Ministry of Education and Science, Serbia

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Ministry of Education and Science, Serbia

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Publications

Prediction and correlation of viscosity of binary mixtures of ionic liquids with organic solvents

Majstorović, Divna; Šerbanović, Slobodan P.; Živković, Emila; Jovanović, Jovan; Kijevčanin, Mirjana

(Elsevier, Amsterdam, 2014)

TY  - JOUR
AU  - Majstorović, Divna
AU  - Šerbanović, Slobodan P.
AU  - Živković, Emila
AU  - Jovanović, Jovan
AU  - Kijevčanin, Mirjana
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2651
AB  - Viscosities of ten binary liquid mixtures consisting of ionic liquids and organic compounds, determined at atmospheric pressure and in a wide temperature range, were calculated using two different approaches, predictive by group contribution models (UNIFAC-VISCO and ASOG-VISCO) and correlative (Seddon, Grunberg-Nissan, McAlister, Eyring-UNIQUAC and Eyring-NRTL models), and compared using literature data. The obtained results were analysed in terms of the applied approach and model. For UNIFAC-VISCO and ASOG-VISCO predictive models, the literature viscosity data were used to determine new interaction parameters.
PB  - Elsevier, Amsterdam
T2  - Journal of Molecular Liquids
T1  - Prediction and correlation of viscosity of binary mixtures of ionic liquids with organic solvents
EP  - 6
SP  - 1
VL  - 197
DO  - 10.1016/j.molliq.2014.04.005
ER  - 
@article{
author = "Majstorović, Divna and Šerbanović, Slobodan P. and Živković, Emila and Jovanović, Jovan and Kijevčanin, Mirjana",
year = "2014",
abstract = "Viscosities of ten binary liquid mixtures consisting of ionic liquids and organic compounds, determined at atmospheric pressure and in a wide temperature range, were calculated using two different approaches, predictive by group contribution models (UNIFAC-VISCO and ASOG-VISCO) and correlative (Seddon, Grunberg-Nissan, McAlister, Eyring-UNIQUAC and Eyring-NRTL models), and compared using literature data. The obtained results were analysed in terms of the applied approach and model. For UNIFAC-VISCO and ASOG-VISCO predictive models, the literature viscosity data were used to determine new interaction parameters.",
publisher = "Elsevier, Amsterdam",
journal = "Journal of Molecular Liquids",
title = "Prediction and correlation of viscosity of binary mixtures of ionic liquids with organic solvents",
pages = "6-1",
volume = "197",
doi = "10.1016/j.molliq.2014.04.005"
}
Majstorović, D., Šerbanović, S. P., Živković, E., Jovanović, J.,& Kijevčanin, M.. (2014). Prediction and correlation of viscosity of binary mixtures of ionic liquids with organic solvents. in Journal of Molecular Liquids
Elsevier, Amsterdam., 197, 1-6.
https://doi.org/10.1016/j.molliq.2014.04.005
Majstorović D, Šerbanović SP, Živković E, Jovanović J, Kijevčanin M. Prediction and correlation of viscosity of binary mixtures of ionic liquids with organic solvents. in Journal of Molecular Liquids. 2014;197:1-6.
doi:10.1016/j.molliq.2014.04.005 .
Majstorović, Divna, Šerbanović, Slobodan P., Živković, Emila, Jovanović, Jovan, Kijevčanin, Mirjana, "Prediction and correlation of viscosity of binary mixtures of ionic liquids with organic solvents" in Journal of Molecular Liquids, 197 (2014):1-6,
https://doi.org/10.1016/j.molliq.2014.04.005 . .
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Experimental study and modelling of volumetric properties, viscosities and refractive indices of binary liquid mixtures benzene + PEG 200/PEG 400 and toluene + PEG 200/PEG 400

Vuksanović, Jelena; Živković, Emila; Radović, Ivona; Đorđević, Bojan D.; Šerbanović, Slobodan P.; Kijevčanin, Mirjana

(Elsevier Science Bv, Amsterdam, 2013)

TY  - JOUR
AU  - Vuksanović, Jelena
AU  - Živković, Emila
AU  - Radović, Ivona
AU  - Đorđević, Bojan D.
AU  - Šerbanović, Slobodan P.
AU  - Kijevčanin, Mirjana
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2526
AB  - Densities, viscosities and refractive indices of four binary systems benzene + PEG 200, benzene + PEG 400, toluene + PEG 200 and toluene + PEG 400 were measured at ten temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, 333.15 K) and at atmospheric pressure. From these data, excess molar volumes, viscosity deviations and deviations in refractive index were calculated and fitted to the Redlich-Kister equation. The obtained results have been analyzed in terms of specific molecular interactions and mixing behaviour between mixture components, taking into considerations effect of temperature on them. The refractive indices of binary mixtures were predicted by various mixing rules and compared with experimental data. The viscosity modelling was done by two types of models: group contribution UNIFAC-VISCO and ASOG-VISCO and correlative Teja-Rice and McAllister equations. The experimental values of viscosity were used to determine the interaction parameters of following groups CHar-CH2O, CHar-C-ar, C-ar-CH3, C-ar-CH2, C-ar-OH and C-ar-CH2O for their application in the UNIFAC-VISCO model. The same approach was used for calculation of following binary interaction parameters used in ASOG-VISCO model: CHar-CH2O, CHar-C-ar, C-ar-CH2, C-ar-OH and C-ar-CH2O.
PB  - Elsevier Science Bv, Amsterdam
T2  - Fluid Phase Equilibria
T1  - Experimental study and modelling of volumetric properties, viscosities and refractive indices of binary liquid mixtures benzene + PEG 200/PEG 400 and toluene + PEG 200/PEG 400
EP  - 44
SP  - 28
VL  - 345
DO  - 10.1016/j.fluid.2013.02.010
ER  - 
@article{
author = "Vuksanović, Jelena and Živković, Emila and Radović, Ivona and Đorđević, Bojan D. and Šerbanović, Slobodan P. and Kijevčanin, Mirjana",
year = "2013",
abstract = "Densities, viscosities and refractive indices of four binary systems benzene + PEG 200, benzene + PEG 400, toluene + PEG 200 and toluene + PEG 400 were measured at ten temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, 333.15 K) and at atmospheric pressure. From these data, excess molar volumes, viscosity deviations and deviations in refractive index were calculated and fitted to the Redlich-Kister equation. The obtained results have been analyzed in terms of specific molecular interactions and mixing behaviour between mixture components, taking into considerations effect of temperature on them. The refractive indices of binary mixtures were predicted by various mixing rules and compared with experimental data. The viscosity modelling was done by two types of models: group contribution UNIFAC-VISCO and ASOG-VISCO and correlative Teja-Rice and McAllister equations. The experimental values of viscosity were used to determine the interaction parameters of following groups CHar-CH2O, CHar-C-ar, C-ar-CH3, C-ar-CH2, C-ar-OH and C-ar-CH2O for their application in the UNIFAC-VISCO model. The same approach was used for calculation of following binary interaction parameters used in ASOG-VISCO model: CHar-CH2O, CHar-C-ar, C-ar-CH2, C-ar-OH and C-ar-CH2O.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Fluid Phase Equilibria",
title = "Experimental study and modelling of volumetric properties, viscosities and refractive indices of binary liquid mixtures benzene + PEG 200/PEG 400 and toluene + PEG 200/PEG 400",
pages = "44-28",
volume = "345",
doi = "10.1016/j.fluid.2013.02.010"
}
Vuksanović, J., Živković, E., Radović, I., Đorđević, B. D., Šerbanović, S. P.,& Kijevčanin, M.. (2013). Experimental study and modelling of volumetric properties, viscosities and refractive indices of binary liquid mixtures benzene + PEG 200/PEG 400 and toluene + PEG 200/PEG 400. in Fluid Phase Equilibria
Elsevier Science Bv, Amsterdam., 345, 28-44.
https://doi.org/10.1016/j.fluid.2013.02.010
Vuksanović J, Živković E, Radović I, Đorđević BD, Šerbanović SP, Kijevčanin M. Experimental study and modelling of volumetric properties, viscosities and refractive indices of binary liquid mixtures benzene + PEG 200/PEG 400 and toluene + PEG 200/PEG 400. in Fluid Phase Equilibria. 2013;345:28-44.
doi:10.1016/j.fluid.2013.02.010 .
Vuksanović, Jelena, Živković, Emila, Radović, Ivona, Đorđević, Bojan D., Šerbanović, Slobodan P., Kijevčanin, Mirjana, "Experimental study and modelling of volumetric properties, viscosities and refractive indices of binary liquid mixtures benzene + PEG 200/PEG 400 and toluene + PEG 200/PEG 400" in Fluid Phase Equilibria, 345 (2013):28-44,
https://doi.org/10.1016/j.fluid.2013.02.010 . .
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Environmentally friendly solutions of liquid poly(ethylene glycol) and imidazolium based ionic liquids with bistriflamide and triflate anions: Volumetric and viscosity studies

Vuksanović, Jelena; Calado, Marta S.; Ivaniš, Gorica; Kijevčanin, Mirjana; Šerbanović, Slobodan P.; Višak, Zoran P.

(Elsevier Science Bv, Amsterdam, 2013)

TY  - JOUR
AU  - Vuksanović, Jelena
AU  - Calado, Marta S.
AU  - Ivaniš, Gorica
AU  - Kijevčanin, Mirjana
AU  - Šerbanović, Slobodan P.
AU  - Višak, Zoran P.
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2422
AB  - In this paper, densities and viscosities of the solutions of PEG200 with two imidazolium ionic liquids, 1-ethyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}amide ([C(2)mim][NTf2]) and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([C(2)mim][OTf]), at pressure 0.1 MPa and in the temperature range of 288.15-318.15 K, were measured. The experimental data were used to calculate excess molar volumes, deviations in viscosity and excess molar Gibbs free energies of activation of viscous flow for the studied solutions. Excess molar volumes indicate strong attractive interactions provoked by the studied ionic liquids which are even enhanced in the case of the [C(2)mim][OTf] as a solution component. The analysis of the viscosity data showed that these cannot be solely explained on the basis of the interactions between the present molecules/ions and that the factors also related to entropy - size and packing of molecules - must be considered as well. Thus, excess molar Gibbs free energy of activation of viscous flow appeared as very important for a complete description of the current viscosity behavior.
PB  - Elsevier Science Bv, Amsterdam
T2  - Fluid Phase Equilibria
T1  - Environmentally friendly solutions of liquid poly(ethylene glycol) and imidazolium based ionic liquids with bistriflamide and triflate anions: Volumetric and viscosity studies
EP  - 109
SP  - 100
VL  - 352
DO  - 10.1016/j.fluid.2013.05.013
ER  - 
@article{
author = "Vuksanović, Jelena and Calado, Marta S. and Ivaniš, Gorica and Kijevčanin, Mirjana and Šerbanović, Slobodan P. and Višak, Zoran P.",
year = "2013",
abstract = "In this paper, densities and viscosities of the solutions of PEG200 with two imidazolium ionic liquids, 1-ethyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}amide ([C(2)mim][NTf2]) and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([C(2)mim][OTf]), at pressure 0.1 MPa and in the temperature range of 288.15-318.15 K, were measured. The experimental data were used to calculate excess molar volumes, deviations in viscosity and excess molar Gibbs free energies of activation of viscous flow for the studied solutions. Excess molar volumes indicate strong attractive interactions provoked by the studied ionic liquids which are even enhanced in the case of the [C(2)mim][OTf] as a solution component. The analysis of the viscosity data showed that these cannot be solely explained on the basis of the interactions between the present molecules/ions and that the factors also related to entropy - size and packing of molecules - must be considered as well. Thus, excess molar Gibbs free energy of activation of viscous flow appeared as very important for a complete description of the current viscosity behavior.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Fluid Phase Equilibria",
title = "Environmentally friendly solutions of liquid poly(ethylene glycol) and imidazolium based ionic liquids with bistriflamide and triflate anions: Volumetric and viscosity studies",
pages = "109-100",
volume = "352",
doi = "10.1016/j.fluid.2013.05.013"
}
Vuksanović, J., Calado, M. S., Ivaniš, G., Kijevčanin, M., Šerbanović, S. P.,& Višak, Z. P.. (2013). Environmentally friendly solutions of liquid poly(ethylene glycol) and imidazolium based ionic liquids with bistriflamide and triflate anions: Volumetric and viscosity studies. in Fluid Phase Equilibria
Elsevier Science Bv, Amsterdam., 352, 100-109.
https://doi.org/10.1016/j.fluid.2013.05.013
Vuksanović J, Calado MS, Ivaniš G, Kijevčanin M, Šerbanović SP, Višak ZP. Environmentally friendly solutions of liquid poly(ethylene glycol) and imidazolium based ionic liquids with bistriflamide and triflate anions: Volumetric and viscosity studies. in Fluid Phase Equilibria. 2013;352:100-109.
doi:10.1016/j.fluid.2013.05.013 .
Vuksanović, Jelena, Calado, Marta S., Ivaniš, Gorica, Kijevčanin, Mirjana, Šerbanović, Slobodan P., Višak, Zoran P., "Environmentally friendly solutions of liquid poly(ethylene glycol) and imidazolium based ionic liquids with bistriflamide and triflate anions: Volumetric and viscosity studies" in Fluid Phase Equilibria, 352 (2013):100-109,
https://doi.org/10.1016/j.fluid.2013.05.013 . .
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Prediction of thermophysical and transport properties of ternary organic non-electrolyte systems including water by polynomials

Đorđević, Bojan D.; Kijevčanin, Mirjana; Radović, Ivona; Šerbanović, Slobodan P.; Tasić, Aleksandar Ž.

(Serbian Chemical Society, Belgrade, 2013)

TY  - JOUR
AU  - Đorđević, Bojan D.
AU  - Kijevčanin, Mirjana
AU  - Radović, Ivona
AU  - Šerbanović, Slobodan P.
AU  - Tasić, Aleksandar Ž.
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2359
AB  - The description and prediction of thermophysical and transport properties of ternary organic non-electrolyte systems including water by polynomial equations are reviewed. Empirical equations of Radojković et al. (also known as Redlich-Kister), Kohler, Jacob-Fitzner, Colinet, Tsao-Smith, Toop, Scatchard et al. and Rastogi et al. are compared with experimental data of available papers that appeared in well know international journals (Fluid Phase Equilibria, Journal of Chemical and Engineering Data, Journal of Chemical Thermodynamics, Journal of Solution Chemistry, Journal of the Serbian Chemical Society, The Canadian Journal of Chemical Engineering, Journal of Molecular Liquids, Thermochimica Acta, etc.). The applicability of empirical models to estimate excess molar volumes, VE, excess viscosities, Δη, excess free energies of activation of viscous flow, ΔG*E, molar refraction changes on mixing, ΔR, changes in the refractive indices on mixing, ΔnD, changes of isentropic compressibility, ΔkS, surface tension deviations, ΔϬ, speed of sound deviations, Δu, relative permittivity deviations, Δεr, were checked on the series of ternary mixtures of very complex structure, which is described very shortly. The obtained results of prediction are discussed and some recommendations about the use of symmetric or asymmetric models to the possible application to mixtures are made.
AB  - U ovom preglednom radu je dat opis i predskazivanje termofuzičkih i transportnih svojstava trojnih organskih neelektrolitnih sistema, uključujući i vodu pomoću polinoma. Empirijske jednačine Radojkovića i sar. (odnosno Redlich-Kister), Kohlera, Jacob-Fitznera, Colineta, Tsao-Smitha, Toora, Scatcharda i sar. i Rastogia i sar. su poređene sa raspoloživim eksperimentalnim podacima objavljenim u poznatim međunarodnim časopisima (Fluid Phase Equilibria, Journal of Chemical and Engineering Data, Journal of Chemical Theromodynamics, Journal of Solution Chemistry, Journal of the Serbian Chemical Society, The Canadian Journal of Chemical Engineering, Journal of Molecular Liquids, Thermochimica Acta i dr.). Primenljivost empirijskih modela na određivanje dopunske molarne zapremine, VE, dopunskih viskoznosti, Δη, dopunske slobodne energije aktivacije viskoznog toka, ΔG*E , promene molarne refrakcije mešanja, ΔR, promene indeksa refrakcije pri mešanju, ΔnD, promene izentropske kompresibilnosti, ΔkS, odstupanje površinskog napona, ΔϬ odstupanje brzine zvuka, Δu, i odstupanje relativne permitivnosti, Δεr, proverena je na seriji trojnih smeša vrlo složene strukture koje su i elementarno opisane. Dobijeni rezultati predskazivanja su prodiskutovani i date su izvesne preporuke za korišćenje simetričnih i nesimetričnih modela i mogućoj uspešnoj primeni na smeše. PR Projekat Ministarstva nauke Republike Srbije, br. 112063.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Prediction of thermophysical and transport properties of ternary organic non-electrolyte systems including water by polynomials
T1  - Predskazivanje termofizičkih i transportnih svojstava trojnih organskih neelektrolitnih sistema, uključujući vodu, pomoću polinoma
EP  - 1117
IS  - 8
SP  - 1079
VL  - 78
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2359
ER  - 
@article{
author = "Đorđević, Bojan D. and Kijevčanin, Mirjana and Radović, Ivona and Šerbanović, Slobodan P. and Tasić, Aleksandar Ž.",
year = "2013",
abstract = "The description and prediction of thermophysical and transport properties of ternary organic non-electrolyte systems including water by polynomial equations are reviewed. Empirical equations of Radojković et al. (also known as Redlich-Kister), Kohler, Jacob-Fitzner, Colinet, Tsao-Smith, Toop, Scatchard et al. and Rastogi et al. are compared with experimental data of available papers that appeared in well know international journals (Fluid Phase Equilibria, Journal of Chemical and Engineering Data, Journal of Chemical Thermodynamics, Journal of Solution Chemistry, Journal of the Serbian Chemical Society, The Canadian Journal of Chemical Engineering, Journal of Molecular Liquids, Thermochimica Acta, etc.). The applicability of empirical models to estimate excess molar volumes, VE, excess viscosities, Δη, excess free energies of activation of viscous flow, ΔG*E, molar refraction changes on mixing, ΔR, changes in the refractive indices on mixing, ΔnD, changes of isentropic compressibility, ΔkS, surface tension deviations, ΔϬ, speed of sound deviations, Δu, relative permittivity deviations, Δεr, were checked on the series of ternary mixtures of very complex structure, which is described very shortly. The obtained results of prediction are discussed and some recommendations about the use of symmetric or asymmetric models to the possible application to mixtures are made., U ovom preglednom radu je dat opis i predskazivanje termofuzičkih i transportnih svojstava trojnih organskih neelektrolitnih sistema, uključujući i vodu pomoću polinoma. Empirijske jednačine Radojkovića i sar. (odnosno Redlich-Kister), Kohlera, Jacob-Fitznera, Colineta, Tsao-Smitha, Toora, Scatcharda i sar. i Rastogia i sar. su poređene sa raspoloživim eksperimentalnim podacima objavljenim u poznatim međunarodnim časopisima (Fluid Phase Equilibria, Journal of Chemical and Engineering Data, Journal of Chemical Theromodynamics, Journal of Solution Chemistry, Journal of the Serbian Chemical Society, The Canadian Journal of Chemical Engineering, Journal of Molecular Liquids, Thermochimica Acta i dr.). Primenljivost empirijskih modela na određivanje dopunske molarne zapremine, VE, dopunskih viskoznosti, Δη, dopunske slobodne energije aktivacije viskoznog toka, ΔG*E , promene molarne refrakcije mešanja, ΔR, promene indeksa refrakcije pri mešanju, ΔnD, promene izentropske kompresibilnosti, ΔkS, odstupanje površinskog napona, ΔϬ odstupanje brzine zvuka, Δu, i odstupanje relativne permitivnosti, Δεr, proverena je na seriji trojnih smeša vrlo složene strukture koje su i elementarno opisane. Dobijeni rezultati predskazivanja su prodiskutovani i date su izvesne preporuke za korišćenje simetričnih i nesimetričnih modela i mogućoj uspešnoj primeni na smeše. PR Projekat Ministarstva nauke Republike Srbije, br. 112063.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Prediction of thermophysical and transport properties of ternary organic non-electrolyte systems including water by polynomials, Predskazivanje termofizičkih i transportnih svojstava trojnih organskih neelektrolitnih sistema, uključujući vodu, pomoću polinoma",
pages = "1117-1079",
number = "8",
volume = "78",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2359"
}
Đorđević, B. D., Kijevčanin, M., Radović, I., Šerbanović, S. P.,& Tasić, A. Ž.. (2013). Prediction of thermophysical and transport properties of ternary organic non-electrolyte systems including water by polynomials. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 78(8), 1079-1117.
https://hdl.handle.net/21.15107/rcub_technorep_2359
Đorđević BD, Kijevčanin M, Radović I, Šerbanović SP, Tasić AŽ. Prediction of thermophysical and transport properties of ternary organic non-electrolyte systems including water by polynomials. in Journal of the Serbian Chemical Society. 2013;78(8):1079-1117.
https://hdl.handle.net/21.15107/rcub_technorep_2359 .
Đorđević, Bojan D., Kijevčanin, Mirjana, Radović, Ivona, Šerbanović, Slobodan P., Tasić, Aleksandar Ž., "Prediction of thermophysical and transport properties of ternary organic non-electrolyte systems including water by polynomials" in Journal of the Serbian Chemical Society, 78, no. 8 (2013):1079-1117,
https://hdl.handle.net/21.15107/rcub_technorep_2359 .
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