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Bis(2,2 '-bipyridine)-bis(mu(3)-phthalato)-dicopper(II) tetrahydrate as molecular sieve with zero-dimensional structure
dc.creator | Zdravković, Jelena D. | |
dc.creator | Poleti, Dejan | |
dc.creator | Rogan, Jelena | |
dc.creator | Minić, Dragica M. | |
dc.date.accessioned | 2021-03-10T12:24:09Z | |
dc.date.available | 2021-03-10T12:24:09Z | |
dc.date.issued | 2014 | |
dc.identifier.issn | 0277-5387 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2660 | |
dc.description.abstract | Crystal structure of the title compound: [Cu-2(bipy)(2)(pht)(2)]center dot 4H(2)O (bipy = 2,2'-bipyridine, pht = dianion of phthalic acid), CuBP center dot 4H(2)O, consists of dinuclear entities, which are further connected by pi-pi stacking interactions between bipy ligands. In this way small channels (micropores) oriented parallel to the [001] direction and containing loosely hydrogen bonded water molecules are formed. The structural changes during dehydration-rehydration have been thoroughly investigated using TG/DSC analysis, FT-IR spectroscopy, X-ray powder diffraction, optical and scanning electron microscopy, and sorption experiments. In addition, dehydration process was analyzed from the aspect of kinetics. A complete reversibility of the dehydration-rehydration CuBP center dot 4H(2)O(s) reversible arrow CuBP(s) + 4H(2)O(g) process was confirmed by all means. Therefore, CuBP center dot 4H(2)O can be classified as molecular sieve with quite unexpected zero-dimensional structure. | en |
dc.publisher | Pergamon-Elsevier Science Ltd, Oxford | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45007/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172015/RS// | |
dc.rights | restrictedAccess | |
dc.source | Polyhedron | |
dc.subject | Cu(II) complex | en |
dc.subject | Phthalate ion | en |
dc.subject | Crystal structure | en |
dc.subject | Reversible dehydration | en |
dc.subject | Molecular sieve | en |
dc.title | Bis(2,2 '-bipyridine)-bis(mu(3)-phthalato)-dicopper(II) tetrahydrate as molecular sieve with zero-dimensional structure | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 264 | |
dc.citation.other | 80: 256-264 | |
dc.citation.rank | M22 | |
dc.citation.spage | 256 | |
dc.citation.volume | 80 | |
dc.identifier.doi | 10.1016/j.poly.2014.05.026 | |
dc.identifier.scopus | 2-s2.0-84905512902 | |
dc.identifier.wos | 000341348300034 | |
dc.type.version | publishedVersion |