Alkylation of N-substituted 2-phenylacetamides: Benzylation of N-(4-nitrophenyl)-2-phenylacetamide
Alkilovanje N-supstituisanih 2-fenilacetamida - benzilovanje N-(4-nitrofenil)-2-fenilacetamida
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
N-(4-Nitrophenyl)-2-phenylacetamide was alkylated with benzyl chloride in the presence of powdered potassium hydroxide at different temperatures and in various solvents in order to establish the reactivity and orientation in the reaction. The reactions were also carried out in the presence of different phase-transfer catalysts in toluene. Product formation was followed by GC. The obtained results were compared to the results of the benzylation of other N-substituted 2-phenylacetamides, especially of N-phenyl-2-phenylacetamide.
N-(4-Nitrofenil)-2-fenilacetamid je alkilovan benzil-hloridom u različitim rastvarač ima u prisustvu sprašenog kalijum-hidroksida na različitim temperaturama. Reakcije su izvođene u prisustvu različitih međufaznih katalizatora kao i bez katalizatora u cilju ispitivanja uticaja reakcionih uslova na reaktivnost i orijentaciju reakcije alkilovanja ispitivanog jedinjenja.
Кључне речи:
alkylation / benzylation / 2-phenylacetamides / phase-transfer catalysisИзвор:
Journal of the Serbian Chemical Society, 2002, 67, 6, 373-379Издавач:
- Serbian Chemical Society, Belgrade
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Janković, Vida D. AU - Mijin, Dušan AU - Petrović, Slobodan PY - 2002 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/451 AB - N-(4-Nitrophenyl)-2-phenylacetamide was alkylated with benzyl chloride in the presence of powdered potassium hydroxide at different temperatures and in various solvents in order to establish the reactivity and orientation in the reaction. The reactions were also carried out in the presence of different phase-transfer catalysts in toluene. Product formation was followed by GC. The obtained results were compared to the results of the benzylation of other N-substituted 2-phenylacetamides, especially of N-phenyl-2-phenylacetamide. AB - N-(4-Nitrofenil)-2-fenilacetamid je alkilovan benzil-hloridom u različitim rastvarač ima u prisustvu sprašenog kalijum-hidroksida na različitim temperaturama. Reakcije su izvođene u prisustvu različitih međufaznih katalizatora kao i bez katalizatora u cilju ispitivanja uticaja reakcionih uslova na reaktivnost i orijentaciju reakcije alkilovanja ispitivanog jedinjenja. PB - Serbian Chemical Society, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Alkylation of N-substituted 2-phenylacetamides: Benzylation of N-(4-nitrophenyl)-2-phenylacetamide T1 - Alkilovanje N-supstituisanih 2-fenilacetamida - benzilovanje N-(4-nitrofenil)-2-fenilacetamida EP - 379 IS - 6 SP - 373 VL - 67 UR - https://hdl.handle.net/21.15107/rcub_technorep_451 ER -
@article{ author = "Janković, Vida D. and Mijin, Dušan and Petrović, Slobodan", year = "2002", abstract = "N-(4-Nitrophenyl)-2-phenylacetamide was alkylated with benzyl chloride in the presence of powdered potassium hydroxide at different temperatures and in various solvents in order to establish the reactivity and orientation in the reaction. The reactions were also carried out in the presence of different phase-transfer catalysts in toluene. Product formation was followed by GC. The obtained results were compared to the results of the benzylation of other N-substituted 2-phenylacetamides, especially of N-phenyl-2-phenylacetamide., N-(4-Nitrofenil)-2-fenilacetamid je alkilovan benzil-hloridom u različitim rastvarač ima u prisustvu sprašenog kalijum-hidroksida na različitim temperaturama. Reakcije su izvođene u prisustvu različitih međufaznih katalizatora kao i bez katalizatora u cilju ispitivanja uticaja reakcionih uslova na reaktivnost i orijentaciju reakcije alkilovanja ispitivanog jedinjenja.", publisher = "Serbian Chemical Society, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Alkylation of N-substituted 2-phenylacetamides: Benzylation of N-(4-nitrophenyl)-2-phenylacetamide, Alkilovanje N-supstituisanih 2-fenilacetamida - benzilovanje N-(4-nitrofenil)-2-fenilacetamida", pages = "379-373", number = "6", volume = "67", url = "https://hdl.handle.net/21.15107/rcub_technorep_451" }
Janković, V. D., Mijin, D.,& Petrović, S.. (2002). Alkylation of N-substituted 2-phenylacetamides: Benzylation of N-(4-nitrophenyl)-2-phenylacetamide. in Journal of the Serbian Chemical Society Serbian Chemical Society, Belgrade., 67(6), 373-379. https://hdl.handle.net/21.15107/rcub_technorep_451
Janković VD, Mijin D, Petrović S. Alkylation of N-substituted 2-phenylacetamides: Benzylation of N-(4-nitrophenyl)-2-phenylacetamide. in Journal of the Serbian Chemical Society. 2002;67(6):373-379. https://hdl.handle.net/21.15107/rcub_technorep_451 .
Janković, Vida D., Mijin, Dušan, Petrović, Slobodan, "Alkylation of N-substituted 2-phenylacetamides: Benzylation of N-(4-nitrophenyl)-2-phenylacetamide" in Journal of the Serbian Chemical Society, 67, no. 6 (2002):373-379, https://hdl.handle.net/21.15107/rcub_technorep_451 .