Crystal structure of a new zigzag chain Cu(II) complex with terephthalato and 1,10-phenonthroline ligands, [Cu(C8H4O4)(C12H8N2)(H2O)]n
Kristalna struktura novog Lančastog cik-cak Cu(II) kompleksa sa tereftalato i 1,10-fenantrolin ligandima, [Cu(C8H4O4)(C12H8N2)(H2O)]n
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X-Ray crystal structure analysis of the complex [Cu(tpth)(phen)(H2O)]n, where tpht is the dianion of terephthalic acid and phen is 1,10-phenanthroline showed that two crystallographically different, but chemically identical tpht ions with monodentately coordinated COO groups exist; both tpht ions act as bridging ligands forming zigzag chains. The Cu(II) ions are in a deformed trigonal bipyramidal environment consisting of two N atoms from phen, two O atoms from different tpht ligands and one O atom from coordinated H2O molecule. The crystal data are as follows: C20H14CuN2O5, Mr = 425.87 triclinic system, space group P 1, a = 9.007(5), b = 10.557(5), c = 11.554(5) Å, α= 114.343(5), β = 92.942(5), γ = 114.516(5) º, V = 877.3(7) Å3, Z = 2 F(000) = 434, ρx = 1.612 g cm-3, μ = 1.281 mm-1, R1 = 0.0280 for 4363 reflections with I gt 2σ(I), wR2 = 0.0785 for 5104 independent reflections and 254 refined parameters. Some of data were compared with isostructural Co(II) and Zn(II) complexes havin...g the same ligands.
Rendgenska strukturna analiza kompleksa [Cu(tpht)(phen)(H2O)]n, gde je tpht anjon tereftalne kiseline i phen je 1,10-fenantrolin, pokazala je da postoje dva kristalografski nezavisna, a hemijski identična tpht-jona, sa monodentatno koordiniranim COO-grupama; oba tpht-jona ponašaju se kao mostovni ligandi formirajući cik-cak lance. Cu(II)-joni su u deformisanom trigonalno-bipiramidalnom okruženju koje čine dva atoma N iz phen, dva atoma O iz različitih tpht-liganada i jedan atom O iz koordiniranog molekula H2O. Kristalografski podaci su sledeći: C20H14CuN2O5, Mr = 425,87, triklinični sistem, prostorna grupa P 1, a = 9,007(5), b = 10,557(5), c = 11,554(5) Å, α = 114,343(5), β = 92,942(5), γ = 114,516(5) º, V = 877,3(7) Å3, Z = 2, F(000) = 434, ρx = 1,612 g cm-3, μ = 1,281 mm-1, R1 = 0,0280 za 4363 refleksija sa I gt 2 σ(I), wR2 = 0,0785 za 5104 nezavisnih refleksija i 254 utačnjavana parametra. Neki podaci su upoređeni sa izostrukturnim Co(II) i Zn(II) kompleksima sa istim ligandima.
Кључне речи:
transition metal complexes / copper(II) / terephthalate ions / 1,10-phenanthroline / crystal structureИзвор:
Journal of the Serbian Chemical Society, 2004, 69, 5, 353-362Издавач:
- Serbian Chemical Society
DOI: 10.2298/JSC0405353R
ISSN: 0352-5139
WoS: 000221481800006
Scopus: 2-s2.0-2642520438
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Rogan, Jelena AU - Poleti, Dejan AU - Karanović, Ljiljana PY - 2004 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/611 AB - X-Ray crystal structure analysis of the complex [Cu(tpth)(phen)(H2O)]n, where tpht is the dianion of terephthalic acid and phen is 1,10-phenanthroline showed that two crystallographically different, but chemically identical tpht ions with monodentately coordinated COO groups exist; both tpht ions act as bridging ligands forming zigzag chains. The Cu(II) ions are in a deformed trigonal bipyramidal environment consisting of two N atoms from phen, two O atoms from different tpht ligands and one O atom from coordinated H2O molecule. The crystal data are as follows: C20H14CuN2O5, Mr = 425.87 triclinic system, space group P 1, a = 9.007(5), b = 10.557(5), c = 11.554(5) Å, α= 114.343(5), β = 92.942(5), γ = 114.516(5) º, V = 877.3(7) Å3, Z = 2 F(000) = 434, ρx = 1.612 g cm-3, μ = 1.281 mm-1, R1 = 0.0280 for 4363 reflections with I gt 2σ(I), wR2 = 0.0785 for 5104 independent reflections and 254 refined parameters. Some of data were compared with isostructural Co(II) and Zn(II) complexes having the same ligands. AB - Rendgenska strukturna analiza kompleksa [Cu(tpht)(phen)(H2O)]n, gde je tpht anjon tereftalne kiseline i phen je 1,10-fenantrolin, pokazala je da postoje dva kristalografski nezavisna, a hemijski identična tpht-jona, sa monodentatno koordiniranim COO-grupama; oba tpht-jona ponašaju se kao mostovni ligandi formirajući cik-cak lance. Cu(II)-joni su u deformisanom trigonalno-bipiramidalnom okruženju koje čine dva atoma N iz phen, dva atoma O iz različitih tpht-liganada i jedan atom O iz koordiniranog molekula H2O. Kristalografski podaci su sledeći: C20H14CuN2O5, Mr = 425,87, triklinični sistem, prostorna grupa P 1, a = 9,007(5), b = 10,557(5), c = 11,554(5) Å, α = 114,343(5), β = 92,942(5), γ = 114,516(5) º, V = 877,3(7) Å3, Z = 2, F(000) = 434, ρx = 1,612 g cm-3, μ = 1,281 mm-1, R1 = 0,0280 za 4363 refleksija sa I gt 2 σ(I), wR2 = 0,0785 za 5104 nezavisnih refleksija i 254 utačnjavana parametra. Neki podaci su upoređeni sa izostrukturnim Co(II) i Zn(II) kompleksima sa istim ligandima. PB - Serbian Chemical Society T2 - Journal of the Serbian Chemical Society T1 - Crystal structure of a new zigzag chain Cu(II) complex with terephthalato and 1,10-phenonthroline ligands, [Cu(C8H4O4)(C12H8N2)(H2O)]n T1 - Kristalna struktura novog Lančastog cik-cak Cu(II) kompleksa sa tereftalato i 1,10-fenantrolin ligandima, [Cu(C8H4O4)(C12H8N2)(H2O)]n EP - 362 IS - 5 SP - 353 VL - 69 DO - 10.2298/JSC0405353R UR - https://hdl.handle.net/21.15107/rcub_technorep_611 ER -
@article{ author = "Rogan, Jelena and Poleti, Dejan and Karanović, Ljiljana", year = "2004", abstract = "X-Ray crystal structure analysis of the complex [Cu(tpth)(phen)(H2O)]n, where tpht is the dianion of terephthalic acid and phen is 1,10-phenanthroline showed that two crystallographically different, but chemically identical tpht ions with monodentately coordinated COO groups exist; both tpht ions act as bridging ligands forming zigzag chains. The Cu(II) ions are in a deformed trigonal bipyramidal environment consisting of two N atoms from phen, two O atoms from different tpht ligands and one O atom from coordinated H2O molecule. The crystal data are as follows: C20H14CuN2O5, Mr = 425.87 triclinic system, space group P 1, a = 9.007(5), b = 10.557(5), c = 11.554(5) Å, α= 114.343(5), β = 92.942(5), γ = 114.516(5) º, V = 877.3(7) Å3, Z = 2 F(000) = 434, ρx = 1.612 g cm-3, μ = 1.281 mm-1, R1 = 0.0280 for 4363 reflections with I gt 2σ(I), wR2 = 0.0785 for 5104 independent reflections and 254 refined parameters. Some of data were compared with isostructural Co(II) and Zn(II) complexes having the same ligands., Rendgenska strukturna analiza kompleksa [Cu(tpht)(phen)(H2O)]n, gde je tpht anjon tereftalne kiseline i phen je 1,10-fenantrolin, pokazala je da postoje dva kristalografski nezavisna, a hemijski identična tpht-jona, sa monodentatno koordiniranim COO-grupama; oba tpht-jona ponašaju se kao mostovni ligandi formirajući cik-cak lance. Cu(II)-joni su u deformisanom trigonalno-bipiramidalnom okruženju koje čine dva atoma N iz phen, dva atoma O iz različitih tpht-liganada i jedan atom O iz koordiniranog molekula H2O. Kristalografski podaci su sledeći: C20H14CuN2O5, Mr = 425,87, triklinični sistem, prostorna grupa P 1, a = 9,007(5), b = 10,557(5), c = 11,554(5) Å, α = 114,343(5), β = 92,942(5), γ = 114,516(5) º, V = 877,3(7) Å3, Z = 2, F(000) = 434, ρx = 1,612 g cm-3, μ = 1,281 mm-1, R1 = 0,0280 za 4363 refleksija sa I gt 2 σ(I), wR2 = 0,0785 za 5104 nezavisnih refleksija i 254 utačnjavana parametra. Neki podaci su upoređeni sa izostrukturnim Co(II) i Zn(II) kompleksima sa istim ligandima.", publisher = "Serbian Chemical Society", journal = "Journal of the Serbian Chemical Society", title = "Crystal structure of a new zigzag chain Cu(II) complex with terephthalato and 1,10-phenonthroline ligands, [Cu(C8H4O4)(C12H8N2)(H2O)]n, Kristalna struktura novog Lančastog cik-cak Cu(II) kompleksa sa tereftalato i 1,10-fenantrolin ligandima, [Cu(C8H4O4)(C12H8N2)(H2O)]n", pages = "362-353", number = "5", volume = "69", doi = "10.2298/JSC0405353R", url = "https://hdl.handle.net/21.15107/rcub_technorep_611" }
Rogan, J., Poleti, D.,& Karanović, L.. (2004). Crystal structure of a new zigzag chain Cu(II) complex with terephthalato and 1,10-phenonthroline ligands, [Cu(C8H4O4)(C12H8N2)(H2O)]n. in Journal of the Serbian Chemical Society Serbian Chemical Society., 69(5), 353-362. https://doi.org/10.2298/JSC0405353R https://hdl.handle.net/21.15107/rcub_technorep_611
Rogan J, Poleti D, Karanović L. Crystal structure of a new zigzag chain Cu(II) complex with terephthalato and 1,10-phenonthroline ligands, [Cu(C8H4O4)(C12H8N2)(H2O)]n. in Journal of the Serbian Chemical Society. 2004;69(5):353-362. doi:10.2298/JSC0405353R https://hdl.handle.net/21.15107/rcub_technorep_611 .
Rogan, Jelena, Poleti, Dejan, Karanović, Ljiljana, "Crystal structure of a new zigzag chain Cu(II) complex with terephthalato and 1,10-phenonthroline ligands, [Cu(C8H4O4)(C12H8N2)(H2O)]n" in Journal of the Serbian Chemical Society, 69, no. 5 (2004):353-362, https://doi.org/10.2298/JSC0405353R ., https://hdl.handle.net/21.15107/rcub_technorep_611 .