Slovene Research AgencySlovenian Research Agency - Slovenia [P2-1048]

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Slovene Research AgencySlovenian Research Agency - Slovenia [P2-1048]

Authors

Publications

Surface Analysis and Electrochemical Behavior of Aluminum Pretreated by Vinyltriethoxysilane Films in Mild NaCl Solution

Milosev, Ingrid; Jovanović, Z.; Bajat, Jelena; Jančić-Heinemann, Radmila; Mišković-Stanković, Vesna

(Electrochemical Soc Inc, Pennington, 2012)

TY  - JOUR
AU  - Milosev, Ingrid
AU  - Jovanović, Z.
AU  - Bajat, Jelena
AU  - Jančić-Heinemann, Radmila
AU  - Mišković-Stanković, Vesna
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2121
AB  - Electrochemical characteristics, composition and surface morphology of vinyltriethoxysilane (VTES) coatings on aluminum were investigated. The silane coatings were deposited chemically, by immersion in 2 and 5% VTES, and then cured at 100 degrees C during 10 or 30 min. Surface morphology of VTES films was analyzed by scanning electron microscopy, while the composition was investigated by X-ray photoelectron spectroscopy. The corrosion stability of silane coatings was determined by electrochemical impedance spectroscopy in 0.03% NaCl. The results obtained were compared with the standardized analysis in the salt spray chamber. The percentage of the corroded area was determined by optical microscopy coupled with image analysis. The influence of VTES concentration and curing time on the corrosion stability of silane films on aluminum was shown. The highest corrosion stability was obtained for silane films deposited from 5% VTES solution with 30 min curing, while the lowest stability was determined for silane films deposited from 2% VTES solution with 10 min curing. Surface analysis suggests that the coatings with the highest corrosion stability are related to the intensive siloxane bonding (Si-O-Si), which is favored by deposition from more concentrated VTES solution.
PB  - Electrochemical Soc Inc, Pennington
T2  - Journal of the Electrochemical Society
T1  - Surface Analysis and Electrochemical Behavior of Aluminum Pretreated by Vinyltriethoxysilane Films in Mild NaCl Solution
EP  - C311
IS  - 7
SP  - C303
VL  - 159
DO  - 10.1149/2.042207jes
ER  - 
@article{
author = "Milosev, Ingrid and Jovanović, Z. and Bajat, Jelena and Jančić-Heinemann, Radmila and Mišković-Stanković, Vesna",
year = "2012",
abstract = "Electrochemical characteristics, composition and surface morphology of vinyltriethoxysilane (VTES) coatings on aluminum were investigated. The silane coatings were deposited chemically, by immersion in 2 and 5% VTES, and then cured at 100 degrees C during 10 or 30 min. Surface morphology of VTES films was analyzed by scanning electron microscopy, while the composition was investigated by X-ray photoelectron spectroscopy. The corrosion stability of silane coatings was determined by electrochemical impedance spectroscopy in 0.03% NaCl. The results obtained were compared with the standardized analysis in the salt spray chamber. The percentage of the corroded area was determined by optical microscopy coupled with image analysis. The influence of VTES concentration and curing time on the corrosion stability of silane films on aluminum was shown. The highest corrosion stability was obtained for silane films deposited from 5% VTES solution with 30 min curing, while the lowest stability was determined for silane films deposited from 2% VTES solution with 10 min curing. Surface analysis suggests that the coatings with the highest corrosion stability are related to the intensive siloxane bonding (Si-O-Si), which is favored by deposition from more concentrated VTES solution.",
publisher = "Electrochemical Soc Inc, Pennington",
journal = "Journal of the Electrochemical Society",
title = "Surface Analysis and Electrochemical Behavior of Aluminum Pretreated by Vinyltriethoxysilane Films in Mild NaCl Solution",
pages = "C311-C303",
number = "7",
volume = "159",
doi = "10.1149/2.042207jes"
}
Milosev, I., Jovanović, Z., Bajat, J., Jančić-Heinemann, R.,& Mišković-Stanković, V.. (2012). Surface Analysis and Electrochemical Behavior of Aluminum Pretreated by Vinyltriethoxysilane Films in Mild NaCl Solution. in Journal of the Electrochemical Society
Electrochemical Soc Inc, Pennington., 159(7), C303-C311.
https://doi.org/10.1149/2.042207jes
Milosev I, Jovanović Z, Bajat J, Jančić-Heinemann R, Mišković-Stanković V. Surface Analysis and Electrochemical Behavior of Aluminum Pretreated by Vinyltriethoxysilane Films in Mild NaCl Solution. in Journal of the Electrochemical Society. 2012;159(7):C303-C311.
doi:10.1149/2.042207jes .
Milosev, Ingrid, Jovanović, Z., Bajat, Jelena, Jančić-Heinemann, Radmila, Mišković-Stanković, Vesna, "Surface Analysis and Electrochemical Behavior of Aluminum Pretreated by Vinyltriethoxysilane Films in Mild NaCl Solution" in Journal of the Electrochemical Society, 159, no. 7 (2012):C303-C311,
https://doi.org/10.1149/2.042207jes . .
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Corrosion protection of aluminium pretreated by vinyltriethoxysilane in sodium chloride solution

Bajat, Jelena; Milosev, Ingrid; Jovanović, Z.; Jančić-Heinemann, Radmila; Dimitrijević, M.; Mišković-Stanković, Vesna

(Pergamon-Elsevier Science Ltd, Oxford, 2010)

TY  - JOUR
AU  - Bajat, Jelena
AU  - Milosev, Ingrid
AU  - Jovanović, Z.
AU  - Jančić-Heinemann, Radmila
AU  - Dimitrijević, M.
AU  - Mišković-Stanković, Vesna
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1673
AB  - The corrosion protection of vinyltriethoxysilane (VTES) films on aluminium during exposure to 3% NaCl was investigated using electrochemical impedance spectroscopy (EIS), potential-time measurements and optical microscopy coupled with image analysis. Composition and thickness of films were analyzed using Auger electron spectroscopy (AES) combined with depth profiling. It was shown that films deposited from 5% solution were significantly thicker and exhibited lower porosity and better corrosion stability, as compared to films deposited from 2 vol.% solution. VTES films deposited from 5 vol.% solutions and cured for 30 min exhibited better protection properties than other investigated films.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Corrosion Science
T1  - Corrosion protection of aluminium pretreated by vinyltriethoxysilane in sodium chloride solution
EP  - 1069
IS  - 3
SP  - 1060
VL  - 52
DO  - 10.1016/j.corsci.2009.11.035
ER  - 
@article{
author = "Bajat, Jelena and Milosev, Ingrid and Jovanović, Z. and Jančić-Heinemann, Radmila and Dimitrijević, M. and Mišković-Stanković, Vesna",
year = "2010",
abstract = "The corrosion protection of vinyltriethoxysilane (VTES) films on aluminium during exposure to 3% NaCl was investigated using electrochemical impedance spectroscopy (EIS), potential-time measurements and optical microscopy coupled with image analysis. Composition and thickness of films were analyzed using Auger electron spectroscopy (AES) combined with depth profiling. It was shown that films deposited from 5% solution were significantly thicker and exhibited lower porosity and better corrosion stability, as compared to films deposited from 2 vol.% solution. VTES films deposited from 5 vol.% solutions and cured for 30 min exhibited better protection properties than other investigated films.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Corrosion Science",
title = "Corrosion protection of aluminium pretreated by vinyltriethoxysilane in sodium chloride solution",
pages = "1069-1060",
number = "3",
volume = "52",
doi = "10.1016/j.corsci.2009.11.035"
}
Bajat, J., Milosev, I., Jovanović, Z., Jančić-Heinemann, R., Dimitrijević, M.,& Mišković-Stanković, V.. (2010). Corrosion protection of aluminium pretreated by vinyltriethoxysilane in sodium chloride solution. in Corrosion Science
Pergamon-Elsevier Science Ltd, Oxford., 52(3), 1060-1069.
https://doi.org/10.1016/j.corsci.2009.11.035
Bajat J, Milosev I, Jovanović Z, Jančić-Heinemann R, Dimitrijević M, Mišković-Stanković V. Corrosion protection of aluminium pretreated by vinyltriethoxysilane in sodium chloride solution. in Corrosion Science. 2010;52(3):1060-1069.
doi:10.1016/j.corsci.2009.11.035 .
Bajat, Jelena, Milosev, Ingrid, Jovanović, Z., Jančić-Heinemann, Radmila, Dimitrijević, M., Mišković-Stanković, Vesna, "Corrosion protection of aluminium pretreated by vinyltriethoxysilane in sodium chloride solution" in Corrosion Science, 52, no. 3 (2010):1060-1069,
https://doi.org/10.1016/j.corsci.2009.11.035 . .
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