coefficient values were relatively low and ranged in wide ranges for almost all compounds and sediments. That implicates on the conclusion that capacities of the investigated sorbents are not large for those compounds.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental Science and Pollution Research",
title = "Sorption of selected pharmaceuticals and pesticides on different river sediments",
pages = "25244-25232",
number = "24",
volume = "23",
doi = "10.1007/s11356-016-7752-4"
}

Radović, T., Grujić, S., Kovacević, S. R., Laušević, M.,& Dimkić, M.. (2016). Sorption of selected pharmaceuticals and pesticides on different river sediments. in Environmental Science and Pollution Research
Springer Heidelberg, Heidelberg., 23(24), 25232-25244.
https://doi.org/10.1007/s11356-016-7752-4

Radović T, Grujić S, Kovacević SR, Laušević M, Dimkić M. Sorption of selected pharmaceuticals and pesticides on different river sediments. in Environmental Science and Pollution Research. 2016;23(24):25232-25244.
doi:10.1007/s11356-016-7752-4 .

Radović, Tanja, Grujić, Svetlana, Kovacević, Srdan R., Laušević, Mila, Dimkić, Milan, "Sorption of selected pharmaceuticals and pesticides on different river sediments" in Environmental Science and Pollution Research, 23, no. 24 (2016):25232-25244,
https://doi.org/10.1007/s11356-016-7752-4 . .

TY  - CONF
AU  - Radišić, Marina
AU  - Jauković, Zorica
AU  - Kovačević, Srđan
AU  - Tolić, Ljiljana
AU  - Grujić, Svetlana
AU  - Dimkić, Milan
AU  - Laušević, Mila
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7255
AB  - Lekovi predstavljaju najznačajniju grupu novih zagađujućih supstanci koje se nalaze u prirodnim vodama [1]. Otpadne vode, poreklom iz domaćinstava, industrije i životinjskih farmi predstavljaju osnovne izvore zagađenja životne sredine. U prirodnim vodama, lekovi mogu biti prisutni u svojoj osnovnoj formi ili u formi metabolita. Koncentracije metabolita lekova koje su prisutne u životnoj sredini često su veće od koncentracija osnovnog leka. Metamizol je veoma popularan antipiretik i analgetik koji se koristi u mnogim zemljama preko 70 godina. Iako je, zbog sumnje da može da izazove agranulocitozu kod pacijenata, zabranjen u mnogim zemljama, u većini evropskih zemalja i dalje se koristi zbog svog analgetičkog dejstva. Posle apsorpcije metamizola u gastro-intestinalnom traktu, on potpuno hidrolizuje u 4-metil-aminoantipirin (4-MAA), koji u jetri metabolizuje u 4-aminoantipirin (4-AA), pa se dalje acetilizuje do 4-acetilaminoantipirina (4-AAA) i 4-formil-aminoantipirina (4-FAA) [2]. Krajnji metaboliti 4-AAA i 4-FAA su dosta stabilni u životnoj sredini i nađeni su u dosta visokim koncentracijama u otpadnim i prirodnim vodama [3]. U ovom radu je optimizovana, validirana i primenjena analitička metoda za određivanje metamizola i njegovih metabolita 4-AAA i 4-FAA u podzemnim i površinskim vodama.
PB  - Beograd : Srpsko hemijsko društvo = Serbian Chemical Society
C3  - Knjiga izvoda = Book of Abstracts / 7. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem = 7th Symposium Chemistry and Environmental Protection with International Participation, Palić, Srbija, 09-12. jun 2015
T1  - Određivanje metabolita metamizola u površinskoj i podzemnoj vodi
T1  - Determination of metamizole metabolites in surface water and groundwater
EP  - 242
SP  - 241
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7255
ER  - 

@conference{
author = "Radišić, Marina and Jauković, Zorica and Kovačević, Srđan and Tolić, Ljiljana and Grujić, Svetlana and Dimkić, Milan and Laušević, Mila",
year = "2015",
abstract = "Lekovi predstavljaju najznačajniju grupu novih zagađujućih supstanci koje se nalaze u prirodnim vodama [1]. Otpadne vode, poreklom iz domaćinstava, industrije i životinjskih farmi predstavljaju osnovne izvore zagađenja životne sredine. U prirodnim vodama, lekovi mogu biti prisutni u svojoj osnovnoj formi ili u formi metabolita. Koncentracije metabolita lekova koje su prisutne u životnoj sredini često su veće od koncentracija osnovnog leka. Metamizol je veoma popularan antipiretik i analgetik koji se koristi u mnogim zemljama preko 70 godina. Iako je, zbog sumnje da može da izazove agranulocitozu kod pacijenata, zabranjen u mnogim zemljama, u većini evropskih zemalja i dalje se koristi zbog svog analgetičkog dejstva. Posle apsorpcije metamizola u gastro-intestinalnom traktu, on potpuno hidrolizuje u 4-metil-aminoantipirin (4-MAA), koji u jetri metabolizuje u 4-aminoantipirin (4-AA), pa se dalje acetilizuje do 4-acetilaminoantipirina (4-AAA) i 4-formil-aminoantipirina (4-FAA) [2]. Krajnji metaboliti 4-AAA i 4-FAA su dosta stabilni u životnoj sredini i nađeni su u dosta visokim koncentracijama u otpadnim i prirodnim vodama [3]. U ovom radu je optimizovana, validirana i primenjena analitička metoda za određivanje metamizola i njegovih metabolita 4-AAA i 4-FAA u podzemnim i površinskim vodama.",
publisher = "Beograd : Srpsko hemijsko društvo = Serbian Chemical Society",
journal = "Knjiga izvoda = Book of Abstracts / 7. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem = 7th Symposium Chemistry and Environmental Protection with International Participation, Palić, Srbija, 09-12. jun 2015",
title = "Određivanje metabolita metamizola u površinskoj i podzemnoj vodi, Determination of metamizole metabolites in surface water and groundwater",
pages = "242-241",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7255"
}

Radišić, M., Jauković, Z., Kovačević, S., Tolić, L., Grujić, S., Dimkić, M.,& Laušević, M.. (2015). Određivanje metabolita metamizola u površinskoj i podzemnoj vodi. in Knjiga izvoda = Book of Abstracts / 7. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem = 7th Symposium Chemistry and Environmental Protection with International Participation, Palić, Srbija, 09-12. jun 2015
Beograd : Srpsko hemijsko društvo = Serbian Chemical Society., 241-242.
https://hdl.handle.net/21.15107/rcub_technorep_7255

Radišić M, Jauković Z, Kovačević S, Tolić L, Grujić S, Dimkić M, Laušević M. Određivanje metabolita metamizola u površinskoj i podzemnoj vodi. in Knjiga izvoda = Book of Abstracts / 7. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem = 7th Symposium Chemistry and Environmental Protection with International Participation, Palić, Srbija, 09-12. jun 2015. 2015;:241-242.
https://hdl.handle.net/21.15107/rcub_technorep_7255 .

Radišić, Marina, Jauković, Zorica, Kovačević, Srđan, Tolić, Ljiljana, Grujić, Svetlana, Dimkić, Milan, Laušević, Mila, "Određivanje metabolita metamizola u površinskoj i podzemnoj vodi" in Knjiga izvoda = Book of Abstracts / 7. simpozijum Hemija i zaštita životne sredine sa međunarodnim učešćem = 7th Symposium Chemistry and Environmental Protection with International Participation, Palić, Srbija, 09-12. jun 2015 (2015):241-242,
https://hdl.handle.net/21.15107/rcub_technorep_7255 .

TY  - JOUR
AU  - Radović, Tanja
AU  - Grujić, Svetlana
AU  - Petković, Anđelka
AU  - Dimkić, Milan
AU  - Laušević, Mila
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3024
AB  - The aim of this study was the development of analytical methods for the simultaneous determination of 25 selected pharmaceuticals, metabolites, and pesticides, belonging to the various chemical classes, in river sediments and their corresponding surface and ground water with the purpose of monitoring the contamination levels. The methods were based on the solid-phase extraction as the sample preparation method for water samples, and the ultrasonic solvent extraction for the sediment samples, followed by the liquid chromatography-tandem mass spectrometry. High recoveries were achieved for extraction from both water and sediment samples for the majority of analytes. Low limits of detection were achieved for all investigated compounds in the water sample (1-5 ng L-1) as well as in the sediment (1-3 ng g(-1)). Applicability of the developed methods was demonstrated by determination of pharmaceutical and pesticide residues in 30 surface water, 44 groundwater, and 5 sediment samples from the Danube River Basin in Serbia. Sixty percent of target compounds were detected in environmental samples. The most frequently detected analytes in river sediments were the pesticides dimethoate and atrazine, while carbamazepine and metamizole metabolites 4-AAA and 4-FAA were the most frequently found in water samples.
PB  - Springer, Dordrecht
T2  - Environmental Monitoring and Assessment
T1  - Determination of pharmaceuticals and pesticides in river sediments and corresponding surface and ground water in the Danube River and tributaries in Serbia
IS  - 1
VL  - 187
DO  - 10.1007/s10661-014-4092-z
ER  - 

@article{
author = "Radović, Tanja and Grujić, Svetlana and Petković, Anđelka and Dimkić, Milan and Laušević, Mila",
year = "2015",
abstract = "The aim of this study was the development of analytical methods for the simultaneous determination of 25 selected pharmaceuticals, metabolites, and pesticides, belonging to the various chemical classes, in river sediments and their corresponding surface and ground water with the purpose of monitoring the contamination levels. The methods were based on the solid-phase extraction as the sample preparation method for water samples, and the ultrasonic solvent extraction for the sediment samples, followed by the liquid chromatography-tandem mass spectrometry. High recoveries were achieved for extraction from both water and sediment samples for the majority of analytes. Low limits of detection were achieved for all investigated compounds in the water sample (1-5 ng L-1) as well as in the sediment (1-3 ng g(-1)). Applicability of the developed methods was demonstrated by determination of pharmaceutical and pesticide residues in 30 surface water, 44 groundwater, and 5 sediment samples from the Danube River Basin in Serbia. Sixty percent of target compounds were detected in environmental samples. The most frequently detected analytes in river sediments were the pesticides dimethoate and atrazine, while carbamazepine and metamizole metabolites 4-AAA and 4-FAA were the most frequently found in water samples.",
publisher = "Springer, Dordrecht",
journal = "Environmental Monitoring and Assessment",
title = "Determination of pharmaceuticals and pesticides in river sediments and corresponding surface and ground water in the Danube River and tributaries in Serbia",
number = "1",
volume = "187",
doi = "10.1007/s10661-014-4092-z"
}

Radović, T., Grujić, S., Petković, A., Dimkić, M.,& Laušević, M.. (2015). Determination of pharmaceuticals and pesticides in river sediments and corresponding surface and ground water in the Danube River and tributaries in Serbia. in Environmental Monitoring and Assessment
Springer, Dordrecht., 187(1).
https://doi.org/10.1007/s10661-014-4092-z

Radović T, Grujić S, Petković A, Dimkić M, Laušević M. Determination of pharmaceuticals and pesticides in river sediments and corresponding surface and ground water in the Danube River and tributaries in Serbia. in Environmental Monitoring and Assessment. 2015;187(1).
doi:10.1007/s10661-014-4092-z .

Radović, Tanja, Grujić, Svetlana, Petković, Anđelka, Dimkić, Milan, Laušević, Mila, "Determination of pharmaceuticals and pesticides in river sediments and corresponding surface and ground water in the Danube River and tributaries in Serbia" in Environmental Monitoring and Assessment, 187, no. 1 (2015),
https://doi.org/10.1007/s10661-014-4092-z . .

TY  - JOUR
AU  - Antić, Nikolina
AU  - Radišić, Marina
AU  - Radović, Tanja
AU  - Vasiljević, Tatjana
AU  - Grujić, Svetlana
AU  - Petković, Anđelka
AU  - Dimkić, Milan
AU  - Laušević, Mila
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3041
AB  - In this work, a total of 38 pesticides was monitored in the Danube River Basin in Serbia during ten sampling campaigns in 2009, 2010, and 2011. The quantification of analytes was performed using procedures based on solid-phase extraction (SPE) followed by LC-MS/MS or GC-MS. In general, low pesticide levels were found, except for the samples collected during May-June of 2010 and June of 2011. During this period, pesticide application is high and rainfall was described as extremely above normal or above normal, leading to very pronounced runoff and very high detected pesticide levels. At the sampling site Smederevo (the Danube River), high concentrations of terbuthylazine (200ngL(-1)) and metolachlor (150ngL(-1)) were found. In the Danube tributary Morava, high concentrations of carbendazim (269ngL(-1)), atrazine (188ngL(-1)), terbuthylazine (180ngL(-1)), and acetochlor (110ngL(-1)) were detected, while in the tributary Tisa only terbuthylazine was present at high levels (130ngL(-1)). In other sampling campaigns, pesticides were present at low concentrations. The most frequently found pesticide was carbendazim, probably due to slow degradation rate in environment.
PB  - Wiley, Hoboken
T2  - Clean-Soil Air Water
T1  - Pesticide Residues in the Danube River Basin in Serbia - a Survey during 2009-2011
EP  - 204
IS  - 2
SP  - 197
VL  - 43
DO  - 10.1002/clen.201200360
ER  - 

@article{
author = "Antić, Nikolina and Radišić, Marina and Radović, Tanja and Vasiljević, Tatjana and Grujić, Svetlana and Petković, Anđelka and Dimkić, Milan and Laušević, Mila",
year = "2015",
abstract = "In this work, a total of 38 pesticides was monitored in the Danube River Basin in Serbia during ten sampling campaigns in 2009, 2010, and 2011. The quantification of analytes was performed using procedures based on solid-phase extraction (SPE) followed by LC-MS/MS or GC-MS. In general, low pesticide levels were found, except for the samples collected during May-June of 2010 and June of 2011. During this period, pesticide application is high and rainfall was described as extremely above normal or above normal, leading to very pronounced runoff and very high detected pesticide levels. At the sampling site Smederevo (the Danube River), high concentrations of terbuthylazine (200ngL(-1)) and metolachlor (150ngL(-1)) were found. In the Danube tributary Morava, high concentrations of carbendazim (269ngL(-1)), atrazine (188ngL(-1)), terbuthylazine (180ngL(-1)), and acetochlor (110ngL(-1)) were detected, while in the tributary Tisa only terbuthylazine was present at high levels (130ngL(-1)). In other sampling campaigns, pesticides were present at low concentrations. The most frequently found pesticide was carbendazim, probably due to slow degradation rate in environment.",
publisher = "Wiley, Hoboken",
journal = "Clean-Soil Air Water",
title = "Pesticide Residues in the Danube River Basin in Serbia - a Survey during 2009-2011",
pages = "204-197",
number = "2",
volume = "43",
doi = "10.1002/clen.201200360"
}

Antić, N., Radišić, M., Radović, T., Vasiljević, T., Grujić, S., Petković, A., Dimkić, M.,& Laušević, M.. (2015). Pesticide Residues in the Danube River Basin in Serbia - a Survey during 2009-2011. in Clean-Soil Air Water
Wiley, Hoboken., 43(2), 197-204.
https://doi.org/10.1002/clen.201200360

Antić N, Radišić M, Radović T, Vasiljević T, Grujić S, Petković A, Dimkić M, Laušević M. Pesticide Residues in the Danube River Basin in Serbia - a Survey during 2009-2011. in Clean-Soil Air Water. 2015;43(2):197-204.
doi:10.1002/clen.201200360 .

Antić, Nikolina, Radišić, Marina, Radović, Tanja, Vasiljević, Tatjana, Grujić, Svetlana, Petković, Anđelka, Dimkić, Milan, Laušević, Mila, "Pesticide Residues in the Danube River Basin in Serbia - a Survey during 2009-2011" in Clean-Soil Air Water, 43, no. 2 (2015):197-204,
https://doi.org/10.1002/clen.201200360 . .