Predefined functional properties polymer composite materials processes and equipment development

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Predefined functional properties polymer composite materials processes and equipment development (en)
Развој опреме и процеса добијања полимерних композитних материјала са унапред дефинисаним функционалним својствима (sr)
Razvoj opreme i procesa dobijanja polimernih kompozitnih materijala sa unapred definisanim funkcionalnim svojstvima (sr_RS)
Authors

Publications

An Experimental Study of Mechanical Properties and Heat Transfer of Acrylic Composites with Structural and Surface Modified Al2O3 Particles

Mališić, Vanja Z.; Tomić, Nataša Z.; Vuksanović, Marija M.; Balanč, Bojana D.; Stević, Zoran M.; Marinković, Aleksandar D.; Jančić Heinemann, Radmila M.; Putić, Slaviša S.

(International Institute for the Science of Sintering (IISS), 2020)

TY  - JOUR
AU  - Mališić, Vanja Z.
AU  - Tomić, Nataša Z.
AU  - Vuksanović, Marija M.
AU  - Balanč, Bojana D.
AU  - Stević, Zoran M.
AU  - Marinković, Aleksandar D.
AU  - Jančić Heinemann, Radmila M.
AU  - Putić, Slaviša S.
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4740
AB  - Thermal properties of acrylate-based composite combined with alumina-based particles were investigated. The composites were made of poly (methyl methacrylate) (PMMA) modified with dimethyl itaconate (DMI) as a matrix. Neat alumina particles (Al2O3) and alumina doped with iron oxide (Al2O3-Fe) modified with 3-aminopropyl-trimethoxylane (AM) and flax oil fatty acid methyl esters (biodiesel - BD) were used as reinforcement. Thermal conductivity measurements showed that composite with alumina particles with the highest alpha phase content had the highest thermal conductivity values. Mechanical properties (tensile strength, modulus of elasticity and elongation at break) were improved by the addition of modified alumina particles to PMMA/DMI matrix. The thermal properties are the most improved for composite with 3 wt.% Al2O3-Fe-AM particles that had the lowest temperature in a crack zone was noticed (10.28 %) compared to PMMA added due to the better stiffness and highest thermal conductivity.
PB  - International Institute for the Science of Sintering (IISS)
T2  - Science of Sintering
T1  - An Experimental Study of Mechanical Properties and Heat Transfer of Acrylic Composites with Structural and Surface Modified Al2O3 Particles
EP  - 467
IS  - 4
SP  - 457
VL  - 52
DO  - 10.2298/SOS2004457M
ER  - 
@article{
author = "Mališić, Vanja Z. and Tomić, Nataša Z. and Vuksanović, Marija M. and Balanč, Bojana D. and Stević, Zoran M. and Marinković, Aleksandar D. and Jančić Heinemann, Radmila M. and Putić, Slaviša S.",
year = "2020",
abstract = "Thermal properties of acrylate-based composite combined with alumina-based particles were investigated. The composites were made of poly (methyl methacrylate) (PMMA) modified with dimethyl itaconate (DMI) as a matrix. Neat alumina particles (Al2O3) and alumina doped with iron oxide (Al2O3-Fe) modified with 3-aminopropyl-trimethoxylane (AM) and flax oil fatty acid methyl esters (biodiesel - BD) were used as reinforcement. Thermal conductivity measurements showed that composite with alumina particles with the highest alpha phase content had the highest thermal conductivity values. Mechanical properties (tensile strength, modulus of elasticity and elongation at break) were improved by the addition of modified alumina particles to PMMA/DMI matrix. The thermal properties are the most improved for composite with 3 wt.% Al2O3-Fe-AM particles that had the lowest temperature in a crack zone was noticed (10.28 %) compared to PMMA added due to the better stiffness and highest thermal conductivity.",
publisher = "International Institute for the Science of Sintering (IISS)",
journal = "Science of Sintering",
title = "An Experimental Study of Mechanical Properties and Heat Transfer of Acrylic Composites with Structural and Surface Modified Al2O3 Particles",
pages = "467-457",
number = "4",
volume = "52",
doi = "10.2298/SOS2004457M"
}
Mališić, V. Z., Tomić, N. Z., Vuksanović, M. M., Balanč, B. D., Stević, Z. M., Marinković, A. D., Jančić Heinemann, R. M.,& Putić, S. S.. (2020). An Experimental Study of Mechanical Properties and Heat Transfer of Acrylic Composites with Structural and Surface Modified Al2O3 Particles. in Science of Sintering
International Institute for the Science of Sintering (IISS)., 52(4), 457-467.
https://doi.org/10.2298/SOS2004457M
Mališić VZ, Tomić NZ, Vuksanović MM, Balanč BD, Stević ZM, Marinković AD, Jančić Heinemann RM, Putić SS. An Experimental Study of Mechanical Properties and Heat Transfer of Acrylic Composites with Structural and Surface Modified Al2O3 Particles. in Science of Sintering. 2020;52(4):457-467.
doi:10.2298/SOS2004457M .
Mališić, Vanja Z., Tomić, Nataša Z., Vuksanović, Marija M., Balanč, Bojana D., Stević, Zoran M., Marinković, Aleksandar D., Jančić Heinemann, Radmila M., Putić, Slaviša S., "An Experimental Study of Mechanical Properties and Heat Transfer of Acrylic Composites with Structural and Surface Modified Al2O3 Particles" in Science of Sintering, 52, no. 4 (2020):457-467,
https://doi.org/10.2298/SOS2004457M . .
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Polymer composite films and nanofibers doped with core-shell quantum dots

Abozaid, Rouaida Mohamed; Stojanović, Dušica; Radisavljević, Anđela; Sević, Dragutin M.; Rabasović, Maja S.; Radović, I. M.; Radojević, Vesna

(Natl Inst Optoelectronics, Bucharest-Magurele, 2020)

TY  - JOUR
AU  - Abozaid, Rouaida Mohamed
AU  - Stojanović, Dušica
AU  - Radisavljević, Anđela
AU  - Sević, Dragutin M.
AU  - Rabasović, Maja S.
AU  - Radović, I. M.
AU  - Radojević, Vesna
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4573
AB  - Processing and characterization of polymer nanocomposites based on poly(methyl methacrylate) (PMMA) matrix with embedded core-shell CdSe/ZnS quantum dots were investigated. Nanocomposites were obtained via solution casting and electrospinning. FESEM analysis revealed that the processing with electrospinning enables better dispersion of quantum dots. Time-resolved laser induced fluorescence measurements confirmed uniform size of QDs in fibers with the emission at only one wavelength. Oxidation effects in quantum dots were removed with the use of PMMA as a host, and the core remained active, which was confirmed with FTIR analysis and time-resolved laser induced fluorescence measurements.
PB  - Natl Inst Optoelectronics, Bucharest-Magurele
T2  - Journal of Optoelectronics and Advanced Materials
T1  - Polymer composite films and nanofibers doped with core-shell quantum dots
EP  - 74
IS  - 1-2
SP  - 67
VL  - 22
UR  - https://hdl.handle.net/21.15107/rcub_vinar_9034
ER  - 
@article{
author = "Abozaid, Rouaida Mohamed and Stojanović, Dušica and Radisavljević, Anđela and Sević, Dragutin M. and Rabasović, Maja S. and Radović, I. M. and Radojević, Vesna",
year = "2020",
abstract = "Processing and characterization of polymer nanocomposites based on poly(methyl methacrylate) (PMMA) matrix with embedded core-shell CdSe/ZnS quantum dots were investigated. Nanocomposites were obtained via solution casting and electrospinning. FESEM analysis revealed that the processing with electrospinning enables better dispersion of quantum dots. Time-resolved laser induced fluorescence measurements confirmed uniform size of QDs in fibers with the emission at only one wavelength. Oxidation effects in quantum dots were removed with the use of PMMA as a host, and the core remained active, which was confirmed with FTIR analysis and time-resolved laser induced fluorescence measurements.",
publisher = "Natl Inst Optoelectronics, Bucharest-Magurele",
journal = "Journal of Optoelectronics and Advanced Materials",
title = "Polymer composite films and nanofibers doped with core-shell quantum dots",
pages = "74-67",
number = "1-2",
volume = "22",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9034"
}
Abozaid, R. M., Stojanović, D., Radisavljević, A., Sević, D. M., Rabasović, M. S., Radović, I. M.,& Radojević, V.. (2020). Polymer composite films and nanofibers doped with core-shell quantum dots. in Journal of Optoelectronics and Advanced Materials
Natl Inst Optoelectronics, Bucharest-Magurele., 22(1-2), 67-74.
https://hdl.handle.net/21.15107/rcub_vinar_9034
Abozaid RM, Stojanović D, Radisavljević A, Sević DM, Rabasović MS, Radović IM, Radojević V. Polymer composite films and nanofibers doped with core-shell quantum dots. in Journal of Optoelectronics and Advanced Materials. 2020;22(1-2):67-74.
https://hdl.handle.net/21.15107/rcub_vinar_9034 .
Abozaid, Rouaida Mohamed, Stojanović, Dušica, Radisavljević, Anđela, Sević, Dragutin M., Rabasović, Maja S., Radović, I. M., Radojević, Vesna, "Polymer composite films and nanofibers doped with core-shell quantum dots" in Journal of Optoelectronics and Advanced Materials, 22, no. 1-2 (2020):67-74,
https://hdl.handle.net/21.15107/rcub_vinar_9034 .

Surface optical phonon (SOP) mode in ZnS/Poly (methylmethacrylate) nanocomposites

Ćurčić, Milica; Hadžić, Branka; Gilić, Martina; Radojević, Vesna; Bjelajac, Anđelika; Radović, Ivana; Timotijević, Dejan; Romčević, Maja J.; Trajić, Jelena; Romčević, Nebojša Ž.

(Elsevier, Amsterdam, 2020)

TY  - JOUR
AU  - Ćurčić, Milica
AU  - Hadžić, Branka
AU  - Gilić, Martina
AU  - Radojević, Vesna
AU  - Bjelajac, Anđelika
AU  - Radović, Ivana
AU  - Timotijević, Dejan
AU  - Romčević, Maja J.
AU  - Trajić, Jelena
AU  - Romčević, Nebojša Ž.
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4459
AB  - The polymer nanocomposite ZnS/Poly (methylmethacrylate) was prepared by the solution casting method and its structural and optical properties were investigated using XRD, SEM, TEM, HRTEM, and Raman spectroscopy. The basic material, ZnS, has the cubic structure and its crystallite size was estimated to be 2.3 nm, which implies that a strong confinement regime is in effect. Analysis of Raman spectra was performed using the fitting procedure based on effective medium theory. As a result, the surface optical phonon (SOP) mode was detected. It was found that the shape and position of the SOP mode depend on the type of the composite.
PB  - Elsevier, Amsterdam
T2  - Physica E-Low-Dimensional Systems & Nanostructures
T1  - Surface optical phonon (SOP) mode in ZnS/Poly (methylmethacrylate) nanocomposites
VL  - 115
DO  - 10.1016/j.physe.2019.113708
ER  - 
@article{
author = "Ćurčić, Milica and Hadžić, Branka and Gilić, Martina and Radojević, Vesna and Bjelajac, Anđelika and Radović, Ivana and Timotijević, Dejan and Romčević, Maja J. and Trajić, Jelena and Romčević, Nebojša Ž.",
year = "2020",
abstract = "The polymer nanocomposite ZnS/Poly (methylmethacrylate) was prepared by the solution casting method and its structural and optical properties were investigated using XRD, SEM, TEM, HRTEM, and Raman spectroscopy. The basic material, ZnS, has the cubic structure and its crystallite size was estimated to be 2.3 nm, which implies that a strong confinement regime is in effect. Analysis of Raman spectra was performed using the fitting procedure based on effective medium theory. As a result, the surface optical phonon (SOP) mode was detected. It was found that the shape and position of the SOP mode depend on the type of the composite.",
publisher = "Elsevier, Amsterdam",
journal = "Physica E-Low-Dimensional Systems & Nanostructures",
title = "Surface optical phonon (SOP) mode in ZnS/Poly (methylmethacrylate) nanocomposites",
volume = "115",
doi = "10.1016/j.physe.2019.113708"
}
Ćurčić, M., Hadžić, B., Gilić, M., Radojević, V., Bjelajac, A., Radović, I., Timotijević, D., Romčević, M. J., Trajić, J.,& Romčević, N. Ž.. (2020). Surface optical phonon (SOP) mode in ZnS/Poly (methylmethacrylate) nanocomposites. in Physica E-Low-Dimensional Systems & Nanostructures
Elsevier, Amsterdam., 115.
https://doi.org/10.1016/j.physe.2019.113708
Ćurčić M, Hadžić B, Gilić M, Radojević V, Bjelajac A, Radović I, Timotijević D, Romčević MJ, Trajić J, Romčević NŽ. Surface optical phonon (SOP) mode in ZnS/Poly (methylmethacrylate) nanocomposites. in Physica E-Low-Dimensional Systems & Nanostructures. 2020;115.
doi:10.1016/j.physe.2019.113708 .
Ćurčić, Milica, Hadžić, Branka, Gilić, Martina, Radojević, Vesna, Bjelajac, Anđelika, Radović, Ivana, Timotijević, Dejan, Romčević, Maja J., Trajić, Jelena, Romčević, Nebojša Ž., "Surface optical phonon (SOP) mode in ZnS/Poly (methylmethacrylate) nanocomposites" in Physica E-Low-Dimensional Systems & Nanostructures, 115 (2020),
https://doi.org/10.1016/j.physe.2019.113708 . .
3
1
3

Optimization of modifier deposition on the alumina surface to enhance mechanical properties and cavitation resistance

Ashor, Almabrok A.; Vuksanović, Marija M.; Tomić, Nataša; Petrović, Miloš; Dojčinović, Marina; Volkov-Husović, Tatjana; Radojević, Vesna; Jančić-Heinemann, Radmila

(Springer, New York, 2020)

TY  - JOUR
AU  - Ashor, Almabrok A.
AU  - Vuksanović, Marija M.
AU  - Tomić, Nataša
AU  - Petrović, Miloš
AU  - Dojčinović, Marina
AU  - Volkov-Husović, Tatjana
AU  - Radojević, Vesna
AU  - Jančić-Heinemann, Radmila
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4544
AB  - Composites based on poly(methyl methacrylate), dimethyl itaconate matrix and alumina particles were prepared. Ferrous oxide-doped alumina particles (Al2O3Fe) and commercial alumina nanoparticles (Al(2)O(3)n) modified with (3-aminopropyl)trimethoxysilane (AM) and methyl esters of linseed oil fatty acids (biodiesel-BD) were used as reinforcement. The mechanical properties of the prepared composites, containing 1, 3 and 5 wt% of surface-modified alumina particles, are compared to a neat polymer matrix. The particles were characterized by single-beam Fourier transform infrared spectroscopy, thermogravimetry and differential scanning calorimetry. The mechanical properties of the composites were determined by micro-Vickers hardness and impact testing. The morphology of the surface of the composites exposed to cavitation was observed through a field emission scanning electron microscope. AFM analysis was used to compare surface features seen using the SEM and to interpret the surface degradation properties. The hardness, cavitation resistance and high-impact energy resistance of the composites are better in the case of AM surface modification of alumina fillers, but biodiesel modified particles have comparable mechanical properties and a stabilized Al-O-Si bond that could be important when a composite is exposed to humidity or a wet environment.
PB  - Springer, New York
T2  - Polymer Bulletin
T1  - Optimization of modifier deposition on the alumina surface to enhance mechanical properties and cavitation resistance
EP  - 3620
IS  - 7
SP  - 3603
VL  - 77
DO  - 10.1007/s00289-019-02923-8
ER  - 
@article{
author = "Ashor, Almabrok A. and Vuksanović, Marija M. and Tomić, Nataša and Petrović, Miloš and Dojčinović, Marina and Volkov-Husović, Tatjana and Radojević, Vesna and Jančić-Heinemann, Radmila",
year = "2020",
abstract = "Composites based on poly(methyl methacrylate), dimethyl itaconate matrix and alumina particles were prepared. Ferrous oxide-doped alumina particles (Al2O3Fe) and commercial alumina nanoparticles (Al(2)O(3)n) modified with (3-aminopropyl)trimethoxysilane (AM) and methyl esters of linseed oil fatty acids (biodiesel-BD) were used as reinforcement. The mechanical properties of the prepared composites, containing 1, 3 and 5 wt% of surface-modified alumina particles, are compared to a neat polymer matrix. The particles were characterized by single-beam Fourier transform infrared spectroscopy, thermogravimetry and differential scanning calorimetry. The mechanical properties of the composites were determined by micro-Vickers hardness and impact testing. The morphology of the surface of the composites exposed to cavitation was observed through a field emission scanning electron microscope. AFM analysis was used to compare surface features seen using the SEM and to interpret the surface degradation properties. The hardness, cavitation resistance and high-impact energy resistance of the composites are better in the case of AM surface modification of alumina fillers, but biodiesel modified particles have comparable mechanical properties and a stabilized Al-O-Si bond that could be important when a composite is exposed to humidity or a wet environment.",
publisher = "Springer, New York",
journal = "Polymer Bulletin",
title = "Optimization of modifier deposition on the alumina surface to enhance mechanical properties and cavitation resistance",
pages = "3620-3603",
number = "7",
volume = "77",
doi = "10.1007/s00289-019-02923-8"
}
Ashor, A. A., Vuksanović, M. M., Tomić, N., Petrović, M., Dojčinović, M., Volkov-Husović, T., Radojević, V.,& Jančić-Heinemann, R.. (2020). Optimization of modifier deposition on the alumina surface to enhance mechanical properties and cavitation resistance. in Polymer Bulletin
Springer, New York., 77(7), 3603-3620.
https://doi.org/10.1007/s00289-019-02923-8
Ashor AA, Vuksanović MM, Tomić N, Petrović M, Dojčinović M, Volkov-Husović T, Radojević V, Jančić-Heinemann R. Optimization of modifier deposition on the alumina surface to enhance mechanical properties and cavitation resistance. in Polymer Bulletin. 2020;77(7):3603-3620.
doi:10.1007/s00289-019-02923-8 .
Ashor, Almabrok A., Vuksanović, Marija M., Tomić, Nataša, Petrović, Miloš, Dojčinović, Marina, Volkov-Husović, Tatjana, Radojević, Vesna, Jančić-Heinemann, Radmila, "Optimization of modifier deposition on the alumina surface to enhance mechanical properties and cavitation resistance" in Polymer Bulletin, 77, no. 7 (2020):3603-3620,
https://doi.org/10.1007/s00289-019-02923-8 . .
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6

Basalt-Polyester Hybrid Composite Materials for Demanding Wear Applications

Abusahmin, Faisal; Algellai, Ahmed A.; Tomić, Nataša; Vuksanović, Marija M.; Majstorović, Jelena; Volkov-Husović, Tatjana; Simić, Vladimir; Jančić-Heinemann, Radmila; Toljić, Marinko; Kovacević, Jovan

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2020)

TY  - JOUR
AU  - Abusahmin, Faisal
AU  - Algellai, Ahmed A.
AU  - Tomić, Nataša
AU  - Vuksanović, Marija M.
AU  - Majstorović, Jelena
AU  - Volkov-Husović, Tatjana
AU  - Simić, Vladimir
AU  - Jančić-Heinemann, Radmila
AU  - Toljić, Marinko
AU  - Kovacević, Jovan
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4361
AB  - Basalt as a filler in a polymer-based composite material fulfils the demand of being natural, environment-friendly material for the production of various composite materials. The material could be used as protective layer and the abrasion should be tested in order to evaluate the properties of the material. The cavitation test enables the evaluation of the possible service in conditions that simulate the extensive erosion. The presence of basalt in the matrix improves the resistance to cavitation. The possibility to further improve the material could be obtained using the reinforcement of the matrix itself by incorporation of submicron ceramic particles into the composite. The obtained hybrid composite material with the addition of reinforcement in the matrix further improves the cavitation resistance.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Basalt-Polyester Hybrid Composite Materials for Demanding Wear Applications
EP  - 76
IS  - 1
SP  - 67
VL  - 52
DO  - 10.2298/SOS2001067A
ER  - 
@article{
author = "Abusahmin, Faisal and Algellai, Ahmed A. and Tomić, Nataša and Vuksanović, Marija M. and Majstorović, Jelena and Volkov-Husović, Tatjana and Simić, Vladimir and Jančić-Heinemann, Radmila and Toljić, Marinko and Kovacević, Jovan",
year = "2020",
abstract = "Basalt as a filler in a polymer-based composite material fulfils the demand of being natural, environment-friendly material for the production of various composite materials. The material could be used as protective layer and the abrasion should be tested in order to evaluate the properties of the material. The cavitation test enables the evaluation of the possible service in conditions that simulate the extensive erosion. The presence of basalt in the matrix improves the resistance to cavitation. The possibility to further improve the material could be obtained using the reinforcement of the matrix itself by incorporation of submicron ceramic particles into the composite. The obtained hybrid composite material with the addition of reinforcement in the matrix further improves the cavitation resistance.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Basalt-Polyester Hybrid Composite Materials for Demanding Wear Applications",
pages = "76-67",
number = "1",
volume = "52",
doi = "10.2298/SOS2001067A"
}
Abusahmin, F., Algellai, A. A., Tomić, N., Vuksanović, M. M., Majstorović, J., Volkov-Husović, T., Simić, V., Jančić-Heinemann, R., Toljić, M.,& Kovacević, J.. (2020). Basalt-Polyester Hybrid Composite Materials for Demanding Wear Applications. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 52(1), 67-76.
https://doi.org/10.2298/SOS2001067A
Abusahmin F, Algellai AA, Tomić N, Vuksanović MM, Majstorović J, Volkov-Husović T, Simić V, Jančić-Heinemann R, Toljić M, Kovacević J. Basalt-Polyester Hybrid Composite Materials for Demanding Wear Applications. in Science of Sintering. 2020;52(1):67-76.
doi:10.2298/SOS2001067A .
Abusahmin, Faisal, Algellai, Ahmed A., Tomić, Nataša, Vuksanović, Marija M., Majstorović, Jelena, Volkov-Husović, Tatjana, Simić, Vladimir, Jančić-Heinemann, Radmila, Toljić, Marinko, Kovacević, Jovan, "Basalt-Polyester Hybrid Composite Materials for Demanding Wear Applications" in Science of Sintering, 52, no. 1 (2020):67-76,
https://doi.org/10.2298/SOS2001067A . .
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1
5

Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance

Stojanović, Dušica; Brajović, Ljiljana; Obradović, Vera; Mijailović, Daniel; Dramlić, Dragan; Kojović, Aleksandar; Uskoković, Petar

(Elsevier B.V., 2020)

TY  - JOUR
AU  - Stojanović, Dušica
AU  - Brajović, Ljiljana
AU  - Obradović, Vera
AU  - Mijailović, Daniel
AU  - Dramlić, Dragan
AU  - Kojović, Aleksandar
AU  - Uskoković, Petar
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4454
AB  - The composite nanofibers were used as reinforcement in acrylic polymer for the overall enhancement of thermo-mechanical properties, adhesion between fibers and matrix, and fracture toughness of the final nanocomposite since acrylic materials lack of this feature. So, a good balance between hardness/toughness and transparency is obtained with the addition of poly (vinyl butyral) (PVB) and titania (TiO2) nanofibers simultaneously and controlling their contents. Specifically, when compared to that of pure acrylic polymer, the fracture toughness of the PMMA nanocomposite apparently increased 55% with the addition of 3 wt.% titania nanoparticles, while the produced nanocomposite maintained high transmittance above 75-80% in the visible domain. The transmission spectrum modelling of the reinforced fiber materials and hybrid acrylic composites using Mie scattering theory for different particle sizes and particle content is presented. The calculated transmission coefficients versus wavelength are compared with the experimental ones.
PB  - Elsevier B.V.
T2  - Progress in Organic Coatings
T1  - Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance
SP  - 105437
VL  - 139
DO  - 10.1016/j.porgcoat.2019.105437
ER  - 
@article{
author = "Stojanović, Dušica and Brajović, Ljiljana and Obradović, Vera and Mijailović, Daniel and Dramlić, Dragan and Kojović, Aleksandar and Uskoković, Petar",
year = "2020",
abstract = "The composite nanofibers were used as reinforcement in acrylic polymer for the overall enhancement of thermo-mechanical properties, adhesion between fibers and matrix, and fracture toughness of the final nanocomposite since acrylic materials lack of this feature. So, a good balance between hardness/toughness and transparency is obtained with the addition of poly (vinyl butyral) (PVB) and titania (TiO2) nanofibers simultaneously and controlling their contents. Specifically, when compared to that of pure acrylic polymer, the fracture toughness of the PMMA nanocomposite apparently increased 55% with the addition of 3 wt.% titania nanoparticles, while the produced nanocomposite maintained high transmittance above 75-80% in the visible domain. The transmission spectrum modelling of the reinforced fiber materials and hybrid acrylic composites using Mie scattering theory for different particle sizes and particle content is presented. The calculated transmission coefficients versus wavelength are compared with the experimental ones.",
publisher = "Elsevier B.V.",
journal = "Progress in Organic Coatings",
title = "Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance",
pages = "105437",
volume = "139",
doi = "10.1016/j.porgcoat.2019.105437"
}
Stojanović, D., Brajović, L., Obradović, V., Mijailović, D., Dramlić, D., Kojović, A.,& Uskoković, P.. (2020). Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance. in Progress in Organic Coatings
Elsevier B.V.., 139, 105437.
https://doi.org/10.1016/j.porgcoat.2019.105437
Stojanović D, Brajović L, Obradović V, Mijailović D, Dramlić D, Kojović A, Uskoković P. Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance. in Progress in Organic Coatings. 2020;139:105437.
doi:10.1016/j.porgcoat.2019.105437 .
Stojanović, Dušica, Brajović, Ljiljana, Obradović, Vera, Mijailović, Daniel, Dramlić, Dragan, Kojović, Aleksandar, Uskoković, Petar, "Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance" in Progress in Organic Coatings, 139 (2020):105437,
https://doi.org/10.1016/j.porgcoat.2019.105437 . .
4
5
2
4

Ballistic Composites Reinforced with Inorganic Nanotubes of Tungsten Disulfide

Simić, Danica M.; Stojanović, Dušica B.; Ristović, Novica; Zrilić, Milorad; Burzić, Zijah; Marjanović, Milica; Uskoković, Petar S.; Aleksić, Radoslav

(Springer Nature, 2020)

TY  - CHAP
AU  - Simić, Danica M.
AU  - Stojanović, Dušica B.
AU  - Ristović, Novica
AU  - Zrilić, Milorad
AU  - Burzić, Zijah
AU  - Marjanović, Milica
AU  - Uskoković, Petar S.
AU  - Aleksić, Radoslav
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6672
AB  - This research considers a possibility of improving the impact and ballistic resistance of composite materials based on aramid fabric impregnated with poly (vinyl butyral), PVB, with the application of multi-layer inorganic nanotubes of tungsten disulfide (INT-WS2) as the reinforcement. Multi-layered nano-structures of tungsten disulfide are known by their excellent mechanical resistance, especially shock absorbing properties, which promote their use as a reinforcement in composite materials. INT-WS2 used in this research were observed using scanning electron microscope and the obtained images were analyzed in program Image Pro Plus. Before the application in the composite they were ultrasonically deagglomerated. Ballistic composites were prepared impregnating the aramid fabric with system PVB/INT-WS2 and by pressing defined number of layers under high pressure and defined temperature. Charpy impact test, ballistic shooting with two different ammunition calibers and stab resistance test with controlled knife penetration were performed on prepared composite samples, and resulted in significant improvements for samples with nano-reinforcement regarding the absorbed energy of impact, toughness and the ballistic resistance.
PB  - Springer Nature
T2  - Springer Proceedings in Materials. Advanced Materials for Defense: Development, Analysis and Applications
T1  - Ballistic Composites Reinforced with Inorganic Nanotubes of Tungsten Disulfide
EP  - 43
SP  - 35
VL  - 4
DO  - 10.1007/978-3-030-34123-7_4
ER  - 
@inbook{
author = "Simić, Danica M. and Stojanović, Dušica B. and Ristović, Novica and Zrilić, Milorad and Burzić, Zijah and Marjanović, Milica and Uskoković, Petar S. and Aleksić, Radoslav",
year = "2020",
abstract = "This research considers a possibility of improving the impact and ballistic resistance of composite materials based on aramid fabric impregnated with poly (vinyl butyral), PVB, with the application of multi-layer inorganic nanotubes of tungsten disulfide (INT-WS2) as the reinforcement. Multi-layered nano-structures of tungsten disulfide are known by their excellent mechanical resistance, especially shock absorbing properties, which promote their use as a reinforcement in composite materials. INT-WS2 used in this research were observed using scanning electron microscope and the obtained images were analyzed in program Image Pro Plus. Before the application in the composite they were ultrasonically deagglomerated. Ballistic composites were prepared impregnating the aramid fabric with system PVB/INT-WS2 and by pressing defined number of layers under high pressure and defined temperature. Charpy impact test, ballistic shooting with two different ammunition calibers and stab resistance test with controlled knife penetration were performed on prepared composite samples, and resulted in significant improvements for samples with nano-reinforcement regarding the absorbed energy of impact, toughness and the ballistic resistance.",
publisher = "Springer Nature",
journal = "Springer Proceedings in Materials. Advanced Materials for Defense: Development, Analysis and Applications",
booktitle = "Ballistic Composites Reinforced with Inorganic Nanotubes of Tungsten Disulfide",
pages = "43-35",
volume = "4",
doi = "10.1007/978-3-030-34123-7_4"
}
Simić, D. M., Stojanović, D. B., Ristović, N., Zrilić, M., Burzić, Z., Marjanović, M., Uskoković, P. S.,& Aleksić, R.. (2020). Ballistic Composites Reinforced with Inorganic Nanotubes of Tungsten Disulfide. in Springer Proceedings in Materials. Advanced Materials for Defense: Development, Analysis and Applications
Springer Nature., 4, 35-43.
https://doi.org/10.1007/978-3-030-34123-7_4
Simić DM, Stojanović DB, Ristović N, Zrilić M, Burzić Z, Marjanović M, Uskoković PS, Aleksić R. Ballistic Composites Reinforced with Inorganic Nanotubes of Tungsten Disulfide. in Springer Proceedings in Materials. Advanced Materials for Defense: Development, Analysis and Applications. 2020;4:35-43.
doi:10.1007/978-3-030-34123-7_4 .
Simić, Danica M., Stojanović, Dušica B., Ristović, Novica, Zrilić, Milorad, Burzić, Zijah, Marjanović, Milica, Uskoković, Petar S., Aleksić, Radoslav, "Ballistic Composites Reinforced with Inorganic Nanotubes of Tungsten Disulfide" in Springer Proceedings in Materials. Advanced Materials for Defense: Development, Analysis and Applications, 4 (2020):35-43,
https://doi.org/10.1007/978-3-030-34123-7_4 . .
3
1

Structurally and surface-modified alumina particles as a reinforcement in polyester-based composites with an improved toughness

Drah, Abdusalam; Tomić, Nataša; Kovačević, Tihomir; Đokić, Veljko; Tomić, M.; Jančić-Heinemann, Radmila; Marinković, Aleksandar

(Springer, New York, 2020)

TY  - JOUR
AU  - Drah, Abdusalam
AU  - Tomić, Nataša
AU  - Kovačević, Tihomir
AU  - Đokić, Veljko
AU  - Tomić, M.
AU  - Jančić-Heinemann, Radmila
AU  - Marinković, Aleksandar
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4524
AB  - Commercial gamma - Al2O3 particles, Al2O3 n, and synthesized Al2O3 doped with iron oxide (Al2O3 Fe) were used as reinforcements to enhance the toughness of an unsaturated polyester resin (UPR). Alumina modification with vinyl, Al2O3 (n, Fe)-VT, and methacryloyl, Al2O3 (n, Fe)-ME functionalities contributed to the increase in the extent of covalent binding at the UPR/filler interface. Tensile tests showed a slight improvement in the toughness of UPR/Al2O3 Fe composite and a significant improvement for the UPR/Al2O3 Fe-VT composite at a 1.0 wt.% particle loading. An enhancement in the micro Vickers hardness for UPR/Al2O3 Fe-VT and improved DMA properties were also evidenced.
PB  - Springer, New York
T2  - Mechanics of Composite Materials
T1  - Structurally and surface-modified alumina particles as a reinforcement in polyester-based composites with an improved toughness
EP  - 260
IS  - 2
SP  - 249
VL  - 56
DO  - 10.1007/s11029-020-09877-3
ER  - 
@article{
author = "Drah, Abdusalam and Tomić, Nataša and Kovačević, Tihomir and Đokić, Veljko and Tomić, M. and Jančić-Heinemann, Radmila and Marinković, Aleksandar",
year = "2020",
abstract = "Commercial gamma - Al2O3 particles, Al2O3 n, and synthesized Al2O3 doped with iron oxide (Al2O3 Fe) were used as reinforcements to enhance the toughness of an unsaturated polyester resin (UPR). Alumina modification with vinyl, Al2O3 (n, Fe)-VT, and methacryloyl, Al2O3 (n, Fe)-ME functionalities contributed to the increase in the extent of covalent binding at the UPR/filler interface. Tensile tests showed a slight improvement in the toughness of UPR/Al2O3 Fe composite and a significant improvement for the UPR/Al2O3 Fe-VT composite at a 1.0 wt.% particle loading. An enhancement in the micro Vickers hardness for UPR/Al2O3 Fe-VT and improved DMA properties were also evidenced.",
publisher = "Springer, New York",
journal = "Mechanics of Composite Materials",
title = "Structurally and surface-modified alumina particles as a reinforcement in polyester-based composites with an improved toughness",
pages = "260-249",
number = "2",
volume = "56",
doi = "10.1007/s11029-020-09877-3"
}
Drah, A., Tomić, N., Kovačević, T., Đokić, V., Tomić, M., Jančić-Heinemann, R.,& Marinković, A.. (2020). Structurally and surface-modified alumina particles as a reinforcement in polyester-based composites with an improved toughness. in Mechanics of Composite Materials
Springer, New York., 56(2), 249-260.
https://doi.org/10.1007/s11029-020-09877-3
Drah A, Tomić N, Kovačević T, Đokić V, Tomić M, Jančić-Heinemann R, Marinković A. Structurally and surface-modified alumina particles as a reinforcement in polyester-based composites with an improved toughness. in Mechanics of Composite Materials. 2020;56(2):249-260.
doi:10.1007/s11029-020-09877-3 .
Drah, Abdusalam, Tomić, Nataša, Kovačević, Tihomir, Đokić, Veljko, Tomić, M., Jančić-Heinemann, Radmila, Marinković, Aleksandar, "Structurally and surface-modified alumina particles as a reinforcement in polyester-based composites with an improved toughness" in Mechanics of Composite Materials, 56, no. 2 (2020):249-260,
https://doi.org/10.1007/s11029-020-09877-3 . .
2
2

Structural and surface modification of highly ordered alumina for enhanced removal of Pb2+, Cd2+ and Ni2+ from aqueous solution

Milosević, Dragana L.; Tomić, Nataša; Đokić, Veljko; Vidović, Milka; Veličković, Zlate; Jančić-Heinemann, Radmila; Marinković, Aleksandar

(Desalination Publ, Hopkinton, 2020)

TY  - JOUR
AU  - Milosević, Dragana L.
AU  - Tomić, Nataša
AU  - Đokić, Veljko
AU  - Vidović, Milka
AU  - Veličković, Zlate
AU  - Jančić-Heinemann, Radmila
AU  - Marinković, Aleksandar
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4506
AB  - The adsorption performance of three-dimensionally ordered macroporous (3DOM) alumina doped with iron oxide, and subsequently modified with (3-aminopropyl)triethoxysilane (APTES), FeAl2O3 and FeAl(2)O(3)APTES, was used for enhanced Pb2+, Cd2+ and Ni2+ removal. The phase composition and the structural and surface/textural properties of the obtained adsorbents were analyzed by X-ray diffraction analysis, field emission scanning electron microscope, energy dispersive X-ray analysis, thermogravimetry, Fourier-transfer infrared spectroscopy, specific surface area of the samples and point of zero charge determination. Adsorption of selected cations was examined in the batch conditions using different contact time, adsorbent dosage and temperatures. Different models of the adsorption isotherms were used for determination of the adsorption capacities, in which the best fit of Freundlich and Langmuir model was obtained for FeAl2O3, that is, Freundlich model for FeAl(2)O(3)APTES. A significant increase of adsorption capacities: from 44.21 to 51.66 mg g(-1) for Pb2+, 25.69 to 32.96 mg g(-1) for Cd2+ and 19.48 to 24.64 mg g(-1) for Ni2+ was obtained for FeAl2O3 and FeAl(2)O(3)APTES, respectively, which indicated the significance of the macroporous structure of 3DOM alumina and subsequent amino-terminal modification. The values of the correlation coefficient (R-2) suggested that pseudo-second kinetic model best describes Pb2+, Cd2+ and Ni2+ adsorption on FeAl(2)O(3)APTES, and Cd2+ and Ni2+ onto FeAl2O3, while second kinetic model gave the highest correlation coefficients for Pb2+ adsorption on FeAl2O3.
PB  - Desalination Publ, Hopkinton
T2  - Desalination and Water Treatment
T1  - Structural and surface modification of highly ordered alumina for enhanced removal of Pb2+, Cd2+ and Ni2+ from aqueous solution
EP  - 239
SP  - 220
VL  - 178
DO  - 10.5004/dwt.2020.24982
ER  - 
@article{
author = "Milosević, Dragana L. and Tomić, Nataša and Đokić, Veljko and Vidović, Milka and Veličković, Zlate and Jančić-Heinemann, Radmila and Marinković, Aleksandar",
year = "2020",
abstract = "The adsorption performance of three-dimensionally ordered macroporous (3DOM) alumina doped with iron oxide, and subsequently modified with (3-aminopropyl)triethoxysilane (APTES), FeAl2O3 and FeAl(2)O(3)APTES, was used for enhanced Pb2+, Cd2+ and Ni2+ removal. The phase composition and the structural and surface/textural properties of the obtained adsorbents were analyzed by X-ray diffraction analysis, field emission scanning electron microscope, energy dispersive X-ray analysis, thermogravimetry, Fourier-transfer infrared spectroscopy, specific surface area of the samples and point of zero charge determination. Adsorption of selected cations was examined in the batch conditions using different contact time, adsorbent dosage and temperatures. Different models of the adsorption isotherms were used for determination of the adsorption capacities, in which the best fit of Freundlich and Langmuir model was obtained for FeAl2O3, that is, Freundlich model for FeAl(2)O(3)APTES. A significant increase of adsorption capacities: from 44.21 to 51.66 mg g(-1) for Pb2+, 25.69 to 32.96 mg g(-1) for Cd2+ and 19.48 to 24.64 mg g(-1) for Ni2+ was obtained for FeAl2O3 and FeAl(2)O(3)APTES, respectively, which indicated the significance of the macroporous structure of 3DOM alumina and subsequent amino-terminal modification. The values of the correlation coefficient (R-2) suggested that pseudo-second kinetic model best describes Pb2+, Cd2+ and Ni2+ adsorption on FeAl(2)O(3)APTES, and Cd2+ and Ni2+ onto FeAl2O3, while second kinetic model gave the highest correlation coefficients for Pb2+ adsorption on FeAl2O3.",
publisher = "Desalination Publ, Hopkinton",
journal = "Desalination and Water Treatment",
title = "Structural and surface modification of highly ordered alumina for enhanced removal of Pb2+, Cd2+ and Ni2+ from aqueous solution",
pages = "239-220",
volume = "178",
doi = "10.5004/dwt.2020.24982"
}
Milosević, D. L., Tomić, N., Đokić, V., Vidović, M., Veličković, Z., Jančić-Heinemann, R.,& Marinković, A.. (2020). Structural and surface modification of highly ordered alumina for enhanced removal of Pb2+, Cd2+ and Ni2+ from aqueous solution. in Desalination and Water Treatment
Desalination Publ, Hopkinton., 178, 220-239.
https://doi.org/10.5004/dwt.2020.24982
Milosević DL, Tomić N, Đokić V, Vidović M, Veličković Z, Jančić-Heinemann R, Marinković A. Structural and surface modification of highly ordered alumina for enhanced removal of Pb2+, Cd2+ and Ni2+ from aqueous solution. in Desalination and Water Treatment. 2020;178:220-239.
doi:10.5004/dwt.2020.24982 .
Milosević, Dragana L., Tomić, Nataša, Đokić, Veljko, Vidović, Milka, Veličković, Zlate, Jančić-Heinemann, Radmila, Marinković, Aleksandar, "Structural and surface modification of highly ordered alumina for enhanced removal of Pb2+, Cd2+ and Ni2+ from aqueous solution" in Desalination and Water Treatment, 178 (2020):220-239,
https://doi.org/10.5004/dwt.2020.24982 . .
1
1
1

Image analysis and the finite element method in the characterization of the influence of porosity parameters on the mechanical properties of porous EVA/PMMA polymer blends

Tomić, Nataša; Milanović, Predrag; Međo, Bojan; Vuksanović, Marija M.; Veljović, Đorđe; Rakin, Marko; Jančić-Heinemann, Radmila

(Elsevier Science Bv, Amsterdam, 2019)

TY  - JOUR
AU  - Tomić, Nataša
AU  - Milanović, Predrag
AU  - Međo, Bojan
AU  - Vuksanović, Marija M.
AU  - Veljović, Đorđe
AU  - Rakin, Marko
AU  - Jančić-Heinemann, Radmila
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4155
AB  - Poly(ethylene-co-vinyl acetate) (EVA) and poly(methyl methacrylate) (PMMA) are two incompatible polymers. Compatibilization of EVA/PMMA polymer blends with EVA-g-PMMA decreased the pore diameter and improved the mechanical properties. Image analysis of SEM micrographs enabled statistical analysis of the porosity parameters, including data about their positions. Positioning of the pores on the image was achieved by implementation of Voronoi diagrams and Delaunay triangulation by Python libraries. Hausdorff dimension (DHf) analysis showed improved complexity of the material network obtained by compatibilization. The coordinates of pore contours were processed by the Ramer-Douglas-Peucker algorithm (RDP) to establish the models by the finite element method (FEM). This process is iterative and enables a parametric study of the problem so that the type of pore geometry responsible for the observed mechanical behavior could be revealed. The FEM revealed the regions of the material that bear the load and enabled the extraction of parts of the material that diminish the porosity but do not participate in load carrying. A parametric study showed a decrease of 22% in the maximal shear stress when the porosity increased 10%, suggesting the importance of bulging of the material that played the role in decreasing the porosity of non-bearing material. A procedure for selecting the model with a regular pore shape and distribution based on the actual (irregular) porous microstructure is proposed.
PB  - Elsevier Science Bv, Amsterdam
T2  - Mechanics of Materials
T1  - Image analysis and the finite element method in the characterization of the influence of porosity parameters on the mechanical properties of porous EVA/PMMA polymer blends
EP  - 14
SP  - 1
VL  - 129
DO  - 10.1016/j.mechmat.2018.10.008
ER  - 
@article{
author = "Tomić, Nataša and Milanović, Predrag and Međo, Bojan and Vuksanović, Marija M. and Veljović, Đorđe and Rakin, Marko and Jančić-Heinemann, Radmila",
year = "2019",
abstract = "Poly(ethylene-co-vinyl acetate) (EVA) and poly(methyl methacrylate) (PMMA) are two incompatible polymers. Compatibilization of EVA/PMMA polymer blends with EVA-g-PMMA decreased the pore diameter and improved the mechanical properties. Image analysis of SEM micrographs enabled statistical analysis of the porosity parameters, including data about their positions. Positioning of the pores on the image was achieved by implementation of Voronoi diagrams and Delaunay triangulation by Python libraries. Hausdorff dimension (DHf) analysis showed improved complexity of the material network obtained by compatibilization. The coordinates of pore contours were processed by the Ramer-Douglas-Peucker algorithm (RDP) to establish the models by the finite element method (FEM). This process is iterative and enables a parametric study of the problem so that the type of pore geometry responsible for the observed mechanical behavior could be revealed. The FEM revealed the regions of the material that bear the load and enabled the extraction of parts of the material that diminish the porosity but do not participate in load carrying. A parametric study showed a decrease of 22% in the maximal shear stress when the porosity increased 10%, suggesting the importance of bulging of the material that played the role in decreasing the porosity of non-bearing material. A procedure for selecting the model with a regular pore shape and distribution based on the actual (irregular) porous microstructure is proposed.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Mechanics of Materials",
title = "Image analysis and the finite element method in the characterization of the influence of porosity parameters on the mechanical properties of porous EVA/PMMA polymer blends",
pages = "14-1",
volume = "129",
doi = "10.1016/j.mechmat.2018.10.008"
}
Tomić, N., Milanović, P., Međo, B., Vuksanović, M. M., Veljović, Đ., Rakin, M.,& Jančić-Heinemann, R.. (2019). Image analysis and the finite element method in the characterization of the influence of porosity parameters on the mechanical properties of porous EVA/PMMA polymer blends. in Mechanics of Materials
Elsevier Science Bv, Amsterdam., 129, 1-14.
https://doi.org/10.1016/j.mechmat.2018.10.008
Tomić N, Milanović P, Međo B, Vuksanović MM, Veljović Đ, Rakin M, Jančić-Heinemann R. Image analysis and the finite element method in the characterization of the influence of porosity parameters on the mechanical properties of porous EVA/PMMA polymer blends. in Mechanics of Materials. 2019;129:1-14.
doi:10.1016/j.mechmat.2018.10.008 .
Tomić, Nataša, Milanović, Predrag, Međo, Bojan, Vuksanović, Marija M., Veljović, Đorđe, Rakin, Marko, Jančić-Heinemann, Radmila, "Image analysis and the finite element method in the characterization of the influence of porosity parameters on the mechanical properties of porous EVA/PMMA polymer blends" in Mechanics of Materials, 129 (2019):1-14,
https://doi.org/10.1016/j.mechmat.2018.10.008 . .
4
3
5

Image analysis and the finite element method in the characterization of the influence of porosity parameters on the mechanical properties of porous EVA/PMMA polymer blends

Tomić, Nataša; Milanović, Predrag; Međo, Bojan; Vuksanović, Marija M.; Veljović, Đorđe; Rakin, Marko; Jančić-Heinemann, Radmila

(Elsevier B.V., 2019)

TY  - JOUR
AU  - Tomić, Nataša
AU  - Milanović, Predrag
AU  - Međo, Bojan
AU  - Vuksanović, Marija M.
AU  - Veljović, Đorđe
AU  - Rakin, Marko
AU  - Jančić-Heinemann, Radmila
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5043
AB  - Poly(ethylene-co-vinyl acetate) (EVA) and poly(methyl methacrylate) (PMMA) are two incompatible polymers. Compatibilization of EVA/PMMA polymer blends with EVA-g-PMMA decreased the pore diameter and improved the mechanical properties. Image analysis of SEM micrographs enabled statistical analysis of the porosity parameters, including data about their positions. Positioning of the pores on the image was achieved by implementation of Voronoi diagrams and Delaunay triangulation by Python libraries. Hausdorff dimension (DHf) analysis showed improved complexity of the material network obtained by compatibilization. The coordinates of pore contours were processed by the Ramer–Douglas–Peucker algorithm (RDP) to establish the models by the finite element method (FEM). This process is iterative and enables a parametric study of the problem so that the type of pore geometry responsible for the observed mechanical behavior could be revealed. The FEM revealed the regions of the material that bear the load and enabled the extraction of parts of the material that diminish the porosity but do not participate in load carrying. A parametric study showed a decrease of 22% in the maximal shear stress when the porosity increased 10%, suggesting the importance of bulging of the material that played the role in decreasing the porosity of non-bearing material. A procedure for selecting the model with a regular pore shape and distribution based on the actual (irregular) porous microstructure is proposed.
PB  - Elsevier B.V.
T2  - Mechanics of Materials
T1  - Image analysis and the finite element method in the characterization of the influence of porosity parameters on the mechanical properties of porous EVA/PMMA polymer blends
EP  - 14
SP  - 1
VL  - 129
DO  - 10.1016/j.mechmat.2018.10.008
ER  - 
@article{
author = "Tomić, Nataša and Milanović, Predrag and Međo, Bojan and Vuksanović, Marija M. and Veljović, Đorđe and Rakin, Marko and Jančić-Heinemann, Radmila",
year = "2019",
abstract = "Poly(ethylene-co-vinyl acetate) (EVA) and poly(methyl methacrylate) (PMMA) are two incompatible polymers. Compatibilization of EVA/PMMA polymer blends with EVA-g-PMMA decreased the pore diameter and improved the mechanical properties. Image analysis of SEM micrographs enabled statistical analysis of the porosity parameters, including data about their positions. Positioning of the pores on the image was achieved by implementation of Voronoi diagrams and Delaunay triangulation by Python libraries. Hausdorff dimension (DHf) analysis showed improved complexity of the material network obtained by compatibilization. The coordinates of pore contours were processed by the Ramer–Douglas–Peucker algorithm (RDP) to establish the models by the finite element method (FEM). This process is iterative and enables a parametric study of the problem so that the type of pore geometry responsible for the observed mechanical behavior could be revealed. The FEM revealed the regions of the material that bear the load and enabled the extraction of parts of the material that diminish the porosity but do not participate in load carrying. A parametric study showed a decrease of 22% in the maximal shear stress when the porosity increased 10%, suggesting the importance of bulging of the material that played the role in decreasing the porosity of non-bearing material. A procedure for selecting the model with a regular pore shape and distribution based on the actual (irregular) porous microstructure is proposed.",
publisher = "Elsevier B.V.",
journal = "Mechanics of Materials",
title = "Image analysis and the finite element method in the characterization of the influence of porosity parameters on the mechanical properties of porous EVA/PMMA polymer blends",
pages = "14-1",
volume = "129",
doi = "10.1016/j.mechmat.2018.10.008"
}
Tomić, N., Milanović, P., Međo, B., Vuksanović, M. M., Veljović, Đ., Rakin, M.,& Jančić-Heinemann, R.. (2019). Image analysis and the finite element method in the characterization of the influence of porosity parameters on the mechanical properties of porous EVA/PMMA polymer blends. in Mechanics of Materials
Elsevier B.V.., 129, 1-14.
https://doi.org/10.1016/j.mechmat.2018.10.008
Tomić N, Milanović P, Međo B, Vuksanović MM, Veljović Đ, Rakin M, Jančić-Heinemann R. Image analysis and the finite element method in the characterization of the influence of porosity parameters on the mechanical properties of porous EVA/PMMA polymer blends. in Mechanics of Materials. 2019;129:1-14.
doi:10.1016/j.mechmat.2018.10.008 .
Tomić, Nataša, Milanović, Predrag, Međo, Bojan, Vuksanović, Marija M., Veljović, Đorđe, Rakin, Marko, Jančić-Heinemann, Radmila, "Image analysis and the finite element method in the characterization of the influence of porosity parameters on the mechanical properties of porous EVA/PMMA polymer blends" in Mechanics of Materials, 129 (2019):1-14,
https://doi.org/10.1016/j.mechmat.2018.10.008 . .
4
3
5

Examination of mechanical properties of acrilyc composite materials with different AL2O3 reinforcement by brazil test

Vuksanović, Marija M.; Tomić, Nataša; Algellai, Ahmed A.; Balanč, Bojana; Radovanović, Željko; Trifunović, Dejan; Jančić-Heinemann, Radmila

(Savez inženjera i tehničara Srbije, Beograd, 2019)

TY  - JOUR
AU  - Vuksanović, Marija M.
AU  - Tomić, Nataša
AU  - Algellai, Ahmed A.
AU  - Balanč, Bojana
AU  - Radovanović, Željko
AU  - Trifunović, Dejan
AU  - Jančić-Heinemann, Radmila
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4296
AB  - Composite materials based on UV-curing acrylates and various alumina-based reinforcements represent material that is suitable for the use in dentistry, but also in other areas. Composites were made using four different types of reinforcement of chemically very similar compositions, but different size and morphologies. In order to monitor the mechanical properties of the composite material, samples were made in the form of discs of defined dimensions suitable for polymerization under UV light. The subject of this study is the examination of the mechanical properties of the Bis-GMA (Bisphenol A glycidyl methacrylate)/TEGDMA (trimethylene glycol dimethacrylate) photopolymer composite material as a matrix. The reinforcements were in the form of commercial nanoparticles and alumina whiskers and their influence on mechanical properties were compared with the influence of synthesized alumina particles doped with iron oxide synthesized sol-gel technique. In order to test the mechanical properties of composite materials, the Brazilian Tests and the testing of the microhardness of samples were employed.
AB  - Kompozitni materijali na bazi fotopolimerizujućih akrilata i različitih ojačanja na bazi aluminijum-oksida predstavljaju materijal koji je pogodan za upotrebu u stomatologiji, ali i u drugim oblastima. Kompoziti su napravljeni korišćenjem četiri različita tipa ojačanja hemijski veoma sličnih sastava, ali različite veličine i morfologije. Da bi se pratila mehanička svojstva kompozitnog materijala napravljeni su uzorci u formi diskova definisanih dimenzija pogodni za polimerizaciju pod dejstvom UV svetlosti. Predmet ovog istraživanja je ispitivanje mehaničkih svojstava fotopolimerizujućeg kompozitnog materijala na bazi Bis-GMA (Bisfenol A glicidilmetakrilata)/TEGDMA (trietilen glikol dimetakrilata) kao matrice. Ojačanja su bila u formi komercijalnih nanočestica i viskersa aluminijum-oksida i njihov uticaj na mehanička svojstva upoređen je sa uticajem sintetisanih čestica na bazi aluminijum-oksida dopiranih gvožđe oksidom sintetisanih sol gel tehnikom. Za ispitivanje mehaničkih svojstava kompozitnih materijala korišćen je Brazilski test i ispitivanje tvrdoće uzoraka.
PB  - Savez inženjera i tehničara Srbije, Beograd
T2  - Tehnika
T1  - Examination of mechanical properties of acrilyc composite materials with different AL2O3 reinforcement by brazil test
T1  - Ispitivanje mehaničkih svojstava akrilatnih kompozitnih materijala sa različitim AL2O3 ojačanjima brazilskim testom
EP  - 14
IS  - 1
SP  - 9
VL  - 74
DO  - 10.5937/tehnika1901009V
ER  - 
@article{
author = "Vuksanović, Marija M. and Tomić, Nataša and Algellai, Ahmed A. and Balanč, Bojana and Radovanović, Željko and Trifunović, Dejan and Jančić-Heinemann, Radmila",
year = "2019",
abstract = "Composite materials based on UV-curing acrylates and various alumina-based reinforcements represent material that is suitable for the use in dentistry, but also in other areas. Composites were made using four different types of reinforcement of chemically very similar compositions, but different size and morphologies. In order to monitor the mechanical properties of the composite material, samples were made in the form of discs of defined dimensions suitable for polymerization under UV light. The subject of this study is the examination of the mechanical properties of the Bis-GMA (Bisphenol A glycidyl methacrylate)/TEGDMA (trimethylene glycol dimethacrylate) photopolymer composite material as a matrix. The reinforcements were in the form of commercial nanoparticles and alumina whiskers and their influence on mechanical properties were compared with the influence of synthesized alumina particles doped with iron oxide synthesized sol-gel technique. In order to test the mechanical properties of composite materials, the Brazilian Tests and the testing of the microhardness of samples were employed., Kompozitni materijali na bazi fotopolimerizujućih akrilata i različitih ojačanja na bazi aluminijum-oksida predstavljaju materijal koji je pogodan za upotrebu u stomatologiji, ali i u drugim oblastima. Kompoziti su napravljeni korišćenjem četiri različita tipa ojačanja hemijski veoma sličnih sastava, ali različite veličine i morfologije. Da bi se pratila mehanička svojstva kompozitnog materijala napravljeni su uzorci u formi diskova definisanih dimenzija pogodni za polimerizaciju pod dejstvom UV svetlosti. Predmet ovog istraživanja je ispitivanje mehaničkih svojstava fotopolimerizujućeg kompozitnog materijala na bazi Bis-GMA (Bisfenol A glicidilmetakrilata)/TEGDMA (trietilen glikol dimetakrilata) kao matrice. Ojačanja su bila u formi komercijalnih nanočestica i viskersa aluminijum-oksida i njihov uticaj na mehanička svojstva upoređen je sa uticajem sintetisanih čestica na bazi aluminijum-oksida dopiranih gvožđe oksidom sintetisanih sol gel tehnikom. Za ispitivanje mehaničkih svojstava kompozitnih materijala korišćen je Brazilski test i ispitivanje tvrdoće uzoraka.",
publisher = "Savez inženjera i tehničara Srbije, Beograd",
journal = "Tehnika",
title = "Examination of mechanical properties of acrilyc composite materials with different AL2O3 reinforcement by brazil test, Ispitivanje mehaničkih svojstava akrilatnih kompozitnih materijala sa različitim AL2O3 ojačanjima brazilskim testom",
pages = "14-9",
number = "1",
volume = "74",
doi = "10.5937/tehnika1901009V"
}
Vuksanović, M. M., Tomić, N., Algellai, A. A., Balanč, B., Radovanović, Ž., Trifunović, D.,& Jančić-Heinemann, R.. (2019). Examination of mechanical properties of acrilyc composite materials with different AL2O3 reinforcement by brazil test. in Tehnika
Savez inženjera i tehničara Srbije, Beograd., 74(1), 9-14.
https://doi.org/10.5937/tehnika1901009V
Vuksanović MM, Tomić N, Algellai AA, Balanč B, Radovanović Ž, Trifunović D, Jančić-Heinemann R. Examination of mechanical properties of acrilyc composite materials with different AL2O3 reinforcement by brazil test. in Tehnika. 2019;74(1):9-14.
doi:10.5937/tehnika1901009V .
Vuksanović, Marija M., Tomić, Nataša, Algellai, Ahmed A., Balanč, Bojana, Radovanović, Željko, Trifunović, Dejan, Jančić-Heinemann, Radmila, "Examination of mechanical properties of acrilyc composite materials with different AL2O3 reinforcement by brazil test" in Tehnika, 74, no. 1 (2019):9-14,
https://doi.org/10.5937/tehnika1901009V . .

Synthesis and characterisation of hybrid polymer composite materials based on wood.

Perišić, Srđan

(Univerzitet u Beogradu, Tehnološko-metalurški fakultet, 2019)

TY  - THES
AU  - Perišić, Srđan
PY  - 2019
UR  - http://eteze.bg.ac.rs/application/showtheses?thesesId=6744
UR  - https://fedorabg.bg.ac.rs/fedora/get/o:19594/bdef:Content/download
UR  - http://vbs.rs/scripts/cobiss?command=DISPLAY&base=70036&RID=51334927
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4678
AB  - The focus of this doctoral dissertation is the preparation and characterization of wood-plastic composites (WPC), whereby a new method of obtaining hybrid polymer composites based on wood from solution and forming the final composite by a subsequent unconventional method of thermal processing and pressing is presented. During the workmanship of this doctoral dissertation, the possibilities of synthesis and incorporation of polyethylene teraphthalate (PET) fibers and aluminum oxide (Al2O3) particles in composite materials with a polymeric matrix based on wood were investigated. By adjusting the percentage content of PET fibers and Al2O3 particles during processing, it is possible to influence the mechanical properties of hybrid composites. Poly (methylmethacrylate) (PMMA) was used as the polymer matrix. Based on a detailed literature review, it has been concluded that there is a possibility of modifying wood fibers and polymer matrix by bonding agents (3-mercaptopropyl) trimethoxysilane (MPTMS) and 2,4-toluene diisocyanate (TDI). Also, the polymer matrix acts as a wood fiber impregnator, which is certainly due to the influence of the bonding agents and does not allow the water absorption. The combination of PMMA/wood surface modification and MPET fiber reinforcement (mixture of commercially available and recycled PET in a ratio of 1: 1) and modified Al2O3 particles (MPTMS) in a small percentage (up to 3 wt%) results in composites with advanced mechanical properties and water absorption properties and offers a new way to use recycled PET flakes, and provides the opportunity for further development of incorporation of alumina particles. In order to identify incorporated reinforcements in composites, various analyses were performed, such as scanning electron microscope (FESEM), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction analysis (XRD). These analyses have shown that fibers and particles are well dispersed during the composite processing. In addition, the resistance to moist absorption resistance of the composite was tested. Based on the obtained results, it is concluded that due to well dispersed MPET fibers and Al2O3 particles in the hybrid sample and the realized bonds between the modified particles and the sample, the water absorption was the smallest and amounted to only 1 wt%.
AB  - Fokus ove doktorske disertacije je na pripremi i karakterizaciji drvo-plastičnih kompozita (WPC), pri čemu je predstavljen nov način dobijana hibridnih polimernih kompozita na bazi drveta iz rastvora i formiranje finalnog kompozita naknadnom nekonvencionalnom metodom termičke obrade- presovanjem. U toku izrade ove doktorske disertacije istražene su mogućnosti sinteze i ugradnje različitih polietilen teraftalat (PET) vlakana i aluminijum oksid (Al2O3) čestica u kompozitne materijale sa polimernom matricom na bazi drveta. Podešavanjem procentualnog sadržaja PET vlakana i čestica Al2O3 prilikom procesiranja, moguće je uticati na mehanička svojstva hibridnih kompozita. Kao polimerna matrica korišćen je poli(metilmetakrilat) (PMMA). Na osnovu detaljnog literaturnog pregleda zaključeno je da postoji mogućnost modifikacije drvnih vlakana i polimerne matrice vezujućim agensima (3-merkaptopropil) trimetoksisilanom (MPTMS) i 2,4-toluen diizocijanatom (TDI). Takođe, polimerna matrica se ponaša kao impregnator drvenih vlakana, što je svakako posledica uticaja vezujućih agensa i ne dozvoljava apsorpciju vode. Kombinacija modifikacije površine PMMA/drvo i ojačanje u vidu MPET vlakana (mešavina komercijalno dostupnog i recikliranog PET u odnosu 1:1) i modifikovanih čestica Al2O3 (MPTMS) u malom masenom procentu (do 3 mas%) rezultuje kompozitima sa naprednim mehaničkim svojstvima i svojstima upijanja vode i nudi nov način za upotrebu recikliranih PET ljuspica, i daje mogućnost daljim razvojem inkorporiranja česticama aluminijum oksida. Sa ciljem identifikacije inkorporiranih ojačanja u kompozite, izvršene su različite analize, kao što su skenirajuća elektronska mikroskopija (FESEM), infracrvena spektroskopija sa Furijeovom transformacijom (FTIR) i rendgensko-difraktometrijska analiza (XRD). Navedene analize su pokazale da su vlakna i čestice dobro dispergovani tokom procesiranja kompozita. Pored toga, ispitana je efikasnost rezistentnosti na apsorpciju vlage kompozita. Na osnovu dobijenih rezultata zaključuje se da je zbog dobro dispergovanih MPET vlakna i čestica Al2O3 u hibridnom uzorku i ostvarenih veza između modifikovanih čestica i uzorka, apsorpcija vode najmanja i iznosila je svega 1 mas%.
PB  - Univerzitet u Beogradu, Tehnološko-metalurški fakultet
T1  - Synthesis and characterisation of hybrid polymer composite materials based on wood.
T1  - Sinteza i karakterizacija hibridnih polimernih kompozita na bazi drveta
UR  - https://hdl.handle.net/21.15107/rcub_technorep_4678
ER  - 
@phdthesis{
author = "Perišić, Srđan",
year = "2019",
abstract = "The focus of this doctoral dissertation is the preparation and characterization of wood-plastic composites (WPC), whereby a new method of obtaining hybrid polymer composites based on wood from solution and forming the final composite by a subsequent unconventional method of thermal processing and pressing is presented. During the workmanship of this doctoral dissertation, the possibilities of synthesis and incorporation of polyethylene teraphthalate (PET) fibers and aluminum oxide (Al2O3) particles in composite materials with a polymeric matrix based on wood were investigated. By adjusting the percentage content of PET fibers and Al2O3 particles during processing, it is possible to influence the mechanical properties of hybrid composites. Poly (methylmethacrylate) (PMMA) was used as the polymer matrix. Based on a detailed literature review, it has been concluded that there is a possibility of modifying wood fibers and polymer matrix by bonding agents (3-mercaptopropyl) trimethoxysilane (MPTMS) and 2,4-toluene diisocyanate (TDI). Also, the polymer matrix acts as a wood fiber impregnator, which is certainly due to the influence of the bonding agents and does not allow the water absorption. The combination of PMMA/wood surface modification and MPET fiber reinforcement (mixture of commercially available and recycled PET in a ratio of 1: 1) and modified Al2O3 particles (MPTMS) in a small percentage (up to 3 wt%) results in composites with advanced mechanical properties and water absorption properties and offers a new way to use recycled PET flakes, and provides the opportunity for further development of incorporation of alumina particles. In order to identify incorporated reinforcements in composites, various analyses were performed, such as scanning electron microscope (FESEM), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction analysis (XRD). These analyses have shown that fibers and particles are well dispersed during the composite processing. In addition, the resistance to moist absorption resistance of the composite was tested. Based on the obtained results, it is concluded that due to well dispersed MPET fibers and Al2O3 particles in the hybrid sample and the realized bonds between the modified particles and the sample, the water absorption was the smallest and amounted to only 1 wt%., Fokus ove doktorske disertacije je na pripremi i karakterizaciji drvo-plastičnih kompozita (WPC), pri čemu je predstavljen nov način dobijana hibridnih polimernih kompozita na bazi drveta iz rastvora i formiranje finalnog kompozita naknadnom nekonvencionalnom metodom termičke obrade- presovanjem. U toku izrade ove doktorske disertacije istražene su mogućnosti sinteze i ugradnje različitih polietilen teraftalat (PET) vlakana i aluminijum oksid (Al2O3) čestica u kompozitne materijale sa polimernom matricom na bazi drveta. Podešavanjem procentualnog sadržaja PET vlakana i čestica Al2O3 prilikom procesiranja, moguće je uticati na mehanička svojstva hibridnih kompozita. Kao polimerna matrica korišćen je poli(metilmetakrilat) (PMMA). Na osnovu detaljnog literaturnog pregleda zaključeno je da postoji mogućnost modifikacije drvnih vlakana i polimerne matrice vezujućim agensima (3-merkaptopropil) trimetoksisilanom (MPTMS) i 2,4-toluen diizocijanatom (TDI). Takođe, polimerna matrica se ponaša kao impregnator drvenih vlakana, što je svakako posledica uticaja vezujućih agensa i ne dozvoljava apsorpciju vode. Kombinacija modifikacije površine PMMA/drvo i ojačanje u vidu MPET vlakana (mešavina komercijalno dostupnog i recikliranog PET u odnosu 1:1) i modifikovanih čestica Al2O3 (MPTMS) u malom masenom procentu (do 3 mas%) rezultuje kompozitima sa naprednim mehaničkim svojstvima i svojstima upijanja vode i nudi nov način za upotrebu recikliranih PET ljuspica, i daje mogućnost daljim razvojem inkorporiranja česticama aluminijum oksida. Sa ciljem identifikacije inkorporiranih ojačanja u kompozite, izvršene su različite analize, kao što su skenirajuća elektronska mikroskopija (FESEM), infracrvena spektroskopija sa Furijeovom transformacijom (FTIR) i rendgensko-difraktometrijska analiza (XRD). Navedene analize su pokazale da su vlakna i čestice dobro dispergovani tokom procesiranja kompozita. Pored toga, ispitana je efikasnost rezistentnosti na apsorpciju vlage kompozita. Na osnovu dobijenih rezultata zaključuje se da je zbog dobro dispergovanih MPET vlakna i čestica Al2O3 u hibridnom uzorku i ostvarenih veza između modifikovanih čestica i uzorka, apsorpcija vode najmanja i iznosila je svega 1 mas%.",
publisher = "Univerzitet u Beogradu, Tehnološko-metalurški fakultet",
title = "Synthesis and characterisation of hybrid polymer composite materials based on wood., Sinteza i karakterizacija hibridnih polimernih kompozita na bazi drveta",
url = "https://hdl.handle.net/21.15107/rcub_technorep_4678"
}
Perišić, S.. (2019). Synthesis and characterisation of hybrid polymer composite materials based on wood.. 
Univerzitet u Beogradu, Tehnološko-metalurški fakultet..
https://hdl.handle.net/21.15107/rcub_technorep_4678
Perišić S. Synthesis and characterisation of hybrid polymer composite materials based on wood.. 2019;.
https://hdl.handle.net/21.15107/rcub_technorep_4678 .
Perišić, Srđan, "Synthesis and characterisation of hybrid polymer composite materials based on wood." (2019),
https://hdl.handle.net/21.15107/rcub_technorep_4678 .

Impact of Alumina Particles on the Morphology and Mechanics of Hybrid Wood Plastic Composite Materials

Perišić, Srđan; Vuksanović, Marija M.; Petrović, Miloš; Radisavljević, Anđela; Grujić, Aleksandar; Jančić-Heinemann, Radmila; Radojević, Vesna

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2019)

TY  - JOUR
AU  - Perišić, Srđan
AU  - Vuksanović, Marija M.
AU  - Petrović, Miloš
AU  - Radisavljević, Anđela
AU  - Grujić, Aleksandar
AU  - Jančić-Heinemann, Radmila
AU  - Radojević, Vesna
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4144
AB  - Hybrid composite panels of Wood-Plastic Composites (WPC) consisting of wood and poly (methyl methacrylate) (PMMA) were reinforced with alumina particles and made by "hot pressing" method. Alumina-based particles were made by sol-gel technique. The particles were characterized by the X-ray diffraction (XRD). The resulting alumina particles were modified with (3mercaptopropyl) trimethoxysilane (MPTMS), in order to obtain better mechanical properties of the composite relative to the composite with unmodified alumina particles. The aim of this work was to study the influence of composite structure and the moisture absorption on bending and the impact properties of the hybrid composite. The bending and impact tests revealed that modulus of elasticity and absorbed energy of deformation increased with modification of alumina and slightly decrease after moisture absorption.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Impact of Alumina Particles on the Morphology and Mechanics of Hybrid Wood Plastic Composite Materials
EP  - 124
IS  - 1
SP  - 115
VL  - 51
DO  - 10.2298/SOS1901115P
ER  - 
@article{
author = "Perišić, Srđan and Vuksanović, Marija M. and Petrović, Miloš and Radisavljević, Anđela and Grujić, Aleksandar and Jančić-Heinemann, Radmila and Radojević, Vesna",
year = "2019",
abstract = "Hybrid composite panels of Wood-Plastic Composites (WPC) consisting of wood and poly (methyl methacrylate) (PMMA) were reinforced with alumina particles and made by "hot pressing" method. Alumina-based particles were made by sol-gel technique. The particles were characterized by the X-ray diffraction (XRD). The resulting alumina particles were modified with (3mercaptopropyl) trimethoxysilane (MPTMS), in order to obtain better mechanical properties of the composite relative to the composite with unmodified alumina particles. The aim of this work was to study the influence of composite structure and the moisture absorption on bending and the impact properties of the hybrid composite. The bending and impact tests revealed that modulus of elasticity and absorbed energy of deformation increased with modification of alumina and slightly decrease after moisture absorption.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Impact of Alumina Particles on the Morphology and Mechanics of Hybrid Wood Plastic Composite Materials",
pages = "124-115",
number = "1",
volume = "51",
doi = "10.2298/SOS1901115P"
}
Perišić, S., Vuksanović, M. M., Petrović, M., Radisavljević, A., Grujić, A., Jančić-Heinemann, R.,& Radojević, V.. (2019). Impact of Alumina Particles on the Morphology and Mechanics of Hybrid Wood Plastic Composite Materials. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 51(1), 115-124.
https://doi.org/10.2298/SOS1901115P
Perišić S, Vuksanović MM, Petrović M, Radisavljević A, Grujić A, Jančić-Heinemann R, Radojević V. Impact of Alumina Particles on the Morphology and Mechanics of Hybrid Wood Plastic Composite Materials. in Science of Sintering. 2019;51(1):115-124.
doi:10.2298/SOS1901115P .
Perišić, Srđan, Vuksanović, Marija M., Petrović, Miloš, Radisavljević, Anđela, Grujić, Aleksandar, Jančić-Heinemann, Radmila, Radojević, Vesna, "Impact of Alumina Particles on the Morphology and Mechanics of Hybrid Wood Plastic Composite Materials" in Science of Sintering, 51, no. 1 (2019):115-124,
https://doi.org/10.2298/SOS1901115P . .
4
3
6

The influence of alumina crystal structures on the morphology and surface erosion of PMMA composite materials exposed to cavitation testing

Vuksanović, Marija M.; Tomić, Nataša; Gajić-Kvaščev, Maja; Đokić, Veljko; Dojčinović, Marina; Volkov-Husović, Tatjana; Jančić-Heinemann, Radmila

(Elsevier Science Sa, Lausanne, 2019)

TY  - JOUR
AU  - Vuksanović, Marija M.
AU  - Tomić, Nataša
AU  - Gajić-Kvaščev, Maja
AU  - Đokić, Veljko
AU  - Dojčinović, Marina
AU  - Volkov-Husović, Tatjana
AU  - Jančić-Heinemann, Radmila
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4308
AB  - Composites are materials that reach many users and therefore, it is necessary to correlate the properties of every component on the behaviour of the material. Alumina is used as reinforcement with the aim of improving hardness. It was proven that the hardness depends on the crystal structure of the reinforcement. As the hardness is related to cavitation resistance, the influence of different reinforcements on the composite cavitation resistance was studied. Alumina and iron(III) oxide doped alumina particles were prepared by the sol-gel technique, starting from soluble salts of both elements. The gels were calcined at three different temperatures: 700, 800 and 900 degrees C. Poly(methyl methacrylate), PMMA, was used as the polymer matrix reinforced with alumina particles. The reinforcement content of all the samples was 3 wt %. Cavitation erosion of the samples was measured using a standard ultrasonic vibratory setup with a stationary sample. The cavitation resistance of the samples was studied using the classical mass loss method and the surface defects resulting from cavitation were analyzed. The morphologies of the defects after 1 h of cavitation erosion were examined by field emission scanning electron microscopy (FE-SEM). The images were characterized using the image analysis procedure. The results showed that the alumina crystal structure resulting at different calcination temperatures influences the defect morphology, cavitation resistance and the hardness of the composites.
PB  - Elsevier Science Sa, Lausanne
T2  - Wear
T1  - The influence of alumina crystal structures on the morphology and surface erosion of PMMA composite materials exposed to cavitation testing
VL  - 436
DO  - 10.1016/j.wear.2019.203033
ER  - 
@article{
author = "Vuksanović, Marija M. and Tomić, Nataša and Gajić-Kvaščev, Maja and Đokić, Veljko and Dojčinović, Marina and Volkov-Husović, Tatjana and Jančić-Heinemann, Radmila",
year = "2019",
abstract = "Composites are materials that reach many users and therefore, it is necessary to correlate the properties of every component on the behaviour of the material. Alumina is used as reinforcement with the aim of improving hardness. It was proven that the hardness depends on the crystal structure of the reinforcement. As the hardness is related to cavitation resistance, the influence of different reinforcements on the composite cavitation resistance was studied. Alumina and iron(III) oxide doped alumina particles were prepared by the sol-gel technique, starting from soluble salts of both elements. The gels were calcined at three different temperatures: 700, 800 and 900 degrees C. Poly(methyl methacrylate), PMMA, was used as the polymer matrix reinforced with alumina particles. The reinforcement content of all the samples was 3 wt %. Cavitation erosion of the samples was measured using a standard ultrasonic vibratory setup with a stationary sample. The cavitation resistance of the samples was studied using the classical mass loss method and the surface defects resulting from cavitation were analyzed. The morphologies of the defects after 1 h of cavitation erosion were examined by field emission scanning electron microscopy (FE-SEM). The images were characterized using the image analysis procedure. The results showed that the alumina crystal structure resulting at different calcination temperatures influences the defect morphology, cavitation resistance and the hardness of the composites.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Wear",
title = "The influence of alumina crystal structures on the morphology and surface erosion of PMMA composite materials exposed to cavitation testing",
volume = "436",
doi = "10.1016/j.wear.2019.203033"
}
Vuksanović, M. M., Tomić, N., Gajić-Kvaščev, M., Đokić, V., Dojčinović, M., Volkov-Husović, T.,& Jančić-Heinemann, R.. (2019). The influence of alumina crystal structures on the morphology and surface erosion of PMMA composite materials exposed to cavitation testing. in Wear
Elsevier Science Sa, Lausanne., 436.
https://doi.org/10.1016/j.wear.2019.203033
Vuksanović MM, Tomić N, Gajić-Kvaščev M, Đokić V, Dojčinović M, Volkov-Husović T, Jančić-Heinemann R. The influence of alumina crystal structures on the morphology and surface erosion of PMMA composite materials exposed to cavitation testing. in Wear. 2019;436.
doi:10.1016/j.wear.2019.203033 .
Vuksanović, Marija M., Tomić, Nataša, Gajić-Kvaščev, Maja, Đokić, Veljko, Dojčinović, Marina, Volkov-Husović, Tatjana, Jančić-Heinemann, Radmila, "The influence of alumina crystal structures on the morphology and surface erosion of PMMA composite materials exposed to cavitation testing" in Wear, 436 (2019),
https://doi.org/10.1016/j.wear.2019.203033 . .
6
3
5

Dimethyl Itaconate Modified PMMA - Alumina Fillers Composites With Improved Mechanical Properties

Lazouzi, Gamal; Vuksanović, Marija M.; Tomić, Nataša; Petrović, Miloš; Spasojević, Pavle; Radojević, Vesna; Jančić-Heinemann, Radmila

(Wiley, Hoboken, 2019)

TY  - JOUR
AU  - Lazouzi, Gamal
AU  - Vuksanović, Marija M.
AU  - Tomić, Nataša
AU  - Petrović, Miloš
AU  - Spasojević, Pavle
AU  - Radojević, Vesna
AU  - Jančić-Heinemann, Radmila
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4241
AB  - PMMA poly(methyl methacrylate) has a large spectrum of uses as bone cements, in dentistry as denture base materials and other industrial applications. One of the main drawbacks of these materials is the residual monomer that is proven allergen and irritant. It was shown that addition of dimethyl itaconate (DMI) to the PMMA denture base systems decrease the quantity of residual monomer but, also deteriorate mechanical properties. The addition of alumina fillers in the PMMA/DMI produced composite materials results in improved mechanical properties compared with pure PMMA and additionally reduces the level of residual monomer in the composition. POLYM. COMPOS., 40:1691-1701, 2019.
PB  - Wiley, Hoboken
T2  - Polymer Composites
T1  - Dimethyl Itaconate Modified PMMA - Alumina Fillers Composites With Improved Mechanical Properties
EP  - 1701
IS  - 5
SP  - 1691
VL  - 40
DO  - 10.1002/pc.24952
ER  - 
@article{
author = "Lazouzi, Gamal and Vuksanović, Marija M. and Tomić, Nataša and Petrović, Miloš and Spasojević, Pavle and Radojević, Vesna and Jančić-Heinemann, Radmila",
year = "2019",
abstract = "PMMA poly(methyl methacrylate) has a large spectrum of uses as bone cements, in dentistry as denture base materials and other industrial applications. One of the main drawbacks of these materials is the residual monomer that is proven allergen and irritant. It was shown that addition of dimethyl itaconate (DMI) to the PMMA denture base systems decrease the quantity of residual monomer but, also deteriorate mechanical properties. The addition of alumina fillers in the PMMA/DMI produced composite materials results in improved mechanical properties compared with pure PMMA and additionally reduces the level of residual monomer in the composition. POLYM. COMPOS., 40:1691-1701, 2019.",
publisher = "Wiley, Hoboken",
journal = "Polymer Composites",
title = "Dimethyl Itaconate Modified PMMA - Alumina Fillers Composites With Improved Mechanical Properties",
pages = "1701-1691",
number = "5",
volume = "40",
doi = "10.1002/pc.24952"
}
Lazouzi, G., Vuksanović, M. M., Tomić, N., Petrović, M., Spasojević, P., Radojević, V.,& Jančić-Heinemann, R.. (2019). Dimethyl Itaconate Modified PMMA - Alumina Fillers Composites With Improved Mechanical Properties. in Polymer Composites
Wiley, Hoboken., 40(5), 1691-1701.
https://doi.org/10.1002/pc.24952
Lazouzi G, Vuksanović MM, Tomić N, Petrović M, Spasojević P, Radojević V, Jančić-Heinemann R. Dimethyl Itaconate Modified PMMA - Alumina Fillers Composites With Improved Mechanical Properties. in Polymer Composites. 2019;40(5):1691-1701.
doi:10.1002/pc.24952 .
Lazouzi, Gamal, Vuksanović, Marija M., Tomić, Nataša, Petrović, Miloš, Spasojević, Pavle, Radojević, Vesna, Jančić-Heinemann, Radmila, "Dimethyl Itaconate Modified PMMA - Alumina Fillers Composites With Improved Mechanical Properties" in Polymer Composites, 40, no. 5 (2019):1691-1701,
https://doi.org/10.1002/pc.24952 . .
18
11
17

The influence of alumina particle modification on the adhesion of the polyacrylate matrix composite films and the metal substrate

Ashor, Almabrok A.; Vuksanović, Marija M.; Tomić, Nataša; Marinković, Aleksandar; Jančić-Heinemann, Radmila

(Taylor & Francis Ltd, Abingdon, 2019)

TY  - JOUR
AU  - Ashor, Almabrok A.
AU  - Vuksanović, Marija M.
AU  - Tomić, Nataša
AU  - Marinković, Aleksandar
AU  - Jančić-Heinemann, Radmila
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4325
AB  - Adhesion behavior between the composite films, consisting of UV cured Bis-GMA (Bisphenol A glycidylmethacrylate)/TEGDMA (triethylene glycol dimethacrylate) as a matrix and the ferrous oxide doped alumina particles, Al2O3 Fe, modified with 3-aminopropyl)tri - methoxysilane (AM) and methyl esters of linseed oil fatty acids (biodiesel - BD) used as a reinforcement, and metallic surface was investigated in this study. Al2O3 Fe-BD particles showed pronounced hydrophobicity and hydrolytic stability of alumina surface. Adhesive and mechanical properties of prepared composites, containing 0.5, 1.5 and 3 wt. % of surface modified Al2O3 Fe-AM and Al2O3 Fe-BD particles, were compared to the neat polymer matrix. Adhesion parameter was evaluated using the micro hardness testing method. The comparison of determined contact angle with adhesive parameter, obtained from micro hardness measurements, was discussed in relation to structural effect of reinforcement used.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Composite Interfaces
T1  - The influence of alumina particle modification on the adhesion of the polyacrylate matrix composite films and the metal substrate
EP  - 430
IS  - 5
SP  - 417
VL  - 26
DO  - 10.1080/09276440.2018.1506240
ER  - 
@article{
author = "Ashor, Almabrok A. and Vuksanović, Marija M. and Tomić, Nataša and Marinković, Aleksandar and Jančić-Heinemann, Radmila",
year = "2019",
abstract = "Adhesion behavior between the composite films, consisting of UV cured Bis-GMA (Bisphenol A glycidylmethacrylate)/TEGDMA (triethylene glycol dimethacrylate) as a matrix and the ferrous oxide doped alumina particles, Al2O3 Fe, modified with 3-aminopropyl)tri - methoxysilane (AM) and methyl esters of linseed oil fatty acids (biodiesel - BD) used as a reinforcement, and metallic surface was investigated in this study. Al2O3 Fe-BD particles showed pronounced hydrophobicity and hydrolytic stability of alumina surface. Adhesive and mechanical properties of prepared composites, containing 0.5, 1.5 and 3 wt. % of surface modified Al2O3 Fe-AM and Al2O3 Fe-BD particles, were compared to the neat polymer matrix. Adhesion parameter was evaluated using the micro hardness testing method. The comparison of determined contact angle with adhesive parameter, obtained from micro hardness measurements, was discussed in relation to structural effect of reinforcement used.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Composite Interfaces",
title = "The influence of alumina particle modification on the adhesion of the polyacrylate matrix composite films and the metal substrate",
pages = "430-417",
number = "5",
volume = "26",
doi = "10.1080/09276440.2018.1506240"
}
Ashor, A. A., Vuksanović, M. M., Tomić, N., Marinković, A.,& Jančić-Heinemann, R.. (2019). The influence of alumina particle modification on the adhesion of the polyacrylate matrix composite films and the metal substrate. in Composite Interfaces
Taylor & Francis Ltd, Abingdon., 26(5), 417-430.
https://doi.org/10.1080/09276440.2018.1506240
Ashor AA, Vuksanović MM, Tomić N, Marinković A, Jančić-Heinemann R. The influence of alumina particle modification on the adhesion of the polyacrylate matrix composite films and the metal substrate. in Composite Interfaces. 2019;26(5):417-430.
doi:10.1080/09276440.2018.1506240 .
Ashor, Almabrok A., Vuksanović, Marija M., Tomić, Nataša, Marinković, Aleksandar, Jančić-Heinemann, Radmila, "The influence of alumina particle modification on the adhesion of the polyacrylate matrix composite films and the metal substrate" in Composite Interfaces, 26, no. 5 (2019):417-430,
https://doi.org/10.1080/09276440.2018.1506240 . .
10
10
11

Optimizacija procesa prečišćavanja otpadnih voda iz Fabrike streljačke municije Uzići

Jovanović, Aleksandar; Kovačina, Jovanka N.; Marinković, Aleksandar; Onjia, Antonije; Povrenović, Dragan; Trišović, Tomislav

(University of Belgrade, Faculty of Technology and Metallurgy, 2019)


                                            

                                            
Jovanović, A., Kovačina, J. N., Marinković, A., Onjia, A., Povrenović, D.,& Trišović, T.. (2019). Optimizacija procesa prečišćavanja otpadnih voda iz Fabrike streljačke municije Uzići. 
University of Belgrade, Faculty of Technology and Metallurgy..
https://hdl.handle.net/21.15107/rcub_technorep_4176
Jovanović A, Kovačina JN, Marinković A, Onjia A, Povrenović D, Trišović T. Optimizacija procesa prečišćavanja otpadnih voda iz Fabrike streljačke municije Uzići. 2019;.
https://hdl.handle.net/21.15107/rcub_technorep_4176 .
Jovanović, Aleksandar, Kovačina, Jovanka N., Marinković, Aleksandar, Onjia, Antonije, Povrenović, Dragan, Trišović, Tomislav, "Optimizacija procesa prečišćavanja otpadnih voda iz Fabrike streljačke municije Uzići" (2019),
https://hdl.handle.net/21.15107/rcub_technorep_4176 .

Razvoj novih antikorozivnih organo-metalnih jedinjenja na bazi Cerijuma za primenu u alkidnim premazima

Marinković, Aleksandar; Tomić, Nataša; Vuksanović, Marija M.; Kovačina, Jovanka N.; Marunkić, Dunja D.; Milošević, Milena D.; Perendija, Jovana

(Univerzitet u Beogradu, Tehnološko-metalurški fakultet, 2019)


                                            

                                            
Marinković, A., Tomić, N., Vuksanović, M. M., Kovačina, J. N., Marunkić, D. D., Milošević, M. D.,& Perendija, J.. (2019). Razvoj novih antikorozivnih organo-metalnih jedinjenja na bazi Cerijuma za primenu u alkidnim premazima. 
Univerzitet u Beogradu, Tehnološko-metalurški fakultet..
https://hdl.handle.net/21.15107/rcub_technorep_4148
Marinković A, Tomić N, Vuksanović MM, Kovačina JN, Marunkić DD, Milošević MD, Perendija J. Razvoj novih antikorozivnih organo-metalnih jedinjenja na bazi Cerijuma za primenu u alkidnim premazima. 2019;.
https://hdl.handle.net/21.15107/rcub_technorep_4148 .
Marinković, Aleksandar, Tomić, Nataša, Vuksanović, Marija M., Kovačina, Jovanka N., Marunkić, Dunja D., Milošević, Milena D., Perendija, Jovana, "Razvoj novih antikorozivnih organo-metalnih jedinjenja na bazi Cerijuma za primenu u alkidnim premazima" (2019),
https://hdl.handle.net/21.15107/rcub_technorep_4148 .

Optical properties and fluorescence of quantum dots CdSe/ZnS-PMMA composite films with interface modifications

Abozaid, Rouaida Mohamed; Lazarević, Zorica Ž.; Radović, Ivana; Gilić, Martina; Sević, Dragutin M.; Rabasović, Maja S.; Radojević, Vesna

(Elsevier Science Bv, Amsterdam, 2019)

TY  - JOUR
AU  - Abozaid, Rouaida Mohamed
AU  - Lazarević, Zorica Ž.
AU  - Radović, Ivana
AU  - Gilić, Martina
AU  - Sević, Dragutin M.
AU  - Rabasović, Maja S.
AU  - Radojević, Vesna
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4225
AB  - Processing and characterization of polymer nanocomposites based on poly (methyl methacrylate) (PMMA) matrix with embedded core-shell CdSe/ZnS quantum dots (QD's) were presented in this work. The aim is to preserve the optical activity of QD's in nanocomposite processing with improved mechanical properties. The modification of QD's CdSe/ZnS-PMMA interface was achieved with 3-mercaptopropyltrimethoxysilane (MPTMS). Nanocomposites were processed by solution casting. The samples of pure PMMA, and composites with unmodified and silane modified QD's CdSe/ZnS were processed. FTIR analysis revealed modification of QD's with silane and characteristic bonding with PMMA matrix. Raman spectrum confirms a presence of alloyed layer at the core-shell interface. Time-resolved laser induced fluorescence measurements confirmed slight blue shift in QD's CdSe/ZnS-PMMA composite without interface modification, while there was a slight red shift with modified particles. Oxidation effects in quantum dots were removed with the use of PMMA as a host, and the core remained active, which was confirmed with FTIR analysis and time-resolved laser induced fluorescence measurements.
PB  - Elsevier Science Bv, Amsterdam
T2  - Optical Materials
T1  - Optical properties and fluorescence of quantum dots CdSe/ZnS-PMMA composite films with interface modifications
EP  - 410
SP  - 405
VL  - 92
DO  - 10.1016/j.optmat.2019.05.012
ER  - 
@article{
author = "Abozaid, Rouaida Mohamed and Lazarević, Zorica Ž. and Radović, Ivana and Gilić, Martina and Sević, Dragutin M. and Rabasović, Maja S. and Radojević, Vesna",
year = "2019",
abstract = "Processing and characterization of polymer nanocomposites based on poly (methyl methacrylate) (PMMA) matrix with embedded core-shell CdSe/ZnS quantum dots (QD's) were presented in this work. The aim is to preserve the optical activity of QD's in nanocomposite processing with improved mechanical properties. The modification of QD's CdSe/ZnS-PMMA interface was achieved with 3-mercaptopropyltrimethoxysilane (MPTMS). Nanocomposites were processed by solution casting. The samples of pure PMMA, and composites with unmodified and silane modified QD's CdSe/ZnS were processed. FTIR analysis revealed modification of QD's with silane and characteristic bonding with PMMA matrix. Raman spectrum confirms a presence of alloyed layer at the core-shell interface. Time-resolved laser induced fluorescence measurements confirmed slight blue shift in QD's CdSe/ZnS-PMMA composite without interface modification, while there was a slight red shift with modified particles. Oxidation effects in quantum dots were removed with the use of PMMA as a host, and the core remained active, which was confirmed with FTIR analysis and time-resolved laser induced fluorescence measurements.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Optical Materials",
title = "Optical properties and fluorescence of quantum dots CdSe/ZnS-PMMA composite films with interface modifications",
pages = "410-405",
volume = "92",
doi = "10.1016/j.optmat.2019.05.012"
}
Abozaid, R. M., Lazarević, Z. Ž., Radović, I., Gilić, M., Sević, D. M., Rabasović, M. S.,& Radojević, V.. (2019). Optical properties and fluorescence of quantum dots CdSe/ZnS-PMMA composite films with interface modifications. in Optical Materials
Elsevier Science Bv, Amsterdam., 92, 405-410.
https://doi.org/10.1016/j.optmat.2019.05.012
Abozaid RM, Lazarević ZŽ, Radović I, Gilić M, Sević DM, Rabasović MS, Radojević V. Optical properties and fluorescence of quantum dots CdSe/ZnS-PMMA composite films with interface modifications. in Optical Materials. 2019;92:405-410.
doi:10.1016/j.optmat.2019.05.012 .
Abozaid, Rouaida Mohamed, Lazarević, Zorica Ž., Radović, Ivana, Gilić, Martina, Sević, Dragutin M., Rabasović, Maja S., Radojević, Vesna, "Optical properties and fluorescence of quantum dots CdSe/ZnS-PMMA composite films with interface modifications" in Optical Materials, 92 (2019):405-410,
https://doi.org/10.1016/j.optmat.2019.05.012 . .
33
13
27

Artificial Neural Network for Composite Hardness Modeling of Cu/Si Systems Fabricated Using Various Electrodeposition Parameters

Mladenović, Ivana; Lamovec, Jelena; Jović, Vesna; Obradov, M.; Radulović, Katarina; Vasiljević-Radović, Dana; Radojević, Vesna

(IEEE, Electron Devices Soc & Reliability Group, New York, 2019)

TY  - CONF
AU  - Mladenović, Ivana
AU  - Lamovec, Jelena
AU  - Jović, Vesna
AU  - Obradov, M.
AU  - Radulović, Katarina
AU  - Vasiljević-Radović, Dana
AU  - Radojević, Vesna
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4228
AB  - Copper coatings are produced on silicon wafer by electrodeposition (ED) for various cathode current densities. The resulting composite systems consist of 10 mu m monolavered copper films electrodeposited from sulphate bath on Si wafers with sputtered layers of Cr/Au. Hardness measurements were performed to evaluate properties of the composites. The composite hardness (H-c) was characterized using Vickers microindentation test. Then, an artificial neural network (ANN) model was used to study the relationship between the parameters of metallic composite and their hardness. Two experimental values: applied load during indentation test and current density during the ED process were used as the inputs to the neural network. Finally, the results of the composite hardness (experimental and predicted) were used to estimate the film hardness (H-f) of copper for each variations of the current density. This article shows that ANN is an useful tool in modeling composite hardness change with variation of experimental parameters predicting hardness change of composite Si/Cu with average error of 6 %. Using created ANN model it is possible to predict microhardness of Cu film for current density or indentation load for which we do not have experimental data.
PB  - IEEE, Electron Devices Soc & Reliability Group, New York
C3  - 2019 IEEE 31st International Conference on Microelectronics (MIEL 2019)
T1  - Artificial Neural Network for Composite Hardness Modeling of Cu/Si Systems Fabricated Using Various Electrodeposition Parameters
EP  - 136
SP  - 133
UR  - https://hdl.handle.net/21.15107/rcub_technorep_4228
ER  - 
@conference{
author = "Mladenović, Ivana and Lamovec, Jelena and Jović, Vesna and Obradov, M. and Radulović, Katarina and Vasiljević-Radović, Dana and Radojević, Vesna",
year = "2019",
abstract = "Copper coatings are produced on silicon wafer by electrodeposition (ED) for various cathode current densities. The resulting composite systems consist of 10 mu m monolavered copper films electrodeposited from sulphate bath on Si wafers with sputtered layers of Cr/Au. Hardness measurements were performed to evaluate properties of the composites. The composite hardness (H-c) was characterized using Vickers microindentation test. Then, an artificial neural network (ANN) model was used to study the relationship between the parameters of metallic composite and their hardness. Two experimental values: applied load during indentation test and current density during the ED process were used as the inputs to the neural network. Finally, the results of the composite hardness (experimental and predicted) were used to estimate the film hardness (H-f) of copper for each variations of the current density. This article shows that ANN is an useful tool in modeling composite hardness change with variation of experimental parameters predicting hardness change of composite Si/Cu with average error of 6 %. Using created ANN model it is possible to predict microhardness of Cu film for current density or indentation load for which we do not have experimental data.",
publisher = "IEEE, Electron Devices Soc & Reliability Group, New York",
journal = "2019 IEEE 31st International Conference on Microelectronics (MIEL 2019)",
title = "Artificial Neural Network for Composite Hardness Modeling of Cu/Si Systems Fabricated Using Various Electrodeposition Parameters",
pages = "136-133",
url = "https://hdl.handle.net/21.15107/rcub_technorep_4228"
}
Mladenović, I., Lamovec, J., Jović, V., Obradov, M., Radulović, K., Vasiljević-Radović, D.,& Radojević, V.. (2019). Artificial Neural Network for Composite Hardness Modeling of Cu/Si Systems Fabricated Using Various Electrodeposition Parameters. in 2019 IEEE 31st International Conference on Microelectronics (MIEL 2019)
IEEE, Electron Devices Soc & Reliability Group, New York., 133-136.
https://hdl.handle.net/21.15107/rcub_technorep_4228
Mladenović I, Lamovec J, Jović V, Obradov M, Radulović K, Vasiljević-Radović D, Radojević V. Artificial Neural Network for Composite Hardness Modeling of Cu/Si Systems Fabricated Using Various Electrodeposition Parameters. in 2019 IEEE 31st International Conference on Microelectronics (MIEL 2019). 2019;:133-136.
https://hdl.handle.net/21.15107/rcub_technorep_4228 .
Mladenović, Ivana, Lamovec, Jelena, Jović, Vesna, Obradov, M., Radulović, Katarina, Vasiljević-Radović, Dana, Radojević, Vesna, "Artificial Neural Network for Composite Hardness Modeling of Cu/Si Systems Fabricated Using Various Electrodeposition Parameters" in 2019 IEEE 31st International Conference on Microelectronics (MIEL 2019) (2019):133-136,
https://hdl.handle.net/21.15107/rcub_technorep_4228 .

Hardness and assessment of adhesion of monolayer and multilayer nickel thin films electrochemically deposited on silicon substrates with and without the ultrasonic agitation

Lamovec, Jelena; Jović, Vesna; Jaćimovski, Stevo; Jovanov, Goran; Radojević, Vesna; Šetrajčić, Jovan

(Academy of Criminalistic and Police Studies, Belgrade, 2019)

TY  - JOUR
AU  - Lamovec, Jelena
AU  - Jović, Vesna
AU  - Jaćimovski, Stevo
AU  - Jovanov, Goran
AU  - Radojević, Vesna
AU  - Šetrajčić, Jovan
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4292
AB  - Composite systems of monolayer and multilayer nickel films electrochemically deposited on single crystal (100)-oriented silicon wafers were fabricated with and without the ultrasonic agitation. The hardness and adhesion behaviour of these composite structures were characterized by Vickers microindentation test. The dependence of composite microhardness and film adhesion on the structure of the film and mixing conditions of electrolyte were analysed. Mathematical models of Chicot-Lesage and Chen-Gao were applied to experimental data in order to obtain the film hardness and adhesion parameter respectively. It is confirmed that the mechanical properties of composite systems of nickel thin films on silicon substrate can be enhanced by formation of multilayer film structure by ultrasound-assisted electro-deposition and by reducing the layer thickness in the multilayer film.
AB  - Formirani su kompozitni sistemi od jednoslojnih i višeslojnih filmova nikla elektrohemijski deponovanih sa i bez ultrazvučnog mešanja na pločicama od monokristalnog silicijuma orijentacije (100). Tvrdoća i adhezija tih kompozitnih struktura su okarakterisane testom mikrotvrdoće po Vikersu. Analizirana je zavisnost mikrotvrdoće kompozita i adhezije filma od strukture filma i uslova mešanja elektrolita. Matematički modeli Šiko-Lezaža i Čen-Gaoa su primenjeni na eksperimentalne podatke kako bi se dobile vrednosti tvrdoće filma i parametra adhezije. Potvrđeno je da se mehanička svojstva kompozitnih sistema sastavljenih od tankih filmova nikla na silicijumskoj podlozi mogu poboljšati formiranjem višeslojne strukture filmova, primenom ultrazvučnog mešanja pri elektrodepoziciji i smanjenjem debljine sloja u višeslojnom filmu.
PB  - Academy of Criminalistic and Police Studies, Belgrade
T2  - NBP. Nauka, bezbednost, policija
T1  - Hardness and assessment of adhesion of monolayer and multilayer nickel thin films electrochemically deposited on silicon substrates with and without the ultrasonic agitation
T1  - Tvrdoća i procena adhezije jednoslojnih i višeslojnih tankih filmova nikla elektrohemijski deponovanih na silicijumskim podlogama sa i bez ultrazvučnog mešanja
EP  - 29
IS  - 1
SP  - 17
VL  - 24
DO  - 10.5937/nabepo24-19682
ER  - 
@article{
author = "Lamovec, Jelena and Jović, Vesna and Jaćimovski, Stevo and Jovanov, Goran and Radojević, Vesna and Šetrajčić, Jovan",
year = "2019",
abstract = "Composite systems of monolayer and multilayer nickel films electrochemically deposited on single crystal (100)-oriented silicon wafers were fabricated with and without the ultrasonic agitation. The hardness and adhesion behaviour of these composite structures were characterized by Vickers microindentation test. The dependence of composite microhardness and film adhesion on the structure of the film and mixing conditions of electrolyte were analysed. Mathematical models of Chicot-Lesage and Chen-Gao were applied to experimental data in order to obtain the film hardness and adhesion parameter respectively. It is confirmed that the mechanical properties of composite systems of nickel thin films on silicon substrate can be enhanced by formation of multilayer film structure by ultrasound-assisted electro-deposition and by reducing the layer thickness in the multilayer film., Formirani su kompozitni sistemi od jednoslojnih i višeslojnih filmova nikla elektrohemijski deponovanih sa i bez ultrazvučnog mešanja na pločicama od monokristalnog silicijuma orijentacije (100). Tvrdoća i adhezija tih kompozitnih struktura su okarakterisane testom mikrotvrdoće po Vikersu. Analizirana je zavisnost mikrotvrdoće kompozita i adhezije filma od strukture filma i uslova mešanja elektrolita. Matematički modeli Šiko-Lezaža i Čen-Gaoa su primenjeni na eksperimentalne podatke kako bi se dobile vrednosti tvrdoće filma i parametra adhezije. Potvrđeno je da se mehanička svojstva kompozitnih sistema sastavljenih od tankih filmova nikla na silicijumskoj podlozi mogu poboljšati formiranjem višeslojne strukture filmova, primenom ultrazvučnog mešanja pri elektrodepoziciji i smanjenjem debljine sloja u višeslojnom filmu.",
publisher = "Academy of Criminalistic and Police Studies, Belgrade",
journal = "NBP. Nauka, bezbednost, policija",
title = "Hardness and assessment of adhesion of monolayer and multilayer nickel thin films electrochemically deposited on silicon substrates with and without the ultrasonic agitation, Tvrdoća i procena adhezije jednoslojnih i višeslojnih tankih filmova nikla elektrohemijski deponovanih na silicijumskim podlogama sa i bez ultrazvučnog mešanja",
pages = "29-17",
number = "1",
volume = "24",
doi = "10.5937/nabepo24-19682"
}
Lamovec, J., Jović, V., Jaćimovski, S., Jovanov, G., Radojević, V.,& Šetrajčić, J.. (2019). Hardness and assessment of adhesion of monolayer and multilayer nickel thin films electrochemically deposited on silicon substrates with and without the ultrasonic agitation. in NBP. Nauka, bezbednost, policija
Academy of Criminalistic and Police Studies, Belgrade., 24(1), 17-29.
https://doi.org/10.5937/nabepo24-19682
Lamovec J, Jović V, Jaćimovski S, Jovanov G, Radojević V, Šetrajčić J. Hardness and assessment of adhesion of monolayer and multilayer nickel thin films electrochemically deposited on silicon substrates with and without the ultrasonic agitation. in NBP. Nauka, bezbednost, policija. 2019;24(1):17-29.
doi:10.5937/nabepo24-19682 .
Lamovec, Jelena, Jović, Vesna, Jaćimovski, Stevo, Jovanov, Goran, Radojević, Vesna, Šetrajčić, Jovan, "Hardness and assessment of adhesion of monolayer and multilayer nickel thin films electrochemically deposited on silicon substrates with and without the ultrasonic agitation" in NBP. Nauka, bezbednost, policija, 24, no. 1 (2019):17-29,
https://doi.org/10.5937/nabepo24-19682 . .

Artificial Neural Network for Composite Hardness Modeling of Cu/Si Systems Fabricated Using Various Electrodeposition Parameters

Mladenović, Ivana; Lamovec, Jelena; Jović, Vesna; Obradov, M.; Radulović, Katarina; Vasiljević-Radović, Dana; Radojević, Vesna

(Institute of Electrical and Electronics Engineers (IEEE), 2019)

TY  - CONF
AU  - Mladenović, Ivana
AU  - Lamovec, Jelena
AU  - Jović, Vesna
AU  - Obradov, M.
AU  - Radulović, Katarina
AU  - Vasiljević-Radović, Dana
AU  - Radojević, Vesna
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4186
AB  - Copper coatings are produced on silicon wafer by electrodeposition (ED) for various cathode current densities. The resulting composite systems consist of 10 μm monolayered copper films electrodeposited from sulphate bath on Si wafers with sputtered layers of Cr/Au. Hardness measurements were performed to evaluate properties of the composites. The composite hardness (H c ) was characterized using Vickers microindentation test. Then, an artificial neural network (ANN) model was used to study the relationship between the parameters of metallic composite and their hardness. Two experimental values: applied load during indentation test and current density during the ED process were used as the inputs to the neural network. Finally, the results of the composite hardness (experimental and predicted) were used to estimate the film hardness (H f ) of copper for each variations of the current density. This article shows that ANN is an useful tool in modeling composite hardness change with variation of experimental parameters predicting hardness change of composite Si/Cu with average error of 6 %. Using created ANN model it is possible to predict microhardness of Cu film for current density or indentation load for which we do not have experimental data.
PB  - Institute of Electrical and Electronics Engineers (IEEE)
C3  - 2019 IEEE 31st International Conference on Microelectronics, MIEL 2019 - Proceedings
T1  - Artificial Neural Network for Composite Hardness Modeling of Cu/Si Systems Fabricated Using Various Electrodeposition Parameters
EP  - 136
SP  - 133
DO  - 10.1109/MIEL.2019.8889610
ER  - 
@conference{
author = "Mladenović, Ivana and Lamovec, Jelena and Jović, Vesna and Obradov, M. and Radulović, Katarina and Vasiljević-Radović, Dana and Radojević, Vesna",
year = "2019",
abstract = "Copper coatings are produced on silicon wafer by electrodeposition (ED) for various cathode current densities. The resulting composite systems consist of 10 μm monolayered copper films electrodeposited from sulphate bath on Si wafers with sputtered layers of Cr/Au. Hardness measurements were performed to evaluate properties of the composites. The composite hardness (H c ) was characterized using Vickers microindentation test. Then, an artificial neural network (ANN) model was used to study the relationship between the parameters of metallic composite and their hardness. Two experimental values: applied load during indentation test and current density during the ED process were used as the inputs to the neural network. Finally, the results of the composite hardness (experimental and predicted) were used to estimate the film hardness (H f ) of copper for each variations of the current density. This article shows that ANN is an useful tool in modeling composite hardness change with variation of experimental parameters predicting hardness change of composite Si/Cu with average error of 6 %. Using created ANN model it is possible to predict microhardness of Cu film for current density or indentation load for which we do not have experimental data.",
publisher = "Institute of Electrical and Electronics Engineers (IEEE)",
journal = "2019 IEEE 31st International Conference on Microelectronics, MIEL 2019 - Proceedings",
title = "Artificial Neural Network for Composite Hardness Modeling of Cu/Si Systems Fabricated Using Various Electrodeposition Parameters",
pages = "136-133",
doi = "10.1109/MIEL.2019.8889610"
}
Mladenović, I., Lamovec, J., Jović, V., Obradov, M., Radulović, K., Vasiljević-Radović, D.,& Radojević, V.. (2019). Artificial Neural Network for Composite Hardness Modeling of Cu/Si Systems Fabricated Using Various Electrodeposition Parameters. in 2019 IEEE 31st International Conference on Microelectronics, MIEL 2019 - Proceedings
Institute of Electrical and Electronics Engineers (IEEE)., 133-136.
https://doi.org/10.1109/MIEL.2019.8889610
Mladenović I, Lamovec J, Jović V, Obradov M, Radulović K, Vasiljević-Radović D, Radojević V. Artificial Neural Network for Composite Hardness Modeling of Cu/Si Systems Fabricated Using Various Electrodeposition Parameters. in 2019 IEEE 31st International Conference on Microelectronics, MIEL 2019 - Proceedings. 2019;:133-136.
doi:10.1109/MIEL.2019.8889610 .
Mladenović, Ivana, Lamovec, Jelena, Jović, Vesna, Obradov, M., Radulović, Katarina, Vasiljević-Radović, Dana, Radojević, Vesna, "Artificial Neural Network for Composite Hardness Modeling of Cu/Si Systems Fabricated Using Various Electrodeposition Parameters" in 2019 IEEE 31st International Conference on Microelectronics, MIEL 2019 - Proceedings (2019):133-136,
https://doi.org/10.1109/MIEL.2019.8889610 . .
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Photocatalytic Degradation of Bisphenol A with alpha-Fe2O3 Fibers and Particles

Tomić, Nataša; Vuksanović, Marija M.; Veljović, Đorđe; Đokić, Veljko; Marinković, Aleksandar; Jančić-Heinemann, Radmila

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2019)

TY  - JOUR
AU  - Tomić, Nataša
AU  - Vuksanović, Marija M.
AU  - Veljović, Đorđe
AU  - Đokić, Veljko
AU  - Marinković, Aleksandar
AU  - Jančić-Heinemann, Radmila
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4103
AB  - Two-step synthesis of Fe2O3 particles, performed by precipitation from iron(III) chloride (FeCl3 center dot 6H(2)O) using ammonium hydroxide in first step and calcination at 400 and 700 degrees C during 4 h, provided Fe2O3 400 degrees C and Fe2O3 700 degrees C photocatalysts, respectively. The electrospinning process was used to prepare iron oxide fibers, named Fe2O3 fiber. Morphological and structural properties of samples were determined by Scanning Electron Microscopy (SEM), X-ray diffraction (XRD), Fourier Transform Infra-Red (FT-IR) and BET/BJH analysis. It was found that the alpha-Fe2O3 phase (hematite) has shown the compaction of the structure at 700 degrees C, i.e. lower textural properties. Hematite particles and fibers are used for bisphenol A (BPA) removal by photocatalytic decomposition and the enhanced catalytic performance was found with the use of Fe2O3 400 degrees C particles.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Photocatalytic Degradation of Bisphenol A with alpha-Fe2O3 Fibers and Particles
EP  - 276
IS  - 3
SP  - 265
VL  - 51
DO  - 10.2298/SOS1903265T
ER  - 
@article{
author = "Tomić, Nataša and Vuksanović, Marija M. and Veljović, Đorđe and Đokić, Veljko and Marinković, Aleksandar and Jančić-Heinemann, Radmila",
year = "2019",
abstract = "Two-step synthesis of Fe2O3 particles, performed by precipitation from iron(III) chloride (FeCl3 center dot 6H(2)O) using ammonium hydroxide in first step and calcination at 400 and 700 degrees C during 4 h, provided Fe2O3 400 degrees C and Fe2O3 700 degrees C photocatalysts, respectively. The electrospinning process was used to prepare iron oxide fibers, named Fe2O3 fiber. Morphological and structural properties of samples were determined by Scanning Electron Microscopy (SEM), X-ray diffraction (XRD), Fourier Transform Infra-Red (FT-IR) and BET/BJH analysis. It was found that the alpha-Fe2O3 phase (hematite) has shown the compaction of the structure at 700 degrees C, i.e. lower textural properties. Hematite particles and fibers are used for bisphenol A (BPA) removal by photocatalytic decomposition and the enhanced catalytic performance was found with the use of Fe2O3 400 degrees C particles.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Photocatalytic Degradation of Bisphenol A with alpha-Fe2O3 Fibers and Particles",
pages = "276-265",
number = "3",
volume = "51",
doi = "10.2298/SOS1903265T"
}
Tomić, N., Vuksanović, M. M., Veljović, Đ., Đokić, V., Marinković, A.,& Jančić-Heinemann, R.. (2019). Photocatalytic Degradation of Bisphenol A with alpha-Fe2O3 Fibers and Particles. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 51(3), 265-276.
https://doi.org/10.2298/SOS1903265T
Tomić N, Vuksanović MM, Veljović Đ, Đokić V, Marinković A, Jančić-Heinemann R. Photocatalytic Degradation of Bisphenol A with alpha-Fe2O3 Fibers and Particles. in Science of Sintering. 2019;51(3):265-276.
doi:10.2298/SOS1903265T .
Tomić, Nataša, Vuksanović, Marija M., Veljović, Đorđe, Đokić, Veljko, Marinković, Aleksandar, Jančić-Heinemann, Radmila, "Photocatalytic Degradation of Bisphenol A with alpha-Fe2O3 Fibers and Particles" in Science of Sintering, 51, no. 3 (2019):265-276,
https://doi.org/10.2298/SOS1903265T . .
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Synthesis and characterization of nanocrystalline polyhedral oligo silsesquioxanes (POSS) with cross-linkable functionalities

Tomić, Nataša; Vuksanović, Marija M.; Đokić, Veljko; Mitrić, Miodrag; Simić, Milena R.; Pavlović, Vladimir B.; Jančić-Heinemann, Radmila; Marinković, Aleksandar

(Pergamon-Elsevier Science Ltd, Oxford, 2019)

TY  - JOUR
AU  - Tomić, Nataša
AU  - Vuksanović, Marija M.
AU  - Đokić, Veljko
AU  - Mitrić, Miodrag
AU  - Simić, Milena R.
AU  - Pavlović, Vladimir B.
AU  - Jančić-Heinemann, Radmila
AU  - Marinković, Aleksandar
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4121
AB  - A facile synthesis was employed for three polyhedral oligo silsequioxanes (POSS), obtaining incompletely condensed structures with fern-like and cubic morphologies. Proton nuclear magnetic resonance spectroscopy (H-1 NMR) indicated the successful synthesis of the proposed POSS structures. The hydroxyl groups affected the manner and type of POSS morphology, as seen under a scanning electron microscope (SEM) and a transmission electron microscope (TEM). Fourier-transform infrared spectroscopy (FTIR) showed the availability of surface hydroxyl groups that contributed to the formation of a higher amount of char residue, as found from TGA analysis. The highest decomposition temperature (281 degrees C) and the least char residue were found for a cross-linkable POSS, obtained by esterification of the hydroxyl groups with methacryloyl chloride.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Synthesis and characterization of nanocrystalline polyhedral oligo silsesquioxanes (POSS) with cross-linkable functionalities
EP  - 304
SP  - 299
VL  - 171
DO  - 10.1016/j.poly.2019.06.059
ER  - 
@article{
author = "Tomić, Nataša and Vuksanović, Marija M. and Đokić, Veljko and Mitrić, Miodrag and Simić, Milena R. and Pavlović, Vladimir B. and Jančić-Heinemann, Radmila and Marinković, Aleksandar",
year = "2019",
abstract = "A facile synthesis was employed for three polyhedral oligo silsequioxanes (POSS), obtaining incompletely condensed structures with fern-like and cubic morphologies. Proton nuclear magnetic resonance spectroscopy (H-1 NMR) indicated the successful synthesis of the proposed POSS structures. The hydroxyl groups affected the manner and type of POSS morphology, as seen under a scanning electron microscope (SEM) and a transmission electron microscope (TEM). Fourier-transform infrared spectroscopy (FTIR) showed the availability of surface hydroxyl groups that contributed to the formation of a higher amount of char residue, as found from TGA analysis. The highest decomposition temperature (281 degrees C) and the least char residue were found for a cross-linkable POSS, obtained by esterification of the hydroxyl groups with methacryloyl chloride.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Synthesis and characterization of nanocrystalline polyhedral oligo silsesquioxanes (POSS) with cross-linkable functionalities",
pages = "304-299",
volume = "171",
doi = "10.1016/j.poly.2019.06.059"
}
Tomić, N., Vuksanović, M. M., Đokić, V., Mitrić, M., Simić, M. R., Pavlović, V. B., Jančić-Heinemann, R.,& Marinković, A.. (2019). Synthesis and characterization of nanocrystalline polyhedral oligo silsesquioxanes (POSS) with cross-linkable functionalities. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford., 171, 299-304.
https://doi.org/10.1016/j.poly.2019.06.059
Tomić N, Vuksanović MM, Đokić V, Mitrić M, Simić MR, Pavlović VB, Jančić-Heinemann R, Marinković A. Synthesis and characterization of nanocrystalline polyhedral oligo silsesquioxanes (POSS) with cross-linkable functionalities. in Polyhedron. 2019;171:299-304.
doi:10.1016/j.poly.2019.06.059 .
Tomić, Nataša, Vuksanović, Marija M., Đokić, Veljko, Mitrić, Miodrag, Simić, Milena R., Pavlović, Vladimir B., Jančić-Heinemann, Radmila, Marinković, Aleksandar, "Synthesis and characterization of nanocrystalline polyhedral oligo silsesquioxanes (POSS) with cross-linkable functionalities" in Polyhedron, 171 (2019):299-304,
https://doi.org/10.1016/j.poly.2019.06.059 . .
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