dc.creator | Radovanović, Lidija | |
dc.creator | Rogan, Jelena | |
dc.creator | Poleti, Dejan | |
dc.creator | Rodić, Marko V. | |
dc.creator | Jagličić, Zvonko | |
dc.date.accessioned | 2021-03-10T13:48:45Z | |
dc.date.available | 2021-03-10T13:48:45Z | |
dc.date.issued | 2018 | |
dc.identifier.issn | 1318-0207 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3969 | |
dc.description.abstract | Two new isostructural M(II) (M = Ni, Co) complexes with 2,2'-dipyridylamine (dipya) and dianion of terephthalic acid (H-2 tpht), [M(dipya) (2)(H2O)(2)](tpht) center dot 2H(2)O, have been synthesized by ligand exchange reaction and characterized by single-crystal X-ray diffraction, FTIR spectroscopy, TG/DSC analysis and magnetic measurements. The crystal structures of [M(dipya)(2)(H2O)(2)](tpht) center dot 2H(2)O consist of discrete complex units in which M(II) adopts deformed octahedral geometries. Two dipya ligands and two water molecules are coordinated to M(II) atom, tpht acts as a counter ion, while additional two water molecules remained uncoordinated. By numerous hydrogen bonds, all structural fragments are connected in three different chains which extend along [100], [010] and [001] directions, giving as a result a complex 3D network. The stabilization of 3D structure is accomplished by non-covalent face to face pi-pi interactions among pyridyl ring of dipya and benzene ring of tpht from adjacent chains. Towards the applied magnetic field, the both complexes exhibited almost perfect paramagnetic behavior. | en |
dc.publisher | Slovensko Kemijsko Drustvo | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45007/RS// | |
dc.relation | Slovenian Research AgencySlovenian Research Agency - Slovenia [P2-0348] | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.source | Acta Chimica Slovenica | |
dc.subject | Co(II) | en |
dc.subject | Ni(II) | en |
dc.subject | 1,4-benzenedicarboxylate | en |
dc.subject | discrete complex | en |
dc.subject | magnetism | en |
dc.title | Diaquabis(2,2'-dipyridylamine) M(II) Terephthalate Dihydrates, M(II) = Ni, Co: Synthesis, Crystal Structures, Thermal and Magnetic Properties | en |
dc.type | article | |
dc.rights.license | BY | |
dc.citation.epage | 198 | |
dc.citation.issue | 1 | |
dc.citation.other | 65(1): 191-198 | |
dc.citation.rank | M23 | |
dc.citation.spage | 191 | |
dc.citation.volume | 65 | |
dc.identifier.doi | 10.17344/acsi.2017.3813 | |
dc.identifier.fulltext | http://TechnoRep.tmf.bg.ac.rs/bitstream/id/9859/3813-28473-1-PB.pdf | |
dc.identifier.pmid | 29562104 | |
dc.identifier.scopus | 2-s2.0-85044390339 | |
dc.identifier.wos | 000428179900021 | |
dc.type.version | publishedVersion | |