Приказ основних података о документу
A novel open framework zincophosphate: Synthesis and characterization
dc.creator | Rajić, Nevenka | |
dc.creator | Zabukovec Logar, Nataša | |
dc.creator | Kaučič, Venčeslav | |
dc.date.accessioned | 2023-05-23T07:27:22Z | |
dc.date.available | 2023-05-23T07:27:22Z | |
dc.date.issued | 1995 | |
dc.identifier.issn | 0144-2449 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6387 | |
dc.description.abstract | The crystallization of a reactive zincophosphate gel (which may contain Co(ll) component) in the presence of sodium cations at ambient temperature and pressure yielded products (abbreviated ZnPO-HEX or CoZnPO-HEX) with a novel anionic open framework topology. The Co(ll) ions isomorphously replace zinc(ll) in this zincophosphate lattice up to 30%. The hopeite phase appears as a precursor in the crystallization of these new products. The single crystal structure determination of CoZnPO-HEX reveals that the structure belongs to the hexagonal P61 space group with unit cell parameters a = 10.447(3) and c = 15.049(5) A. The structure consists of a three-dimensional tetrahedral framework containing one-dimensional six-ring channels. An in finite helix built up of sodium cations and water molecules has been found inside the channel. The helix plays an important structural role because a complete dehydration of the materials is the cause for the transformation of the hexagonal structure to an unknown crystalline phase. | sr |
dc.language.iso | en | sr |
dc.publisher | Elsevier Science Inc. | sr |
dc.rights | restrictedAccess | sr |
dc.source | Zeolites | sr |
dc.subject | Zinc phospate | sr |
dc.subject | molecular sieves | sr |
dc.subject | molecular sieves | sr |
dc.subject | zincophosphates | sr |
dc.subject | zincophospate characterization | sr |
dc.title | A novel open framework zincophosphate: Synthesis and characterization | sr |
dc.type | article | sr |
dc.rights.license | ARR | sr |
dc.citation.epage | 678 | |
dc.citation.issue | 8 | |
dc.citation.spage | 672 | |
dc.citation.volume | 15 | |
dc.identifier.doi | 10.1016/0144-2449(95)00083-I | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_technorep_6387 | |
dc.identifier.scopus | 2-s2.0-0001111834 | |
dc.type.version | publishedVersion | sr |