Research Fund of Ministry of Education, Science and Technological Development, Serbia

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Research Fund of Ministry of Education, Science and Technological Development, Serbia

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Publications

Thermodynamic study of ester diethyl tartrate and its binary systems with iso-alcohols

Majstorović, Divna; Radović, Ivona; Kijevčanin, Mirjana; Živković, Emila

(Elsevier, Amsterdam, 2020)

TY  - JOUR
AU  - Majstorović, Divna
AU  - Radović, Ivona
AU  - Kijevčanin, Mirjana
AU  - Živković, Emila
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4490
AB  - Densities of pure ester diethyl tartrate and alcohols isobutanol and isopentanol are measured on high pressures up to 60 MPa and temperatures from 293.15 K to 413.15 K, while thermophysical properties for two systems ester + alcohol are obtained on atmospheric pressure and temperatures 288.15-323.15 K. High pressure densities were correlated with Tammann-Tait equation. Experimental data on atmospheric pressure for mixtures were used to determine derived properties, excess molar volume, viscosity and refractive index deviations, which are then correlated with Redlich-Kister polynomial equation. To support the discussion regarding interactions, FF-IR analyses of pure components and mixtures with highest absolute values of excess molar volume were presented. Additionally, viscosity modelling was performed with predictive and correlative models and results were discussed from the point of potential usage of applied models to calculate viscosity of investigated systems.
PB  - Elsevier, Amsterdam
T2  - Fluid Phase Equilibria
T1  - Thermodynamic study of ester diethyl tartrate and its binary systems with iso-alcohols
VL  - 509
DO  - 10.1016/j.fluid.2020.112461
ER  - 
@article{
author = "Majstorović, Divna and Radović, Ivona and Kijevčanin, Mirjana and Živković, Emila",
year = "2020",
abstract = "Densities of pure ester diethyl tartrate and alcohols isobutanol and isopentanol are measured on high pressures up to 60 MPa and temperatures from 293.15 K to 413.15 K, while thermophysical properties for two systems ester + alcohol are obtained on atmospheric pressure and temperatures 288.15-323.15 K. High pressure densities were correlated with Tammann-Tait equation. Experimental data on atmospheric pressure for mixtures were used to determine derived properties, excess molar volume, viscosity and refractive index deviations, which are then correlated with Redlich-Kister polynomial equation. To support the discussion regarding interactions, FF-IR analyses of pure components and mixtures with highest absolute values of excess molar volume were presented. Additionally, viscosity modelling was performed with predictive and correlative models and results were discussed from the point of potential usage of applied models to calculate viscosity of investigated systems.",
publisher = "Elsevier, Amsterdam",
journal = "Fluid Phase Equilibria",
title = "Thermodynamic study of ester diethyl tartrate and its binary systems with iso-alcohols",
volume = "509",
doi = "10.1016/j.fluid.2020.112461"
}
Majstorović, D., Radović, I., Kijevčanin, M.,& Živković, E.. (2020). Thermodynamic study of ester diethyl tartrate and its binary systems with iso-alcohols. in Fluid Phase Equilibria
Elsevier, Amsterdam., 509.
https://doi.org/10.1016/j.fluid.2020.112461
Majstorović D, Radović I, Kijevčanin M, Živković E. Thermodynamic study of ester diethyl tartrate and its binary systems with iso-alcohols. in Fluid Phase Equilibria. 2020;509.
doi:10.1016/j.fluid.2020.112461 .
Majstorović, Divna, Radović, Ivona, Kijevčanin, Mirjana, Živković, Emila, "Thermodynamic study of ester diethyl tartrate and its binary systems with iso-alcohols" in Fluid Phase Equilibria, 509 (2020),
https://doi.org/10.1016/j.fluid.2020.112461 . .
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Effect of water addition on extraction ability of eutectic solvent choline chloride+1,2-propanediol for separation of hexane/heptane plus ethanol systems

Vuksanović, Jelena; Kijevčanin, Mirjana; Radović, Ivona

(Korean Institute Chemical Engineers, Seoul, 2018)

TY  - JOUR
AU  - Vuksanović, Jelena
AU  - Kijevčanin, Mirjana
AU  - Radović, Ivona
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3864
AB  - The ability of binary deep eutectic solvent choline chloride+1,2-propanediol (DES1; 1 : 3 mole ratio) and ternary deep eutectic solvent choline chloride+1,2-propanediol+water (DES2; 1 : 3 : 3 mole ratio) for breaking the azeotropes hexane/heptane+ethanol by means of liquid-liquid extraction was evaluated. Liquid-liquid equilibrium experiments were performed at 298.15 K, at atmospheric pressure, and data were correlated by NRTL and UNIQUAC models. Thermodynamic properties (density, viscosity, refractive index and speed of sound) of DES1 and DES2 were determined in temperature range from 288.15 K to 333.15 K and at atmospheric pressure. Extraction ability of the investigated eutectics yielded promising results in comparison with conventional solvents. Besides a high selectivity towards ethanol, an advantage of DES2 is its lower viscosity and higher distribution ratio values, which is an important aspect for a potential industrial application. Another advantage of both investigated eutectics is their easy and high recoverability from the extract layer based on their negligible vapor pressure.
PB  - Korean Institute Chemical  Engineers, Seoul
T2  - Korean Journal of Chemical Engineering
T1  - Effect of water addition on extraction ability of eutectic solvent choline chloride+1,2-propanediol for separation of hexane/heptane plus ethanol systems
EP  - 1487
IS  - 7
SP  - 1477
VL  - 35
DO  - 10.1007/s11814-018-0030-z
ER  - 
@article{
author = "Vuksanović, Jelena and Kijevčanin, Mirjana and Radović, Ivona",
year = "2018",
abstract = "The ability of binary deep eutectic solvent choline chloride+1,2-propanediol (DES1; 1 : 3 mole ratio) and ternary deep eutectic solvent choline chloride+1,2-propanediol+water (DES2; 1 : 3 : 3 mole ratio) for breaking the azeotropes hexane/heptane+ethanol by means of liquid-liquid extraction was evaluated. Liquid-liquid equilibrium experiments were performed at 298.15 K, at atmospheric pressure, and data were correlated by NRTL and UNIQUAC models. Thermodynamic properties (density, viscosity, refractive index and speed of sound) of DES1 and DES2 were determined in temperature range from 288.15 K to 333.15 K and at atmospheric pressure. Extraction ability of the investigated eutectics yielded promising results in comparison with conventional solvents. Besides a high selectivity towards ethanol, an advantage of DES2 is its lower viscosity and higher distribution ratio values, which is an important aspect for a potential industrial application. Another advantage of both investigated eutectics is their easy and high recoverability from the extract layer based on their negligible vapor pressure.",
publisher = "Korean Institute Chemical  Engineers, Seoul",
journal = "Korean Journal of Chemical Engineering",
title = "Effect of water addition on extraction ability of eutectic solvent choline chloride+1,2-propanediol for separation of hexane/heptane plus ethanol systems",
pages = "1487-1477",
number = "7",
volume = "35",
doi = "10.1007/s11814-018-0030-z"
}
Vuksanović, J., Kijevčanin, M.,& Radović, I.. (2018). Effect of water addition on extraction ability of eutectic solvent choline chloride+1,2-propanediol for separation of hexane/heptane plus ethanol systems. in Korean Journal of Chemical Engineering
Korean Institute Chemical  Engineers, Seoul., 35(7), 1477-1487.
https://doi.org/10.1007/s11814-018-0030-z
Vuksanović J, Kijevčanin M, Radović I. Effect of water addition on extraction ability of eutectic solvent choline chloride+1,2-propanediol for separation of hexane/heptane plus ethanol systems. in Korean Journal of Chemical Engineering. 2018;35(7):1477-1487.
doi:10.1007/s11814-018-0030-z .
Vuksanović, Jelena, Kijevčanin, Mirjana, Radović, Ivona, "Effect of water addition on extraction ability of eutectic solvent choline chloride+1,2-propanediol for separation of hexane/heptane plus ethanol systems" in Korean Journal of Chemical Engineering, 35, no. 7 (2018):1477-1487,
https://doi.org/10.1007/s11814-018-0030-z . .
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Poly(ethylene glycol) diacrylate as a novel chaotropic compound for design of aqueous biphasic systems

Vuksanović, Jelena; Kijevčanin, Mirjana; Radović, Ivona

(Elsevier Science Bv, Amsterdam, 2018)

TY  - JOUR
AU  - Vuksanović, Jelena
AU  - Kijevčanin, Mirjana
AU  - Radović, Ivona
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3872
AB  - In this work novel solvent, poly(ethylene glycol) diacrylate (PEGDA) of average number molecular weight 700, is proposed for design of aqueous biphasic systems with salting-out agents: K3PO4/Na3C6H5O7/K2CO3/MnSO4/Li2SO4/ZnSO4. Ternary liquid-liquid equilibrium experiments were conducted at constant temperature 298.15 K and 0.1 MPa, where binodal curves and tie-lines were determined. The consistency of equilibrium data were checked and confirmed using Othmer-Tobias and Bancroft equations. Density rho, viscosity eta and refractive index n(D) have been experimentally measured for PEGDA 700 + water system over the temperature range T = (293.15 to 323.15) K with temperature step 5 K and at atmospheric pressure. Excess molar volumes V-E, viscosity deviations Delta eta, deviations in refractive index Delta n(D), excess Gibbs free energy of activation of viscous flow Delta G*(E), partial molar volumes (V) over bar (i), excess partial molar volumes (V) over bar (E)(i) and it's values at infinite dilutions (V) over bar (E,infinity)(i) were calculated from experimental data and used to analyze non-ideal behavior of polymer aqueous solution. Fourier-transform infrared analysis (FT-IR) of PEGDA + water mixture and corresponding pure components was performed at T = 298.15 K in order to gain insight into the molecular structure of the mixture. FT-IR analysis indicates the absence of hydrogen bonding between PEGDA 700 and water. This leads to the conclusion that non-ideal behavior of mixture is contributed to geometrical packing or van der Waals forces of different species.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Molecular Liquids
T1  - Poly(ethylene glycol) diacrylate as a novel chaotropic compound for design of aqueous biphasic systems
EP  - 264
SP  - 250
VL  - 261
DO  - 10.1016/j.molliq.2018.04.023
ER  - 
@article{
author = "Vuksanović, Jelena and Kijevčanin, Mirjana and Radović, Ivona",
year = "2018",
abstract = "In this work novel solvent, poly(ethylene glycol) diacrylate (PEGDA) of average number molecular weight 700, is proposed for design of aqueous biphasic systems with salting-out agents: K3PO4/Na3C6H5O7/K2CO3/MnSO4/Li2SO4/ZnSO4. Ternary liquid-liquid equilibrium experiments were conducted at constant temperature 298.15 K and 0.1 MPa, where binodal curves and tie-lines were determined. The consistency of equilibrium data were checked and confirmed using Othmer-Tobias and Bancroft equations. Density rho, viscosity eta and refractive index n(D) have been experimentally measured for PEGDA 700 + water system over the temperature range T = (293.15 to 323.15) K with temperature step 5 K and at atmospheric pressure. Excess molar volumes V-E, viscosity deviations Delta eta, deviations in refractive index Delta n(D), excess Gibbs free energy of activation of viscous flow Delta G*(E), partial molar volumes (V) over bar (i), excess partial molar volumes (V) over bar (E)(i) and it's values at infinite dilutions (V) over bar (E,infinity)(i) were calculated from experimental data and used to analyze non-ideal behavior of polymer aqueous solution. Fourier-transform infrared analysis (FT-IR) of PEGDA + water mixture and corresponding pure components was performed at T = 298.15 K in order to gain insight into the molecular structure of the mixture. FT-IR analysis indicates the absence of hydrogen bonding between PEGDA 700 and water. This leads to the conclusion that non-ideal behavior of mixture is contributed to geometrical packing or van der Waals forces of different species.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Molecular Liquids",
title = "Poly(ethylene glycol) diacrylate as a novel chaotropic compound for design of aqueous biphasic systems",
pages = "264-250",
volume = "261",
doi = "10.1016/j.molliq.2018.04.023"
}
Vuksanović, J., Kijevčanin, M.,& Radović, I.. (2018). Poly(ethylene glycol) diacrylate as a novel chaotropic compound for design of aqueous biphasic systems. in Journal of Molecular Liquids
Elsevier Science Bv, Amsterdam., 261, 250-264.
https://doi.org/10.1016/j.molliq.2018.04.023
Vuksanović J, Kijevčanin M, Radović I. Poly(ethylene glycol) diacrylate as a novel chaotropic compound for design of aqueous biphasic systems. in Journal of Molecular Liquids. 2018;261:250-264.
doi:10.1016/j.molliq.2018.04.023 .
Vuksanović, Jelena, Kijevčanin, Mirjana, Radović, Ivona, "Poly(ethylene glycol) diacrylate as a novel chaotropic compound for design of aqueous biphasic systems" in Journal of Molecular Liquids, 261 (2018):250-264,
https://doi.org/10.1016/j.molliq.2018.04.023 . .
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Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes

Živković, Emila; Živković, Nikola V.; Majstorović, Divna; Stanimirović, Andrej M.; Kijevčanin, Mirjana

(Academic Press Ltd- Elsevier Science Ltd, London, 2018)

TY  - JOUR
AU  - Živković, Emila
AU  - Živković, Nikola V.
AU  - Majstorović, Divna
AU  - Stanimirović, Andrej M.
AU  - Kijevčanin, Mirjana
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3981
AB  - This paper presents novel data on density, viscosity and refractive index of four binary mixtures constituted of ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate and N-methyl-2-pyrrolidone/or 1-hexanol/or liquid polyethylene glycols with molar mass 200/or 400, in the temperature range from T = 288.15 K to 333.15 K and at pressure of p =.1 MPa. Thermal conductivity has been measured for mixtures of ionic liquid and polyethylene glycol 200/or polyethylene glycol 400 in the temperature range from T = 303.15 to 323.15 K and at a pressure of p =.1 MPa. All these solutions have the potential for application in regenerative flue gas desulfurization processes. From experimental values of densities, viscosities, thermal conductivities and refractive indices, excess molar volumes and deviations in viscosity, thermal conductivity and refractive index have been calculated and correlated with Redlich-Kister polynomial equation. The values of excess and deviation functions were used for analysis of molecular interactions present in the investigated solutions. In addition, modeling of transport properties, viscosity and thermal conductivity, was carried out and the obtained results were interpreted taking into account the applied approaches and models.
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Chemical Thermodynamics
T1  - Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes
EP  - 154
SP  - 135
VL  - 119
DO  - 10.1016/j.jct.2017.12.023
ER  - 
@article{
author = "Živković, Emila and Živković, Nikola V. and Majstorović, Divna and Stanimirović, Andrej M. and Kijevčanin, Mirjana",
year = "2018",
abstract = "This paper presents novel data on density, viscosity and refractive index of four binary mixtures constituted of ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate and N-methyl-2-pyrrolidone/or 1-hexanol/or liquid polyethylene glycols with molar mass 200/or 400, in the temperature range from T = 288.15 K to 333.15 K and at pressure of p =.1 MPa. Thermal conductivity has been measured for mixtures of ionic liquid and polyethylene glycol 200/or polyethylene glycol 400 in the temperature range from T = 303.15 to 323.15 K and at a pressure of p =.1 MPa. All these solutions have the potential for application in regenerative flue gas desulfurization processes. From experimental values of densities, viscosities, thermal conductivities and refractive indices, excess molar volumes and deviations in viscosity, thermal conductivity and refractive index have been calculated and correlated with Redlich-Kister polynomial equation. The values of excess and deviation functions were used for analysis of molecular interactions present in the investigated solutions. In addition, modeling of transport properties, viscosity and thermal conductivity, was carried out and the obtained results were interpreted taking into account the applied approaches and models.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes",
pages = "154-135",
volume = "119",
doi = "10.1016/j.jct.2017.12.023"
}
Živković, E., Živković, N. V., Majstorović, D., Stanimirović, A. M.,& Kijevčanin, M.. (2018). Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes. in Journal of Chemical Thermodynamics
Academic Press Ltd- Elsevier Science Ltd, London., 119, 135-154.
https://doi.org/10.1016/j.jct.2017.12.023
Živković E, Živković NV, Majstorović D, Stanimirović AM, Kijevčanin M. Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes. in Journal of Chemical Thermodynamics. 2018;119:135-154.
doi:10.1016/j.jct.2017.12.023 .
Živković, Emila, Živković, Nikola V., Majstorović, Divna, Stanimirović, Andrej M., Kijevčanin, Mirjana, "Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes" in Journal of Chemical Thermodynamics, 119 (2018):135-154,
https://doi.org/10.1016/j.jct.2017.12.023 . .
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Experimental investigation and modeling of thermophysical and extraction properties of choline chloride plus DL-malic acid based deep eutectic solvent

Vuksanović, Jelena; Todorović, Nina; Kijevčanin, Mirjana; Šerbanović, Slobodan P.; Radović, Ivona

(Srpsko hemijsko društvo, Beograd, 2017)

TY  - JOUR
AU  - Vuksanović, Jelena
AU  - Todorović, Nina
AU  - Kijevčanin, Mirjana
AU  - Šerbanović, Slobodan P.
AU  - Radović, Ivona
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3601
AB  - The ability of non-toxic and biodegradable deep eutectic solvent (DES) choline chloride + DL-malic acid in mole ratio 1: 1, for the breaking of the azeotropes heptane + methanol and toluene + methanol by means of liquid-liquid extraction was evaluated. Ternary liquid-liquid equilibrium experiments were performed at 298.15 K and at atmospheric pressure. Densities, viscosities and refractive indices of DES + methanol and water + DES systems were experimentally determined over a wide temperature range and at atmospheric pressure. Additionally, the viscosities of DES + glycerol mixture were determined at temperatures up to 363.15 K to check how much the addition of glycerol decreases high viscosities of DES. The results indicate that the addition of small amounts of water or glycerol as a third component significantly decreases the viscosity of the investigated deep eutectic solvent. Based on the selectivity and distribution ratio values, the extraction ability of the investigated deep eutectic solvent, in comparison with the conventionally used solvents, yields promising results. Non-random two-liquid (NRTL) and universal quasichemical (UNIQUAC) models were satisfactorily applied for correlation of experimental phase equilibrium data for two ternary mixtures.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Experimental investigation and modeling of thermophysical and extraction properties of choline chloride plus DL-malic acid based deep eutectic solvent
EP  - 1302
IS  - 11
SP  - 1287
VL  - 82
DO  - 10.2298/JSC170316054V
ER  - 
@article{
author = "Vuksanović, Jelena and Todorović, Nina and Kijevčanin, Mirjana and Šerbanović, Slobodan P. and Radović, Ivona",
year = "2017",
abstract = "The ability of non-toxic and biodegradable deep eutectic solvent (DES) choline chloride + DL-malic acid in mole ratio 1: 1, for the breaking of the azeotropes heptane + methanol and toluene + methanol by means of liquid-liquid extraction was evaluated. Ternary liquid-liquid equilibrium experiments were performed at 298.15 K and at atmospheric pressure. Densities, viscosities and refractive indices of DES + methanol and water + DES systems were experimentally determined over a wide temperature range and at atmospheric pressure. Additionally, the viscosities of DES + glycerol mixture were determined at temperatures up to 363.15 K to check how much the addition of glycerol decreases high viscosities of DES. The results indicate that the addition of small amounts of water or glycerol as a third component significantly decreases the viscosity of the investigated deep eutectic solvent. Based on the selectivity and distribution ratio values, the extraction ability of the investigated deep eutectic solvent, in comparison with the conventionally used solvents, yields promising results. Non-random two-liquid (NRTL) and universal quasichemical (UNIQUAC) models were satisfactorily applied for correlation of experimental phase equilibrium data for two ternary mixtures.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Experimental investigation and modeling of thermophysical and extraction properties of choline chloride plus DL-malic acid based deep eutectic solvent",
pages = "1302-1287",
number = "11",
volume = "82",
doi = "10.2298/JSC170316054V"
}
Vuksanović, J., Todorović, N., Kijevčanin, M., Šerbanović, S. P.,& Radović, I.. (2017). Experimental investigation and modeling of thermophysical and extraction properties of choline chloride plus DL-malic acid based deep eutectic solvent. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 82(11), 1287-1302.
https://doi.org/10.2298/JSC170316054V
Vuksanović J, Todorović N, Kijevčanin M, Šerbanović SP, Radović I. Experimental investigation and modeling of thermophysical and extraction properties of choline chloride plus DL-malic acid based deep eutectic solvent. in Journal of the Serbian Chemical Society. 2017;82(11):1287-1302.
doi:10.2298/JSC170316054V .
Vuksanović, Jelena, Todorović, Nina, Kijevčanin, Mirjana, Šerbanović, Slobodan P., Radović, Ivona, "Experimental investigation and modeling of thermophysical and extraction properties of choline chloride plus DL-malic acid based deep eutectic solvent" in Journal of the Serbian Chemical Society, 82, no. 11 (2017):1287-1302,
https://doi.org/10.2298/JSC170316054V . .
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Volumetric and viscometric study and modelling of binary systems of diethyl tartrate and alcohols

Majstorović, Divna; Živković, Emila; Kijevčanin, Mirjana

(Elsevier Science Bv, Amsterdam, 2017)

TY  - JOUR
AU  - Majstorović, Divna
AU  - Živković, Emila
AU  - Kijevčanin, Mirjana
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3596
AB  - Density, viscosity, refractive index and speed of sound have been measured for the pure ester diethyl tartrate at atmospheric pressure and over the temperature range from 288.15 K to 323.15 K. Detailed investigation regarding volumetric and viscometric properties was conducted under the same conditions for three binary mixtures: diethyl tartrate +1-propanol or +1-butanol or +1-hexanol. Excess and deviation functions have been calculated from experimental data and correlated with the Redlich-Kister equation. These functions were further discussed in terms of molecular interactions existing in the mixtures as well as the temperature influence on them. Additionally, excess molar Gibbs energies of activation of viscous flow and partial and excess partial molar volumes were determined for investigated systems. Modelling was performed for viscosity and excess molar volume and the obtained results were analyzed taking into account the applied approaches and models.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Molecular Liquids
T1  - Volumetric and viscometric study and modelling of binary systems of diethyl tartrate and alcohols
EP  - 226
SP  - 219
VL  - 248
DO  - 10.1016/j.molliq.2017.10.067
ER  - 
@article{
author = "Majstorović, Divna and Živković, Emila and Kijevčanin, Mirjana",
year = "2017",
abstract = "Density, viscosity, refractive index and speed of sound have been measured for the pure ester diethyl tartrate at atmospheric pressure and over the temperature range from 288.15 K to 323.15 K. Detailed investigation regarding volumetric and viscometric properties was conducted under the same conditions for three binary mixtures: diethyl tartrate +1-propanol or +1-butanol or +1-hexanol. Excess and deviation functions have been calculated from experimental data and correlated with the Redlich-Kister equation. These functions were further discussed in terms of molecular interactions existing in the mixtures as well as the temperature influence on them. Additionally, excess molar Gibbs energies of activation of viscous flow and partial and excess partial molar volumes were determined for investigated systems. Modelling was performed for viscosity and excess molar volume and the obtained results were analyzed taking into account the applied approaches and models.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Molecular Liquids",
title = "Volumetric and viscometric study and modelling of binary systems of diethyl tartrate and alcohols",
pages = "226-219",
volume = "248",
doi = "10.1016/j.molliq.2017.10.067"
}
Majstorović, D., Živković, E.,& Kijevčanin, M.. (2017). Volumetric and viscometric study and modelling of binary systems of diethyl tartrate and alcohols. in Journal of Molecular Liquids
Elsevier Science Bv, Amsterdam., 248, 219-226.
https://doi.org/10.1016/j.molliq.2017.10.067
Majstorović D, Živković E, Kijevčanin M. Volumetric and viscometric study and modelling of binary systems of diethyl tartrate and alcohols. in Journal of Molecular Liquids. 2017;248:219-226.
doi:10.1016/j.molliq.2017.10.067 .
Majstorović, Divna, Živković, Emila, Kijevčanin, Mirjana, "Volumetric and viscometric study and modelling of binary systems of diethyl tartrate and alcohols" in Journal of Molecular Liquids, 248 (2017):219-226,
https://doi.org/10.1016/j.molliq.2017.10.067 . .
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13

Volumetric and viscometric study with FT-IR analysis of binary systems with diethyl succinate and alcohols

Majstorović, Divna; Živković, Emila; Mitrović, Aleksandra D.; Muncan, Jelena S.; Kijevčanin, Mirjana

(Academic Press Ltd- Elsevier Science Ltd, London, 2016)

TY  - JOUR
AU  - Majstorović, Divna
AU  - Živković, Emila
AU  - Mitrović, Aleksandra D.
AU  - Muncan, Jelena S.
AU  - Kijevčanin, Mirjana
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3226
AB  - Density, viscosity and refractive index of binary mixtures consisting of diethyl succinate + 1-propanol, or + 1-butanol, or + 1-hexanol have been measured at atmospheric pressure and over the temperature range from 288.15 K to 323.15 K. Excess and deviation functions have been calculated from these data and fitted to the Redlich-Kister equation. The values of excess molar volume and deviation functions, with Fourier transform infrared (FT-IR) spectroscopy, were further used in the analysis of molecular interactions present in the mixture as well as the temperature influence on them.
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Chemical Thermodynamics
T1  - Volumetric and viscometric study with FT-IR analysis of binary systems with diethyl succinate and alcohols
EP  - 336
SP  - 323
VL  - 101
DO  - 10.1016/j.jct.2016.06.016
ER  - 
@article{
author = "Majstorović, Divna and Živković, Emila and Mitrović, Aleksandra D. and Muncan, Jelena S. and Kijevčanin, Mirjana",
year = "2016",
abstract = "Density, viscosity and refractive index of binary mixtures consisting of diethyl succinate + 1-propanol, or + 1-butanol, or + 1-hexanol have been measured at atmospheric pressure and over the temperature range from 288.15 K to 323.15 K. Excess and deviation functions have been calculated from these data and fitted to the Redlich-Kister equation. The values of excess molar volume and deviation functions, with Fourier transform infrared (FT-IR) spectroscopy, were further used in the analysis of molecular interactions present in the mixture as well as the temperature influence on them.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Volumetric and viscometric study with FT-IR analysis of binary systems with diethyl succinate and alcohols",
pages = "336-323",
volume = "101",
doi = "10.1016/j.jct.2016.06.016"
}
Majstorović, D., Živković, E., Mitrović, A. D., Muncan, J. S.,& Kijevčanin, M.. (2016). Volumetric and viscometric study with FT-IR analysis of binary systems with diethyl succinate and alcohols. in Journal of Chemical Thermodynamics
Academic Press Ltd- Elsevier Science Ltd, London., 101, 323-336.
https://doi.org/10.1016/j.jct.2016.06.016
Majstorović D, Živković E, Mitrović AD, Muncan JS, Kijevčanin M. Volumetric and viscometric study with FT-IR analysis of binary systems with diethyl succinate and alcohols. in Journal of Chemical Thermodynamics. 2016;101:323-336.
doi:10.1016/j.jct.2016.06.016 .
Majstorović, Divna, Živković, Emila, Mitrović, Aleksandra D., Muncan, Jelena S., Kijevčanin, Mirjana, "Volumetric and viscometric study with FT-IR analysis of binary systems with diethyl succinate and alcohols" in Journal of Chemical Thermodynamics, 101 (2016):323-336,
https://doi.org/10.1016/j.jct.2016.06.016 . .
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Thermodynamic and spectroscopic interpretation of molecular interactions of nicotine plus alcohol binary mixtures

Soldatović, Danijela; Vuksanović, Jelena; Radović, Ivona; Kijevčanin, Mirjana

(Academic Press Ltd- Elsevier Science Ltd, London, 2016)

TY  - JOUR
AU  - Soldatović, Danijela
AU  - Vuksanović, Jelena
AU  - Radović, Ivona
AU  - Kijevčanin, Mirjana
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3366
AB  - Density rho, viscosity eta and refractive index n(D) have been experimentally measured for four binary mixtures nicotine + 1-butanol, nicotine + 2-butanol, nicotine + 1,2-propanediol and nicotine + 1,3-propanediol over the temperature range T = (293.15-323.15) K with temperature step 5 K and at atmospheric pressure. Excess molar volumes V-E, viscosity deviations Delta eta, deviations in refractive index Delta n(D), excess Gibbs free energy of activation of viscous flow Delta G*(E), thermal expansion coefficients a, excess thermal expansion coefficients alpha(E), partial molar volumes (V) over bar (i), excess partial molar volumes (V) over bar (E)(i) and it's values at infinite dilutions (V) over bar (E,infinity)(i) were calculated from experimental data and used to analyze non-ideal behavior of mixtures. Fourier-transform infrared analysis of binary mixtures and corresponding pure components was performed at 298.15 K in order to gain insight into the molecular structure of mixtures and possible intermolecular interactions. Performed infra-red analysis confirms the presence of hydrogen bonding between unlike compounds, except for the system nicotine + 1-butanol. Here, the non-ideal behavior of mixtures is contributed to strong intermolecular interaction or in the case of nicotine + 1-butanol due to geometrical packing or dispersion forces of different species.
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Chemical Thermodynamics
T1  - Thermodynamic and spectroscopic interpretation of molecular interactions of nicotine plus alcohol binary mixtures
EP  - 129
SP  - 105
VL  - 102
DO  - 10.1016/j.jct.2016.07.005
ER  - 
@article{
author = "Soldatović, Danijela and Vuksanović, Jelena and Radović, Ivona and Kijevčanin, Mirjana",
year = "2016",
abstract = "Density rho, viscosity eta and refractive index n(D) have been experimentally measured for four binary mixtures nicotine + 1-butanol, nicotine + 2-butanol, nicotine + 1,2-propanediol and nicotine + 1,3-propanediol over the temperature range T = (293.15-323.15) K with temperature step 5 K and at atmospheric pressure. Excess molar volumes V-E, viscosity deviations Delta eta, deviations in refractive index Delta n(D), excess Gibbs free energy of activation of viscous flow Delta G*(E), thermal expansion coefficients a, excess thermal expansion coefficients alpha(E), partial molar volumes (V) over bar (i), excess partial molar volumes (V) over bar (E)(i) and it's values at infinite dilutions (V) over bar (E,infinity)(i) were calculated from experimental data and used to analyze non-ideal behavior of mixtures. Fourier-transform infrared analysis of binary mixtures and corresponding pure components was performed at 298.15 K in order to gain insight into the molecular structure of mixtures and possible intermolecular interactions. Performed infra-red analysis confirms the presence of hydrogen bonding between unlike compounds, except for the system nicotine + 1-butanol. Here, the non-ideal behavior of mixtures is contributed to strong intermolecular interaction or in the case of nicotine + 1-butanol due to geometrical packing or dispersion forces of different species.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Thermodynamic and spectroscopic interpretation of molecular interactions of nicotine plus alcohol binary mixtures",
pages = "129-105",
volume = "102",
doi = "10.1016/j.jct.2016.07.005"
}
Soldatović, D., Vuksanović, J., Radović, I.,& Kijevčanin, M.. (2016). Thermodynamic and spectroscopic interpretation of molecular interactions of nicotine plus alcohol binary mixtures. in Journal of Chemical Thermodynamics
Academic Press Ltd- Elsevier Science Ltd, London., 102, 105-129.
https://doi.org/10.1016/j.jct.2016.07.005
Soldatović D, Vuksanović J, Radović I, Kijevčanin M. Thermodynamic and spectroscopic interpretation of molecular interactions of nicotine plus alcohol binary mixtures. in Journal of Chemical Thermodynamics. 2016;102:105-129.
doi:10.1016/j.jct.2016.07.005 .
Soldatović, Danijela, Vuksanović, Jelena, Radović, Ivona, Kijevčanin, Mirjana, "Thermodynamic and spectroscopic interpretation of molecular interactions of nicotine plus alcohol binary mixtures" in Journal of Chemical Thermodynamics, 102 (2016):105-129,
https://doi.org/10.1016/j.jct.2016.07.005 . .
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