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A Study of the Mn, Co and Ni Environment in the As-synthesized and Rehydrated-calcined Aluminophosphate with Chabazite-like Topology
dc.creator | Rajić, Nevenka | |
dc.creator | Arčin, Iztok | |
dc.creator | Kaučič, Venčeslav | |
dc.creator | Kodre, Alojz | |
dc.date.accessioned | 2023-05-23T09:32:41Z | |
dc.date.available | 2023-05-23T09:32:41Z | |
dc.date.issued | 1999 | |
dc.identifier.issn | 0011-1643 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6399 | |
dc.description.abstract | Diffuse-reflectance spectroscopy (DRS), X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) methods are applied to an investigation of Mn, Co and Ni local environments in MnAlPO, CoAlPO, and NiAlPO materials with chabazite-like topology. For all three products, insertion of the transition metals into tetrahedral Al-sites has been found. Calcination and rehydration of the as-synthesised materials cause a change of the oxidation number and co-ordination geometry of Mn and Co, while the oxidation and co-ordination number of Ni remain unaffected. | sr |
dc.language.iso | en | sr |
dc.publisher | Croatian Chemical Society | sr |
dc.relation | Ministry of Science and Technology of the Republic of Slovenia | sr |
dc.relation | International Buro Julich (Germany) | sr |
dc.rights | openAccess | sr |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.source | Croatica Chemica Acta | sr |
dc.subject | aluminophosphates | sr |
dc.subject | molecular sieves | sr |
dc.subject | MAPO-34 | sr |
dc.subject | chabazite-like | sr |
dc.subject | EXAFS, XANES | sr |
dc.subject | diffuse reflectance spectroscopy | sr |
dc.title | A Study of the Mn, Co and Ni Environment in the As-synthesized and Rehydrated-calcined Aluminophosphate with Chabazite-like Topology | sr |
dc.type | article | sr |
dc.rights.license | BY | sr |
dc.citation.epage | 661 | |
dc.citation.issue | 2-3 | |
dc.citation.spage | 645 | |
dc.citation.volume | 72 | |
dc.identifier.fulltext | http://TechnoRep.tmf.bg.ac.rs/bitstream/id/8186/CCA_72_1999.pdf | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_technorep_6399 | |
dc.type.version | publishedVersion | sr |