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The Effect of Preparation Method on Ni/Ce/Al Catalyst for High Temperature Water-Gas Shift Reaction
dc.creator | Sangsong, S. | |
dc.creator | Srimala, K. | |
dc.creator | Radonjić, Mia | |
dc.creator | Tungkamani, S. | |
dc.creator | Sornchamni, T. | |
dc.creator | Phongaksorn, M. | |
dc.date.accessioned | 2023-04-04T09:08:07Z | |
dc.date.available | 2023-04-04T09:08:07Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 1013-9826 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6346 | |
dc.description.abstract | High temperature water gas shift (HT-WGS) is an important catalytic process connected with reforming process in hydrogen production. Ni/CeO2-Al2O3 (or Al2O3) catalysts were studied in this work on the effect of catalyst preparation method toward the physicochemical properties and the HT-WGS activity. Ni/CeO2-Al2O3 were prepared by sol-gel and impregnation methods whereas Ni/Al2O3 was prepared by impregnation method. The catalyst samples were characterized by XRD, H2-TPR and H2-TPD techniques. The catalytic activities of HT-WGS catalysts was demonstrated at 550°C, GHSV of 2x105 mLh-1gcat-1and steam-to-CO ratio of 3. Nickel was detected as a nickel aluminate phase in the calcined catalyst. Ni strongly interacted with support in the calcined catalyst prepared by sol-gel method. The strong metal-support interaction can be resisted by preparing catalyst via impregnation and CeO2 can promote the H2O dissociation in HT-WGS mechanism. The highest metal dispersion, largest metal surface area and greatest HT-WGS activity were consequently achieved by Ni/CeO2-Al2O3 prepared from impregnation method. | sr |
dc.language.iso | en | sr |
dc.rights | restrictedAccess | sr |
dc.source | Key Engineering Materials | sr |
dc.subject | Catalyst Preparation | sr |
dc.subject | High Temperature Water-Gas Shift Reaction | sr |
dc.subject | Ni⁄CeO2-Al2O3 | sr |
dc.title | The Effect of Preparation Method on Ni/Ce/Al Catalyst for High Temperature Water-Gas Shift Reaction | sr |
dc.type | article | sr |
dc.rights.license | ARR | sr |
dc.citation.epage | 175 | |
dc.citation.spage | 171 | |
dc.citation.volume | 757 | |
dc.identifier.doi | 10.4028/www.scientific.net/KEM.757.171 | |
dc.identifier.scopus | 2-s2.0-85034025656 | |
dc.type.version | publishedVersion | sr |
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