TY  - JOUR
AU  - Gligorijević, Bojan
AU  - Vilotijević, Miroljub N.
AU  - Scepanović, Maja
AU  - Radovanović, Radovan V.
AU  - Radović, Nenad
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3562
AB  - The present study estimated the cracking phenomenon in as-plasma-sprayed hydroxylapatite coatings (HACs) after they were being subjected to the severe cutting conditions in the direction perpendicular to the coating/substrate interface. In order to evaluate the effects of substrate preheating on the occurrence of micro-cracks, the HACs were deposited at different initial substrate temperatures (T-S = 20, 100 and 200 degrees C). The changes in phase composition and HA splat morphology with T-S were observed and were correlated with the cracking occurrence. The results showed that severe cutting conditions introduced a localized cracking in the regions of HACs dominantly attributed to the brittle hydroxyl- deficient amorphous calcium phosphate (ACP) phase. This effect was particularly observable in the HACs deposited without preheating of substrate. On the other hand, the preheating of substrate reduced the presence of micro-cracks and caused insignificant changes in the average local phase composition. In HACs deposited with preheating of substrate, the HA splats (of which HACs are composed) were thinner and recrystallized HA regions seemed smaller in size and more evenly distributed. These results implied potentially important roles of the HA splat formation mechanism on the distribution of ACP and recrystallized HA regions in the as-plasma-sprayed HACs and the cracking resistance of HACs.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Cracking caused by cutting of plasma-sprayed hydroxyapatite coatings and its relation to the structural features of coatings deposited at different initial substrate temperatures
EP  - 249
IS  - 3
SP  - 241
VL  - 71
DO  - 10.2298/HEMIND160513034G
ER  - 

@article{
author = "Gligorijević, Bojan and Vilotijević, Miroljub N. and Scepanović, Maja and Radovanović, Radovan V. and Radović, Nenad",
year = "2017",
abstract = "The present study estimated the cracking phenomenon in as-plasma-sprayed hydroxylapatite coatings (HACs) after they were being subjected to the severe cutting conditions in the direction perpendicular to the coating/substrate interface. In order to evaluate the effects of substrate preheating on the occurrence of micro-cracks, the HACs were deposited at different initial substrate temperatures (T-S = 20, 100 and 200 degrees C). The changes in phase composition and HA splat morphology with T-S were observed and were correlated with the cracking occurrence. The results showed that severe cutting conditions introduced a localized cracking in the regions of HACs dominantly attributed to the brittle hydroxyl- deficient amorphous calcium phosphate (ACP) phase. This effect was particularly observable in the HACs deposited without preheating of substrate. On the other hand, the preheating of substrate reduced the presence of micro-cracks and caused insignificant changes in the average local phase composition. In HACs deposited with preheating of substrate, the HA splats (of which HACs are composed) were thinner and recrystallized HA regions seemed smaller in size and more evenly distributed. These results implied potentially important roles of the HA splat formation mechanism on the distribution of ACP and recrystallized HA regions in the as-plasma-sprayed HACs and the cracking resistance of HACs.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Cracking caused by cutting of plasma-sprayed hydroxyapatite coatings and its relation to the structural features of coatings deposited at different initial substrate temperatures",
pages = "249-241",
number = "3",
volume = "71",
doi = "10.2298/HEMIND160513034G"
}

Gligorijević, B., Vilotijević, M. N., Scepanović, M., Radovanović, R. V.,& Radović, N.. (2017). Cracking caused by cutting of plasma-sprayed hydroxyapatite coatings and its relation to the structural features of coatings deposited at different initial substrate temperatures. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 71(3), 241-249.
https://doi.org/10.2298/HEMIND160513034G

Gligorijević B, Vilotijević MN, Scepanović M, Radovanović RV, Radović N. Cracking caused by cutting of plasma-sprayed hydroxyapatite coatings and its relation to the structural features of coatings deposited at different initial substrate temperatures. in Hemijska industrija. 2017;71(3):241-249.
doi:10.2298/HEMIND160513034G .

Gligorijević, Bojan, Vilotijević, Miroljub N., Scepanović, Maja, Radovanović, Radovan V., Radović, Nenad, "Cracking caused by cutting of plasma-sprayed hydroxyapatite coatings and its relation to the structural features of coatings deposited at different initial substrate temperatures" in Hemijska industrija, 71, no. 3 (2017):241-249,
https://doi.org/10.2298/HEMIND160513034G . .

TY  - JOUR
AU  - Gligorijević, Bojan
AU  - Vilotijević, Miroljub N.
AU  - Scepanović, Maja
AU  - Vuković, Nikola S.
AU  - Radović, Nenad
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3403
AB  - The aim of the present study was to investigate the influence of substrate preheating on the structural properties of hydroxyapatite coatings (HACs) deposited by using the high power (52 kW) laminar plasma jet. The deposition experiments were performed within the 20-200 degrees C temperature range at different stand-off distances. The structural properties in the thickness direction and at the surface of the HACs were investigated by using the micro-Raman spectroscopy, scanning electron microscopy coupled with energy dispersive spectrometry, and X-ray powder diffractometry. The deposition without the preheating of the substrate produced HACs with crystallinity gradient in the thickness direction. At the stand-off distance of 80 mm, the preheating of the substrate at 200 degrees C practically eliminated the crystallinity gradient. At distances from the coating/substrate interface shorter than similar to 100 mu m, the increase of crystallinity with the preheating of the substrate was dominantly attributed to the recrystallization of hydroxyl-rich ACP into HA. At longer distances and higher initial substrate temperatures (  gt  100 degrees C), the crystallinity changes were negligible, whereas the recrystallization of hydroxyl-deficient ACP into oxyapatite (OA) was also possible. The X-ray diffractometry indicated the deposition conditions under which a minimum residual stress was achieved. The results of the present study strongly suggested the relation between the ACP - gt  HA remystallization process and the bonding strength of the HACs.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Substrate preheating and structural properties of power plasma sprayed hydroxyapatite coatings
EP  - 420
IS  - 1
SP  - 411
VL  - 42
DO  - 10.1016/j.ceramint.2015.08.125
ER  - 

@article{
author = "Gligorijević, Bojan and Vilotijević, Miroljub N. and Scepanović, Maja and Vuković, Nikola S. and Radović, Nenad",
year = "2016",
abstract = "The aim of the present study was to investigate the influence of substrate preheating on the structural properties of hydroxyapatite coatings (HACs) deposited by using the high power (52 kW) laminar plasma jet. The deposition experiments were performed within the 20-200 degrees C temperature range at different stand-off distances. The structural properties in the thickness direction and at the surface of the HACs were investigated by using the micro-Raman spectroscopy, scanning electron microscopy coupled with energy dispersive spectrometry, and X-ray powder diffractometry. The deposition without the preheating of the substrate produced HACs with crystallinity gradient in the thickness direction. At the stand-off distance of 80 mm, the preheating of the substrate at 200 degrees C practically eliminated the crystallinity gradient. At distances from the coating/substrate interface shorter than similar to 100 mu m, the increase of crystallinity with the preheating of the substrate was dominantly attributed to the recrystallization of hydroxyl-rich ACP into HA. At longer distances and higher initial substrate temperatures (  gt  100 degrees C), the crystallinity changes were negligible, whereas the recrystallization of hydroxyl-deficient ACP into oxyapatite (OA) was also possible. The X-ray diffractometry indicated the deposition conditions under which a minimum residual stress was achieved. The results of the present study strongly suggested the relation between the ACP - gt  HA remystallization process and the bonding strength of the HACs.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Substrate preheating and structural properties of power plasma sprayed hydroxyapatite coatings",
pages = "420-411",
number = "1",
volume = "42",
doi = "10.1016/j.ceramint.2015.08.125"
}

Gligorijević, B., Vilotijević, M. N., Scepanović, M., Vuković, N. S.,& Radović, N.. (2016). Substrate preheating and structural properties of power plasma sprayed hydroxyapatite coatings. in Ceramics International
Elsevier Sci Ltd, Oxford., 42(1), 411-420.
https://doi.org/10.1016/j.ceramint.2015.08.125

Gligorijević B, Vilotijević MN, Scepanović M, Vuković NS, Radović N. Substrate preheating and structural properties of power plasma sprayed hydroxyapatite coatings. in Ceramics International. 2016;42(1):411-420.
doi:10.1016/j.ceramint.2015.08.125 .

Gligorijević, Bojan, Vilotijević, Miroljub N., Scepanović, Maja, Vuković, Nikola S., Radović, Nenad, "Substrate preheating and structural properties of power plasma sprayed hydroxyapatite coatings" in Ceramics International, 42, no. 1 (2016):411-420,
https://doi.org/10.1016/j.ceramint.2015.08.125 . .