TY  - JOUR
AU  - Kalijadis, Ana
AU  - Đorđević, Jelena S.
AU  - Papp, Zsigmond
AU  - Jokić, Bojan M.
AU  - Spasojević, Vuk D.
AU  - Babić, Biljana M.
AU  - Trtić-Petrović, Tatjana M.
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5813
AB  - In this work, a new carbon paste electrode, prepared from nitrogen-doped hydrothermal carbon (CHTCN) was applied for the electrochemical detection and determination of carbendazim fungicide. CHTCN samples with the nominal nitrogen content 0.05-0.5 wt. % in glucose precursor were prepared by simple, low-cost synthesis with the accompanying carbonization to 1273 K. The presence of nitrogen in CHTCN samples was confirmed by elemental analysis. Characterization of CHTCN as material for carbon paste electrode was achieved by cyclic voltammetry measurement of the Fe(CN)(6)(3-/4-) redox couple. The results showed that best electrochemical response was obtained from the sample with a nominal nitrogen concentration of 0.1 wt. % and with tricresyl phosphate as a binder. During the development of a differential pulse stripping voltammetric method for carbendazim determination applying new electrode, the following experimental parameters were studied: the sort and amount of binding liquid, the effect of pH, accumulation potential and accumulation time. Under optimal conditions, the electrode offered linearity in the wide concentration range from 25 to 490 ng cm(-3) and an estimated detection limit of 1.21 ng cm(-3). Moreover, the electrode showed good stability, high selectivity and satisfactory anti-interference ability. Finally, the developed method was successfully applied for the determination of carbendazim traces in spiked tap and river water samples.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - A novel carbon paste electrode based on nitrogen-doped hydrothermal carbon for electrochemical determination of carbendazim
EP  - 1272
IS  - 11
SP  - 1259
VL  - 82
DO  - 10.2298/JSC161228053K
ER  - 

@article{
author = "Kalijadis, Ana and Đorđević, Jelena S. and Papp, Zsigmond and Jokić, Bojan M. and Spasojević, Vuk D. and Babić, Biljana M. and Trtić-Petrović, Tatjana M.",
year = "2017",
abstract = "In this work, a new carbon paste electrode, prepared from nitrogen-doped hydrothermal carbon (CHTCN) was applied for the electrochemical detection and determination of carbendazim fungicide. CHTCN samples with the nominal nitrogen content 0.05-0.5 wt. % in glucose precursor were prepared by simple, low-cost synthesis with the accompanying carbonization to 1273 K. The presence of nitrogen in CHTCN samples was confirmed by elemental analysis. Characterization of CHTCN as material for carbon paste electrode was achieved by cyclic voltammetry measurement of the Fe(CN)(6)(3-/4-) redox couple. The results showed that best electrochemical response was obtained from the sample with a nominal nitrogen concentration of 0.1 wt. % and with tricresyl phosphate as a binder. During the development of a differential pulse stripping voltammetric method for carbendazim determination applying new electrode, the following experimental parameters were studied: the sort and amount of binding liquid, the effect of pH, accumulation potential and accumulation time. Under optimal conditions, the electrode offered linearity in the wide concentration range from 25 to 490 ng cm(-3) and an estimated detection limit of 1.21 ng cm(-3). Moreover, the electrode showed good stability, high selectivity and satisfactory anti-interference ability. Finally, the developed method was successfully applied for the determination of carbendazim traces in spiked tap and river water samples.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "A novel carbon paste electrode based on nitrogen-doped hydrothermal carbon for electrochemical determination of carbendazim",
pages = "1272-1259",
number = "11",
volume = "82",
doi = "10.2298/JSC161228053K"
}

Kalijadis, A., Đorđević, J. S., Papp, Z., Jokić, B. M., Spasojević, V. D., Babić, B. M.,& Trtić-Petrović, T. M.. (2017). A novel carbon paste electrode based on nitrogen-doped hydrothermal carbon for electrochemical determination of carbendazim. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 82(11), 1259-1272.
https://doi.org/10.2298/JSC161228053K

Kalijadis A, Đorđević JS, Papp Z, Jokić BM, Spasojević VD, Babić BM, Trtić-Petrović TM. A novel carbon paste electrode based on nitrogen-doped hydrothermal carbon for electrochemical determination of carbendazim. in Journal of the Serbian Chemical Society. 2017;82(11):1259-1272.
doi:10.2298/JSC161228053K .

Kalijadis, Ana, Đorđević, Jelena S., Papp, Zsigmond, Jokić, Bojan M., Spasojević, Vuk D., Babić, Biljana M., Trtić-Petrović, Tatjana M., "A novel carbon paste electrode based on nitrogen-doped hydrothermal carbon for electrochemical determination of carbendazim" in Journal of the Serbian Chemical Society, 82, no. 11 (2017):1259-1272,
https://doi.org/10.2298/JSC161228053K . .

TY  - JOUR
AU  - Panić, Vesna
AU  - Seslija, Sanja I.
AU  - Popović, Ivanka
AU  - Spasojević, Vuk D.
AU  - Popović, Aleksandar R.
AU  - Nikolić, Vladimir B.
AU  - Spasojević, Pavle
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3728
AB  - For the preparation of fully biobased unsaturated polyester resins (UPRs), the replacement of styrene with alternate nonpetroleum-based monomers turned out to be one of the most challenging tasks. Its complexity lies in the fact that reactive diluents (RD) have to have low viscosity and volatility, good compatibility with prepolymer, and capability to homopolymerize and copolymerize with its unsaturations. In this context, we directed our efforts to develop fully biobased UPRs using the dialkyl itaconates as an alternative to styrene. Therefore, a series of 100% biobased UPRs were prepared from itaconic acid and 1,2-propandiol and diluted by dialkyl itaconates. The resins were characterized by Fourier transform infrared spectroscopy, NMR, volatility, and viscosity measurements, while the cured samples were characterized by dynamic mechanical properties, thermomechanical analysis, thermogravimetric analysis data, and tensile tests. The influence of RD structure on the properties of cured samples was discussed in detail. It was shown that the prepared resins had evaporation rates of dialkyl itaconates of several orders of magnitude less compared to styrene. The cured resins with dimethyl itaconate showed comparable or even better thermal and mechanical properties compared to the one with styrene. This investigation showed that itaconic acid and dialkyl itaconates are promising bioresources for the preparation of fully biobased UPRs for mass consumption.
PB  - Amer Chemical Soc, Washington
T2  - Biomacromolecules
T1  - Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid
EP  - 3891
IS  - 12
SP  - 3881
VL  - 18
DO  - 10.1021/acs.biomac.7b00840
ER  - 

@article{
author = "Panić, Vesna and Seslija, Sanja I. and Popović, Ivanka and Spasojević, Vuk D. and Popović, Aleksandar R. and Nikolić, Vladimir B. and Spasojević, Pavle",
year = "2017",
abstract = "For the preparation of fully biobased unsaturated polyester resins (UPRs), the replacement of styrene with alternate nonpetroleum-based monomers turned out to be one of the most challenging tasks. Its complexity lies in the fact that reactive diluents (RD) have to have low viscosity and volatility, good compatibility with prepolymer, and capability to homopolymerize and copolymerize with its unsaturations. In this context, we directed our efforts to develop fully biobased UPRs using the dialkyl itaconates as an alternative to styrene. Therefore, a series of 100% biobased UPRs were prepared from itaconic acid and 1,2-propandiol and diluted by dialkyl itaconates. The resins were characterized by Fourier transform infrared spectroscopy, NMR, volatility, and viscosity measurements, while the cured samples were characterized by dynamic mechanical properties, thermomechanical analysis, thermogravimetric analysis data, and tensile tests. The influence of RD structure on the properties of cured samples was discussed in detail. It was shown that the prepared resins had evaporation rates of dialkyl itaconates of several orders of magnitude less compared to styrene. The cured resins with dimethyl itaconate showed comparable or even better thermal and mechanical properties compared to the one with styrene. This investigation showed that itaconic acid and dialkyl itaconates are promising bioresources for the preparation of fully biobased UPRs for mass consumption.",
publisher = "Amer Chemical Soc, Washington",
journal = "Biomacromolecules",
title = "Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid",
pages = "3891-3881",
number = "12",
volume = "18",
doi = "10.1021/acs.biomac.7b00840"
}

Panić, V., Seslija, S. I., Popović, I., Spasojević, V. D., Popović, A. R., Nikolić, V. B.,& Spasojević, P.. (2017). Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid. in Biomacromolecules
Amer Chemical Soc, Washington., 18(12), 3881-3891.
https://doi.org/10.1021/acs.biomac.7b00840

Panić V, Seslija SI, Popović I, Spasojević VD, Popović AR, Nikolić VB, Spasojević P. Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid. in Biomacromolecules. 2017;18(12):3881-3891.
doi:10.1021/acs.biomac.7b00840 .

Panić, Vesna, Seslija, Sanja I., Popović, Ivanka, Spasojević, Vuk D., Popović, Aleksandar R., Nikolić, Vladimir B., Spasojević, Pavle, "Simple One-Pot Synthesis of Fully Biobased Unsaturated Polyester Resins Based on Itaconic Acid" in Biomacromolecules, 18, no. 12 (2017):3881-3891,
https://doi.org/10.1021/acs.biomac.7b00840 . .

TY  - JOUR
AU  - Dodevski, Vladimir
AU  - Kaluđerović, Branka
AU  - Krstić, Sanja S.
AU  - Spasojević, Vuk D.
AU  - Trifunović, Snežana
AU  - Uskoković, Petar
AU  - Marinković, Aleksandar
AU  - Stojmenović, Marija
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3548
AB  - Activated carbons (ACs) were successfully prepared using plane tree seed (PTS) as a cheap and renewable raw material. The plane tree seeds were firstly treated combining magnetic (MM) and ultrasonic mixing (USM) during 0.5, 1 and 3 h in 1 M, 3 M and 6 M of H3PO4 solutions, and then activated at 260 degrees C during 20 h (low temperature hydrothermal carbonization-low HTC) in above mentioned solutions of the same molarity. The influence of combined mixing and activation processes on physical, structural and morphological properties, and their optimization was studied by X-ray powder diffraction (XRPD), Raman spectroscopy, nitrogen adsorption-desorption isotherms, fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) analysis.
PB  - Trans Tech Publications Ltd, Durnten-Zurich
T2  - Journal of Nano Research
T1  - Optimization of Active Carbonaceous Material Obtained by Low Hydrothermal Carbonization of Plane Tree Seed with H3PO4
EP  - 84
SP  - 71
VL  - 48
DO  - 10.4028/www.scientific.net/JNanoR.48.71
ER  - 

@article{
author = "Dodevski, Vladimir and Kaluđerović, Branka and Krstić, Sanja S. and Spasojević, Vuk D. and Trifunović, Snežana and Uskoković, Petar and Marinković, Aleksandar and Stojmenović, Marija",
year = "2017",
abstract = "Activated carbons (ACs) were successfully prepared using plane tree seed (PTS) as a cheap and renewable raw material. The plane tree seeds were firstly treated combining magnetic (MM) and ultrasonic mixing (USM) during 0.5, 1 and 3 h in 1 M, 3 M and 6 M of H3PO4 solutions, and then activated at 260 degrees C during 20 h (low temperature hydrothermal carbonization-low HTC) in above mentioned solutions of the same molarity. The influence of combined mixing and activation processes on physical, structural and morphological properties, and their optimization was studied by X-ray powder diffraction (XRPD), Raman spectroscopy, nitrogen adsorption-desorption isotherms, fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) analysis.",
publisher = "Trans Tech Publications Ltd, Durnten-Zurich",
journal = "Journal of Nano Research",
title = "Optimization of Active Carbonaceous Material Obtained by Low Hydrothermal Carbonization of Plane Tree Seed with H3PO4",
pages = "84-71",
volume = "48",
doi = "10.4028/www.scientific.net/JNanoR.48.71"
}

Dodevski, V., Kaluđerović, B., Krstić, S. S., Spasojević, V. D., Trifunović, S., Uskoković, P., Marinković, A.,& Stojmenović, M.. (2017). Optimization of Active Carbonaceous Material Obtained by Low Hydrothermal Carbonization of Plane Tree Seed with H3PO4. in Journal of Nano Research
Trans Tech Publications Ltd, Durnten-Zurich., 48, 71-84.
https://doi.org/10.4028/www.scientific.net/JNanoR.48.71

Dodevski V, Kaluđerović B, Krstić SS, Spasojević VD, Trifunović S, Uskoković P, Marinković A, Stojmenović M. Optimization of Active Carbonaceous Material Obtained by Low Hydrothermal Carbonization of Plane Tree Seed with H3PO4. in Journal of Nano Research. 2017;48:71-84.
doi:10.4028/www.scientific.net/JNanoR.48.71 .

Dodevski, Vladimir, Kaluđerović, Branka, Krstić, Sanja S., Spasojević, Vuk D., Trifunović, Snežana, Uskoković, Petar, Marinković, Aleksandar, Stojmenović, Marija, "Optimization of Active Carbonaceous Material Obtained by Low Hydrothermal Carbonization of Plane Tree Seed with H3PO4" in Journal of Nano Research, 48 (2017):71-84,
https://doi.org/10.4028/www.scientific.net/JNanoR.48.71 . .

TY  - JOUR
AU  - Spasojević, Jelena P.
AU  - Radosavljević, Aleksandra
AU  - Krstić, Jelena I.
AU  - Jovanović, Dragutin
AU  - Spasojević, Vuk D.
AU  - Kalagasidis Krušić, Melina
AU  - Kačarević-Popović, Zorica M.
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3154
AB  - Thermo- and pH-sensitive Ag-P(NiPAAm/IA) hydrogel nanocomposites were prepared by in situ reduction of Ag+ ions with gamma irradiation. P(NiPAAm/IA) copolymer hydrogel matrices have been previously synthesized by radiation induced copolymerization. The copolymer composition was determined by elemental analysis of the dried gels, and was found to be close to that of the feed. The dependence of swelling properties and phase transitions on the IA comonomer content, temperature, pH values and presence of AgNPs were investigated. The hydrogels showed both thermo- and pH responses. By introducing small amounts of IA, swelling capacity increase, and the volume phase transition temperature (VPIT) of P(NiPAAm/IA) copolymers is transferred to higher values. Presence of AgNPs causes decrease of equilibrium swelling degree and VPIT, and allows of fine-tuning of these properties. Both the average values of compressive elastic modulus and Young's modulus of elasticity were decreased by addition of IA as a consequence of looser structure of the network (increase in molar mass between two neighboring crosslinks and decrease in effective crosslinking density). The introduction of AgNPs promoted not only improvement of these mechanical parameters, but an improvement of stress at failure especially in the systems with the highest content of IA. In addition, Ag-P(NiPAAm/IA) hydrogel nanocomposites showed good antibacterial potentials.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - European Polymer Journal
T1  - Dual responsive antibacterial Ag-poly(N-isopropylacrylamide/itaconic acid) hydrogel nanocomposites synthesized by gamma irradiation
EP  - 185
SP  - 168
VL  - 69
DO  - 10.1016/j.eurpolymj.2015.06.008
ER  - 

@article{
author = "Spasojević, Jelena P. and Radosavljević, Aleksandra and Krstić, Jelena I. and Jovanović, Dragutin and Spasojević, Vuk D. and Kalagasidis Krušić, Melina and Kačarević-Popović, Zorica M.",
year = "2015",
abstract = "Thermo- and pH-sensitive Ag-P(NiPAAm/IA) hydrogel nanocomposites were prepared by in situ reduction of Ag+ ions with gamma irradiation. P(NiPAAm/IA) copolymer hydrogel matrices have been previously synthesized by radiation induced copolymerization. The copolymer composition was determined by elemental analysis of the dried gels, and was found to be close to that of the feed. The dependence of swelling properties and phase transitions on the IA comonomer content, temperature, pH values and presence of AgNPs were investigated. The hydrogels showed both thermo- and pH responses. By introducing small amounts of IA, swelling capacity increase, and the volume phase transition temperature (VPIT) of P(NiPAAm/IA) copolymers is transferred to higher values. Presence of AgNPs causes decrease of equilibrium swelling degree and VPIT, and allows of fine-tuning of these properties. Both the average values of compressive elastic modulus and Young's modulus of elasticity were decreased by addition of IA as a consequence of looser structure of the network (increase in molar mass between two neighboring crosslinks and decrease in effective crosslinking density). The introduction of AgNPs promoted not only improvement of these mechanical parameters, but an improvement of stress at failure especially in the systems with the highest content of IA. In addition, Ag-P(NiPAAm/IA) hydrogel nanocomposites showed good antibacterial potentials.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "European Polymer Journal",
title = "Dual responsive antibacterial Ag-poly(N-isopropylacrylamide/itaconic acid) hydrogel nanocomposites synthesized by gamma irradiation",
pages = "185-168",
volume = "69",
doi = "10.1016/j.eurpolymj.2015.06.008"
}

Spasojević, J. P., Radosavljević, A., Krstić, J. I., Jovanović, D., Spasojević, V. D., Kalagasidis Krušić, M.,& Kačarević-Popović, Z. M.. (2015). Dual responsive antibacterial Ag-poly(N-isopropylacrylamide/itaconic acid) hydrogel nanocomposites synthesized by gamma irradiation. in European Polymer Journal
Pergamon-Elsevier Science Ltd, Oxford., 69, 168-185.
https://doi.org/10.1016/j.eurpolymj.2015.06.008

Spasojević JP, Radosavljević A, Krstić JI, Jovanović D, Spasojević VD, Kalagasidis Krušić M, Kačarević-Popović ZM. Dual responsive antibacterial Ag-poly(N-isopropylacrylamide/itaconic acid) hydrogel nanocomposites synthesized by gamma irradiation. in European Polymer Journal. 2015;69:168-185.
doi:10.1016/j.eurpolymj.2015.06.008 .

Spasojević, Jelena P., Radosavljević, Aleksandra, Krstić, Jelena I., Jovanović, Dragutin, Spasojević, Vuk D., Kalagasidis Krušić, Melina, Kačarević-Popović, Zorica M., "Dual responsive antibacterial Ag-poly(N-isopropylacrylamide/itaconic acid) hydrogel nanocomposites synthesized by gamma irradiation" in European Polymer Journal, 69 (2015):168-185,
https://doi.org/10.1016/j.eurpolymj.2015.06.008 . .

TY  - JOUR
AU  - Spasojević, Vuk D.
AU  - Šerbanović, Slobodan P.
AU  - Stefanović, Predrag
AU  - Kijevčanin, Mirjana
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2646
AB  - In this work a review of the currently available methods for carbon dioxide removal from flue gasses is given. Some of them are commercially available, while others are still under development. Special attention is given to detailed description of the methods based on hemi sorption by aqueous solutions of alkanolamines, which found wide commercial use in industry. Selection of appropriate absorbent, process equipment, methods, working parameters, combustion processes, etc., are some of the key points that will be reviewed within this work in order to present advantages and limitations of carbon dioxide removal methods. In the experimental section we have provided data on density, viscosity and refractive index of insufficiently investigated carbon dioxide removal agents, such as monoisopropanolamine (MIPA), diisopropanolamine (DIPA), triisopropanolamine (TIPA) and currently widely used dietanolamine (DEA). The data obtained are crucial for the equipment design and process optimization.
AB  - Intezivna naučna istraživanja u proteklih dvadeset godina pružaju jasne dokaze da su klimatske promene, kao i porast koncentracije gasova koji izazivaju efekat staklene bašte u atmosferi, prouzrokovane čovekovim delovanjem. Energetski sektor igra ključnu ulogu u ukupnoj emisiji ugljen-dioksida sa udelom između 60 i 70%, obaveza po pitanju smanjenja emisije gasova staklene bašte. Pored toga, povećanje potrošnje energije iz godine u godinu, kao i očekivano povećanje industrijske proizvodnje, dovešće do povećanja potrošnje fosilnih goriva, a samim tim i do povećanja emisije gasova staklene bašte. Navedene činjenice impliciraju da će energetski sektor biti ključan sektor u kome je potrebno ostvariti implementaciju svih mera i aktivnosti koje kao glavni cilj imaju smanjenje emisije gasova staklene bašte. Ovaj rad daje pregled tehnoloških postupaka za uklanjanje ugljen-dioksida od kojih su neki već našli komercijalnu upotrebu, dok su drugi još uvek u fazi razvoja. Posebna pažnja je posvećena opisu metoda zasnovanih na hemisoprpciji rastvora alkanolamina, koji su našli široku komercijalnu upotrebu. Izbor odgovarajućeg rastvarača, procesne opreme, radnih parametara, procesa sagorevanja itd. su samo neki od ključnih tačaka koje su prikazane u okviru ovog rada sa ciljem pružanja jasnije slike o mogućnostima i ograničenjima metoda za uklanjanje ugljen-dioksida. U okviru eksperimentalnog dela rada dati su rezultati merenja transportnih svojstava, nedovoljno ispitanih jedinjenja monoizopropanolamina (MIPA), diizopropanolamina (DIPA), triizopropanolamina (TIPA) i dietanolamina (DEA) kao potencijalnih reagensa za uklanjanje ugljen-dioksida. Od poseb nog interesa su svojsta gustine, indeksa refrakcije i viskoznosti kao i promena ovih svojstava čistih jedinjenja sa temperaturom. Navedeni parametri su ključni za projektovanje procesne opreme kao i za optimizaciju samog procesa uklanjanja ugljen-dioksida.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Review of technological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases
T1  - Pregled tehnoloških postupaka i eksperimentalno određivanje termodinamičkih i transportnih svojstava reagensa za uklanjanje ugljen-dioksida
EP  - 134
IS  - 1
SP  - 123
VL  - 68
DO  - 10.2298/HEMIND130312039S
ER  - 

@article{
author = "Spasojević, Vuk D. and Šerbanović, Slobodan P. and Stefanović, Predrag and Kijevčanin, Mirjana",
year = "2014",
abstract = "In this work a review of the currently available methods for carbon dioxide removal from flue gasses is given. Some of them are commercially available, while others are still under development. Special attention is given to detailed description of the methods based on hemi sorption by aqueous solutions of alkanolamines, which found wide commercial use in industry. Selection of appropriate absorbent, process equipment, methods, working parameters, combustion processes, etc., are some of the key points that will be reviewed within this work in order to present advantages and limitations of carbon dioxide removal methods. In the experimental section we have provided data on density, viscosity and refractive index of insufficiently investigated carbon dioxide removal agents, such as monoisopropanolamine (MIPA), diisopropanolamine (DIPA), triisopropanolamine (TIPA) and currently widely used dietanolamine (DEA). The data obtained are crucial for the equipment design and process optimization., Intezivna naučna istraživanja u proteklih dvadeset godina pružaju jasne dokaze da su klimatske promene, kao i porast koncentracije gasova koji izazivaju efekat staklene bašte u atmosferi, prouzrokovane čovekovim delovanjem. Energetski sektor igra ključnu ulogu u ukupnoj emisiji ugljen-dioksida sa udelom između 60 i 70%, obaveza po pitanju smanjenja emisije gasova staklene bašte. Pored toga, povećanje potrošnje energije iz godine u godinu, kao i očekivano povećanje industrijske proizvodnje, dovešće do povećanja potrošnje fosilnih goriva, a samim tim i do povećanja emisije gasova staklene bašte. Navedene činjenice impliciraju da će energetski sektor biti ključan sektor u kome je potrebno ostvariti implementaciju svih mera i aktivnosti koje kao glavni cilj imaju smanjenje emisije gasova staklene bašte. Ovaj rad daje pregled tehnoloških postupaka za uklanjanje ugljen-dioksida od kojih su neki već našli komercijalnu upotrebu, dok su drugi još uvek u fazi razvoja. Posebna pažnja je posvećena opisu metoda zasnovanih na hemisoprpciji rastvora alkanolamina, koji su našli široku komercijalnu upotrebu. Izbor odgovarajućeg rastvarača, procesne opreme, radnih parametara, procesa sagorevanja itd. su samo neki od ključnih tačaka koje su prikazane u okviru ovog rada sa ciljem pružanja jasnije slike o mogućnostima i ograničenjima metoda za uklanjanje ugljen-dioksida. U okviru eksperimentalnog dela rada dati su rezultati merenja transportnih svojstava, nedovoljno ispitanih jedinjenja monoizopropanolamina (MIPA), diizopropanolamina (DIPA), triizopropanolamina (TIPA) i dietanolamina (DEA) kao potencijalnih reagensa za uklanjanje ugljen-dioksida. Od poseb nog interesa su svojsta gustine, indeksa refrakcije i viskoznosti kao i promena ovih svojstava čistih jedinjenja sa temperaturom. Navedeni parametri su ključni za projektovanje procesne opreme kao i za optimizaciju samog procesa uklanjanja ugljen-dioksida.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Review of technological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases, Pregled tehnoloških postupaka i eksperimentalno određivanje termodinamičkih i transportnih svojstava reagensa za uklanjanje ugljen-dioksida",
pages = "134-123",
number = "1",
volume = "68",
doi = "10.2298/HEMIND130312039S"
}

Spasojević, V. D., Šerbanović, S. P., Stefanović, P.,& Kijevčanin, M.. (2014). Review of technological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases. in Hemijska industrija
Association of Chemical Engineers of Serbia., 68(1), 123-134.
https://doi.org/10.2298/HEMIND130312039S

Spasojević VD, Šerbanović SP, Stefanović P, Kijevčanin M. Review of technological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases. in Hemijska industrija. 2014;68(1):123-134.
doi:10.2298/HEMIND130312039S .

Spasojević, Vuk D., Šerbanović, Slobodan P., Stefanović, Predrag, Kijevčanin, Mirjana, "Review of technological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases" in Hemijska industrija, 68, no. 1 (2014):123-134,
https://doi.org/10.2298/HEMIND130312039S . .

TY  - JOUR
AU  - Spasojević, Vuk D.
AU  - Đorđević, Bojan D.
AU  - Šerbanović, Slobodan P.
AU  - Radović, Ivona
AU  - Kijevčanin, Mirjana
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2787
AB  - Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular interactions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Chemical and Engineering Data
T1  - Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K
EP  - 1829
IS  - 6
SP  - 1817
VL  - 59
DO  - 10.1021/je401036f
ER  - 

@article{
author = "Spasojević, Vuk D. and Đorđević, Bojan D. and Šerbanović, Slobodan P. and Radović, Ivona and Kijevčanin, Mirjana",
year = "2014",
abstract = "Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular interactions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Chemical and Engineering Data",
title = "Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K",
pages = "1829-1817",
number = "6",
volume = "59",
doi = "10.1021/je401036f"
}

Spasojević, V. D., Đorđević, B. D., Šerbanović, S. P., Radović, I.,& Kijevčanin, M.. (2014). Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K. in Journal of Chemical and Engineering Data
Amer Chemical Soc, Washington., 59(6), 1817-1829.
https://doi.org/10.1021/je401036f

Spasojević VD, Đorđević BD, Šerbanović SP, Radović I, Kijevčanin M. Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K. in Journal of Chemical and Engineering Data. 2014;59(6):1817-1829.
doi:10.1021/je401036f .

Spasojević, Vuk D., Đorđević, Bojan D., Šerbanović, Slobodan P., Radović, Ivona, Kijevčanin, Mirjana, "Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K" in Journal of Chemical and Engineering Data, 59, no. 6 (2014):1817-1829,
https://doi.org/10.1021/je401036f . .