The study of physicochemical and biochemical processes in living environment that have impacts on pollution and the investigation of possibilities for minimizing the consequences

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The study of physicochemical and biochemical processes in living environment that have impacts on pollution and the investigation of possibilities for minimizing the consequences (en)
Проучавање физичкохемијских и биохемијских процеса у животној средини који утичу на загађење и истраживање могућности за минимизирање последица (sr)
Proučavanje fizičkohemijskih i biohemijskih procesa u životnoj sredini koji utiču na zagađenje i istraživanje mogućnosti za minimiziranje posledica (sr_RS)
Authors

Publications

Theoretical modeling of sorption of metal ions on amino-functionalized macroporous copolymer in aqueous solution

Suručić, Ljiljana T.; Janjić, Goran; Rakić, Aleksandra; Nastasović, Aleksandra; Popović, Aleksandar R.; Milčić, Miloš; Onjia, Antonije

(Springer, New York, 2019)

TY  - JOUR
AU  - Suručić, Ljiljana T.
AU  - Janjić, Goran
AU  - Rakić, Aleksandra
AU  - Nastasović, Aleksandra
AU  - Popović, Aleksandar R.
AU  - Milčić, Miloš
AU  - Onjia, Antonije
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4217
AB  - With regard to the harmful effects of heavy metals on human health and the environment, the demand for synthesis and investigation of macromolecules with large capacity of harmful substances sorption is ever greater. Quantum-chemical methods may be applied in structural modeling, prediction, and characterization of such molecules and reactions. Sorption of metal ions (Cu2+, Cd2+, Co2+, and Ni2+) to triethylenetetramine-functionalized copolymer poly(GMA-co-EGDMA)-teta was successfully modeled by quantum chemical calculations, at the B3LYP//6-311++G**/lanl2dz level. Optimized structures of metal complexes were used for calculation of real binding energy of metal ion within the complex (Er). Solvent and hydrolyzation effects were essential for obtaining the objective values. Solvent effect was included in Er by using the total solvation energy for reaction of formation of tetaOH complex (Es1, the first approach) or by using dehydration energy of free metal ion (Es2, the second approach). Experimental results were confirmed in our theoretical analyses (using the second approach).
PB  - Springer, New York
T2  - Journal of Molecular Modeling
T1  - Theoretical modeling of sorption of metal ions on amino-functionalized macroporous copolymer in aqueous solution
IS  - 6
VL  - 25
DO  - 10.1007/s00894-019-4053-0
ER  - 
@article{
author = "Suručić, Ljiljana T. and Janjić, Goran and Rakić, Aleksandra and Nastasović, Aleksandra and Popović, Aleksandar R. and Milčić, Miloš and Onjia, Antonije",
year = "2019",
abstract = "With regard to the harmful effects of heavy metals on human health and the environment, the demand for synthesis and investigation of macromolecules with large capacity of harmful substances sorption is ever greater. Quantum-chemical methods may be applied in structural modeling, prediction, and characterization of such molecules and reactions. Sorption of metal ions (Cu2+, Cd2+, Co2+, and Ni2+) to triethylenetetramine-functionalized copolymer poly(GMA-co-EGDMA)-teta was successfully modeled by quantum chemical calculations, at the B3LYP//6-311++G**/lanl2dz level. Optimized structures of metal complexes were used for calculation of real binding energy of metal ion within the complex (Er). Solvent and hydrolyzation effects were essential for obtaining the objective values. Solvent effect was included in Er by using the total solvation energy for reaction of formation of tetaOH complex (Es1, the first approach) or by using dehydration energy of free metal ion (Es2, the second approach). Experimental results were confirmed in our theoretical analyses (using the second approach).",
publisher = "Springer, New York",
journal = "Journal of Molecular Modeling",
title = "Theoretical modeling of sorption of metal ions on amino-functionalized macroporous copolymer in aqueous solution",
number = "6",
volume = "25",
doi = "10.1007/s00894-019-4053-0"
}
Suručić, L. T., Janjić, G., Rakić, A., Nastasović, A., Popović, A. R., Milčić, M.,& Onjia, A.. (2019). Theoretical modeling of sorption of metal ions on amino-functionalized macroporous copolymer in aqueous solution. in Journal of Molecular Modeling
Springer, New York., 25(6).
https://doi.org/10.1007/s00894-019-4053-0
Suručić LT, Janjić G, Rakić A, Nastasović A, Popović AR, Milčić M, Onjia A. Theoretical modeling of sorption of metal ions on amino-functionalized macroporous copolymer in aqueous solution. in Journal of Molecular Modeling. 2019;25(6).
doi:10.1007/s00894-019-4053-0 .
Suručić, Ljiljana T., Janjić, Goran, Rakić, Aleksandra, Nastasović, Aleksandra, Popović, Aleksandar R., Milčić, Miloš, Onjia, Antonije, "Theoretical modeling of sorption of metal ions on amino-functionalized macroporous copolymer in aqueous solution" in Journal of Molecular Modeling, 25, no. 6 (2019),
https://doi.org/10.1007/s00894-019-4053-0 . .
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Partitioning of particulate matter and elements of suburban continental aerosols between fine and coarse modes

Đuričić-Milanković, Jelena; Anđelković, Ivan; Pantelić, Ana; Petrović, Srđan; Gambaro, Andrea; Antonovic, Dusan; Đorđević, Dragana

(Springer Heidelberg, Heidelberg, 2018)

TY  - JOUR
AU  - Đuričić-Milanković, Jelena
AU  - Anđelković, Ivan
AU  - Pantelić, Ana
AU  - Petrović, Srđan
AU  - Gambaro, Andrea
AU  - Antonovic, Dusan
AU  - Đorđević, Dragana
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5876
AB  - The results presented in this work demonstrate for the first time a distribution of elements in the spectral analysis of aerosols in the suburban continental Balkan Peninsula. Samples were collected in the suburban area of Belgrade (Serbia) in the period from March 2012 till December 2013. Results presented here are from long-term measurements of masses of size-segregated aerosols and macro- and microelements in the range of PM0.27-16. The following elements were analyzed: Al, Ag, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, Ni, Pb, Sb, Ti, Tl, V, and Zn; levels of Be, Hg, and Se were under the detection limits in all samples. Average concentrations and time and seasonal variations of particulate matter (PM) as well as element contents and their percentage shares are given. The results showed the domination of particle content around the accumulation mode in the range of 0.53  LT  Dp  LT  1.06 mu m, but the fractional distribution of elements showed maximal average concentrations in different fractions depending on the origin of each element. Crustal elements (Al, Ca, Fe, Mg, Mn, Ti, etc.) dominated in coarse mode, while anthropogenic elements (As, Cd, Cu, Pb, Sb, etc.) were mainly distributed in fine mode fractions. Some elements, such are As and Ni, were detected in investigated aerosols only occasionally, while others, such as Ca, Fe, and Mg, were detected in all analyzed samples. The application of multivariate analysis (PCA) demonstrated the connection between the elements of similar origin, in fine fractions mainly of anthropogenic origin, while in coarse mode of crustal origin, indicating the resuspension with contribution of about 40%. The contents of some measured elements were compared with their contents in aerosols in some European suburban areas.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental Science and Pollution Research
T1  - Partitioning of particulate matter and elements of suburban continental aerosols between fine and coarse modes
EP  - 20853
IS  - 21
SP  - 20841
VL  - 25
DO  - 10.1007/s11356-018-2037-8
ER  - 
@article{
author = "Đuričić-Milanković, Jelena and Anđelković, Ivan and Pantelić, Ana and Petrović, Srđan and Gambaro, Andrea and Antonovic, Dusan and Đorđević, Dragana",
year = "2018",
abstract = "The results presented in this work demonstrate for the first time a distribution of elements in the spectral analysis of aerosols in the suburban continental Balkan Peninsula. Samples were collected in the suburban area of Belgrade (Serbia) in the period from March 2012 till December 2013. Results presented here are from long-term measurements of masses of size-segregated aerosols and macro- and microelements in the range of PM0.27-16. The following elements were analyzed: Al, Ag, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, Ni, Pb, Sb, Ti, Tl, V, and Zn; levels of Be, Hg, and Se were under the detection limits in all samples. Average concentrations and time and seasonal variations of particulate matter (PM) as well as element contents and their percentage shares are given. The results showed the domination of particle content around the accumulation mode in the range of 0.53  LT  Dp  LT  1.06 mu m, but the fractional distribution of elements showed maximal average concentrations in different fractions depending on the origin of each element. Crustal elements (Al, Ca, Fe, Mg, Mn, Ti, etc.) dominated in coarse mode, while anthropogenic elements (As, Cd, Cu, Pb, Sb, etc.) were mainly distributed in fine mode fractions. Some elements, such are As and Ni, were detected in investigated aerosols only occasionally, while others, such as Ca, Fe, and Mg, were detected in all analyzed samples. The application of multivariate analysis (PCA) demonstrated the connection between the elements of similar origin, in fine fractions mainly of anthropogenic origin, while in coarse mode of crustal origin, indicating the resuspension with contribution of about 40%. The contents of some measured elements were compared with their contents in aerosols in some European suburban areas.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental Science and Pollution Research",
title = "Partitioning of particulate matter and elements of suburban continental aerosols between fine and coarse modes",
pages = "20853-20841",
number = "21",
volume = "25",
doi = "10.1007/s11356-018-2037-8"
}
Đuričić-Milanković, J., Anđelković, I., Pantelić, A., Petrović, S., Gambaro, A., Antonovic, D.,& Đorđević, D.. (2018). Partitioning of particulate matter and elements of suburban continental aerosols between fine and coarse modes. in Environmental Science and Pollution Research
Springer Heidelberg, Heidelberg., 25(21), 20841-20853.
https://doi.org/10.1007/s11356-018-2037-8
Đuričić-Milanković J, Anđelković I, Pantelić A, Petrović S, Gambaro A, Antonovic D, Đorđević D. Partitioning of particulate matter and elements of suburban continental aerosols between fine and coarse modes. in Environmental Science and Pollution Research. 2018;25(21):20841-20853.
doi:10.1007/s11356-018-2037-8 .
Đuričić-Milanković, Jelena, Anđelković, Ivan, Pantelić, Ana, Petrović, Srđan, Gambaro, Andrea, Antonovic, Dusan, Đorđević, Dragana, "Partitioning of particulate matter and elements of suburban continental aerosols between fine and coarse modes" in Environmental Science and Pollution Research, 25, no. 21 (2018):20841-20853,
https://doi.org/10.1007/s11356-018-2037-8 . .
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Influence of amine activators and reaction parameters on grafting reaction between polystyrene and starch

Nikolić, Vladimir; Veličković, Sava; Popović, Aleksandar R.

(Springer, Dordrecht, 2014)

TY  - JOUR
AU  - Nikolić, Vladimir
AU  - Veličković, Sava
AU  - Popović, Aleksandar R.
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5777
AB  - Polystyrene graft corn starch copolymers (PS-g-starch) were synthesized by emulsion polymerization using sodium dodecylsulfate (SDS) as the emulsifier and potassium persulfate (PPS) as the initiator. Influences of temperature (25-75 A degrees C), monomer (0.56-0.96 mol/dm(3)) and initiator (0.007-0.020 mol/dm(3)) concentration, reaction time (15-300 min), and type of amine activator and its concentration (0.005-0.08 mol/dm(3)) on the percentage of grafting (G, %) and yield (Y, %) were investigated. Amines showed dual impact on grafting reaction, some of them were activators and other were inhibitors, where N,N-dimethylethanolamine gave the maximal and 1-(2-hydroxyethyl) piperazine gave the minimal value of percentage of grafting. The maximum percentage of grafting was 32.55 %, while in case of piperazine derivate percentage of grafting was zero. Successful grafting was confirmed by Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM). The maximum percentage of grafting was obtained under the following reaction conditions: 10.00 g of starch, monomer concentration was 0.96 mol/dm(3), initiator concentration was 0.015 mol/dm(3), reaction time was 15 min, temperature of 75 A degrees C, and N,N-dimethylethanolamine was used as activator in concentration of 0.01 mol/dm(3).
PB  - Springer, Dordrecht
T2  - Journal of Polymer Research
T1  - Influence of amine activators and reaction parameters on grafting reaction between polystyrene and starch
IS  - 2
SP  - 363
VL  - 21
DO  - 10.1007/s10965-014-0363-1
ER  - 
@article{
author = "Nikolić, Vladimir and Veličković, Sava and Popović, Aleksandar R.",
year = "2014",
abstract = "Polystyrene graft corn starch copolymers (PS-g-starch) were synthesized by emulsion polymerization using sodium dodecylsulfate (SDS) as the emulsifier and potassium persulfate (PPS) as the initiator. Influences of temperature (25-75 A degrees C), monomer (0.56-0.96 mol/dm(3)) and initiator (0.007-0.020 mol/dm(3)) concentration, reaction time (15-300 min), and type of amine activator and its concentration (0.005-0.08 mol/dm(3)) on the percentage of grafting (G, %) and yield (Y, %) were investigated. Amines showed dual impact on grafting reaction, some of them were activators and other were inhibitors, where N,N-dimethylethanolamine gave the maximal and 1-(2-hydroxyethyl) piperazine gave the minimal value of percentage of grafting. The maximum percentage of grafting was 32.55 %, while in case of piperazine derivate percentage of grafting was zero. Successful grafting was confirmed by Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM). The maximum percentage of grafting was obtained under the following reaction conditions: 10.00 g of starch, monomer concentration was 0.96 mol/dm(3), initiator concentration was 0.015 mol/dm(3), reaction time was 15 min, temperature of 75 A degrees C, and N,N-dimethylethanolamine was used as activator in concentration of 0.01 mol/dm(3).",
publisher = "Springer, Dordrecht",
journal = "Journal of Polymer Research",
title = "Influence of amine activators and reaction parameters on grafting reaction between polystyrene and starch",
number = "2",
pages = "363",
volume = "21",
doi = "10.1007/s10965-014-0363-1"
}
Nikolić, V., Veličković, S.,& Popović, A. R.. (2014). Influence of amine activators and reaction parameters on grafting reaction between polystyrene and starch. in Journal of Polymer Research
Springer, Dordrecht., 21(2), 363.
https://doi.org/10.1007/s10965-014-0363-1
Nikolić V, Veličković S, Popović AR. Influence of amine activators and reaction parameters on grafting reaction between polystyrene and starch. in Journal of Polymer Research. 2014;21(2):363.
doi:10.1007/s10965-014-0363-1 .
Nikolić, Vladimir, Veličković, Sava, Popović, Aleksandar R., "Influence of amine activators and reaction parameters on grafting reaction between polystyrene and starch" in Journal of Polymer Research, 21, no. 2 (2014):363,
https://doi.org/10.1007/s10965-014-0363-1 . .
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Biodegradation of starch-graft-polystyrene and starch-graft-poly(methacrylic acid) copolymers in model river water

Nikolić, Vladimir; Veličković, Sava; Antonović, Dušan G.; Popović, Aleksandar R.

(Serbian Chemical Soc, Belgrade, 2013)

TY  - JOUR
AU  - Nikolić, Vladimir
AU  - Veličković, Sava
AU  - Antonović, Dušan G.
AU  - Popović, Aleksandar R.
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5678
AB  - In this paper, a biodegradation study of grafted copolymers of cornstarch and polystyrene (PS) and cornstarch and poly(methacrylic acid) in model river water is described. These copolymers were obtained in the presence of different amine activators. The synthesized copolymers and products of degradation were characterized by Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). Biodegradation was monitored by mass decrease and the number of microorganisms by the Koch method. Biodegradation of both copolymers advanced with time, the starch-graft-poly(methacrylic acid) copolymers had completely degraded after 21 day, and the starch graft polystyrene had partially degraded (45.8-93.1 % mass loss) after 27 days. The differences in the degree of biodegradation are the consequences of the different structures of the samples, and there was a significant negative correlation between the share of polystyrene in the copolymer and the degree of biodegradation. The grafting degree of PS necessary to prevent biodegradation was 54 %. Based on experimental evidence, the mechanisms of both biodegradation processes are proposed, and influence of degree of starch and synthetic component of copolymers on the degradation of the samples were established.
AB  - U ovom radu proučavana je biodegradacija kalemljenih kopolimera kukuruznog skroba i polistirena i kukuruznog skroba i poli(metakrilne kiseline) u rečnoj vodi. Ovi kopolimeri su sintetisani u prisustvu različitih aminoaktivatora. Sintetisani kopolimeri i produkta biodegradacije su karakterisani FTIR spektroskopijom i SEM mikroskopijom. Biodegradacija je praćena gubitkom mase uzoraka, a broj mikroorganizama Kohovom metodom. Stepen biodegradacije obe vrste kopolimera raste sa vremenom. Kalemljeni polimeri skroba i poli(metakrilne kiseline) potpuno se razgrađuju za 21 dan, dok se polimeri na bazi skroba i polistirena delimično razgrađuju nakon 27 dana (45,8-93,1 % od ukupne mase). Razlike u stepenu biodegradacije su posledica različite strukture uzoraka, a postoji i značajna negativna korelacija između udela polistirena u kopolimeru i stepena biodegradacije. Stepen kalemljenja polistirena (udeo polistirena u kopolimeru) koji sprečava biodegradaciju iznosio je 54 %. Na osnovu eksperimentalnih dokaza, predloženi su mehanizmi oba biodegradaciona procesa i ustanovljeni su uticaji količine skroba i sintetske komponente kopolimera na biodegradaciju.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Biodegradation of starch-graft-polystyrene and starch-graft-poly(methacrylic acid) copolymers in model river water
T1  - Biodegradacija kalemljenih kopolimera skroba i polistirena i skroba i poli(metakrilne kiseline) u rečnoj vodi
EP  - 1441
IS  - 9
SP  - 1425
VL  - 78
DO  - 10.2298/JSC121216051N
ER  - 
@article{
author = "Nikolić, Vladimir and Veličković, Sava and Antonović, Dušan G. and Popović, Aleksandar R.",
year = "2013",
abstract = "In this paper, a biodegradation study of grafted copolymers of cornstarch and polystyrene (PS) and cornstarch and poly(methacrylic acid) in model river water is described. These copolymers were obtained in the presence of different amine activators. The synthesized copolymers and products of degradation were characterized by Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). Biodegradation was monitored by mass decrease and the number of microorganisms by the Koch method. Biodegradation of both copolymers advanced with time, the starch-graft-poly(methacrylic acid) copolymers had completely degraded after 21 day, and the starch graft polystyrene had partially degraded (45.8-93.1 % mass loss) after 27 days. The differences in the degree of biodegradation are the consequences of the different structures of the samples, and there was a significant negative correlation between the share of polystyrene in the copolymer and the degree of biodegradation. The grafting degree of PS necessary to prevent biodegradation was 54 %. Based on experimental evidence, the mechanisms of both biodegradation processes are proposed, and influence of degree of starch and synthetic component of copolymers on the degradation of the samples were established., U ovom radu proučavana je biodegradacija kalemljenih kopolimera kukuruznog skroba i polistirena i kukuruznog skroba i poli(metakrilne kiseline) u rečnoj vodi. Ovi kopolimeri su sintetisani u prisustvu različitih aminoaktivatora. Sintetisani kopolimeri i produkta biodegradacije su karakterisani FTIR spektroskopijom i SEM mikroskopijom. Biodegradacija je praćena gubitkom mase uzoraka, a broj mikroorganizama Kohovom metodom. Stepen biodegradacije obe vrste kopolimera raste sa vremenom. Kalemljeni polimeri skroba i poli(metakrilne kiseline) potpuno se razgrađuju za 21 dan, dok se polimeri na bazi skroba i polistirena delimično razgrađuju nakon 27 dana (45,8-93,1 % od ukupne mase). Razlike u stepenu biodegradacije su posledica različite strukture uzoraka, a postoji i značajna negativna korelacija između udela polistirena u kopolimeru i stepena biodegradacije. Stepen kalemljenja polistirena (udeo polistirena u kopolimeru) koji sprečava biodegradaciju iznosio je 54 %. Na osnovu eksperimentalnih dokaza, predloženi su mehanizmi oba biodegradaciona procesa i ustanovljeni su uticaji količine skroba i sintetske komponente kopolimera na biodegradaciju.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Biodegradation of starch-graft-polystyrene and starch-graft-poly(methacrylic acid) copolymers in model river water, Biodegradacija kalemljenih kopolimera skroba i polistirena i skroba i poli(metakrilne kiseline) u rečnoj vodi",
pages = "1441-1425",
number = "9",
volume = "78",
doi = "10.2298/JSC121216051N"
}
Nikolić, V., Veličković, S., Antonović, D. G.,& Popović, A. R.. (2013). Biodegradation of starch-graft-polystyrene and starch-graft-poly(methacrylic acid) copolymers in model river water. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 78(9), 1425-1441.
https://doi.org/10.2298/JSC121216051N
Nikolić V, Veličković S, Antonović DG, Popović AR. Biodegradation of starch-graft-polystyrene and starch-graft-poly(methacrylic acid) copolymers in model river water. in Journal of the Serbian Chemical Society. 2013;78(9):1425-1441.
doi:10.2298/JSC121216051N .
Nikolić, Vladimir, Veličković, Sava, Antonović, Dušan G., Popović, Aleksandar R., "Biodegradation of starch-graft-polystyrene and starch-graft-poly(methacrylic acid) copolymers in model river water" in Journal of the Serbian Chemical Society, 78, no. 9 (2013):1425-1441,
https://doi.org/10.2298/JSC121216051N . .
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Amine activators influence on grafting reaction between methacrylic acid and starch

Nikolić, Vladimir; Veličković, Sava; Popović, Aleksandar R.

(Elsevier Sci Ltd, Oxford, 2012)

TY  - JOUR
AU  - Nikolić, Vladimir
AU  - Veličković, Sava
AU  - Popović, Aleksandar R.
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5665
AB  - The aim of this work was synthesis of grafted copolymers of poly(methacrylic acid) and starch (PMAA-graft-starch) with high percentage of grafting, G (%). The effect of temperature (55-75 degrees C), concentration of methacrylic acid monomer (0.775-1.452 mol/dm(3)), amount of initiator potassium persulfate (PPS) (0.00075-0.0025 mol), reaction time (30-270 min) and nature and amount (0.001-0.005 mol) of amine activator on percentage of grafting were investigated. The following amine activators were used: N,N-dimethylaminoethanol. N,N-diethylaminoethanol, triethylamine, propylamine, iso-butylamine, pentylamine, hexylamine, 4-(2-hidroxyethyl) morpholine and 1-(2-hidroxyethyl) piperazine. The graft copolymer was characterized by Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy. The highest G was 40.92%. Reaction conditions were as follows: 10.00 g of starch, monomer concentration was 0.775 mol/dm(3), temperature of 70 degrees C, the amount of PPS was 0.001 mol. The 4-(2-hidroxyethyl) morpholine was used as amine activator in amount of 0.001 mol. (C) 2012 Elsevier Ltd. All rights reserved.
PB  - Elsevier Sci Ltd, Oxford
T2  - Carbohydrate Polymers
T1  - Amine activators influence on grafting reaction between methacrylic acid and starch
EP  - 1413
IS  - 4
SP  - 1407
VL  - 88
DO  - 10.1016/j.carbpol.2012.02.027
ER  - 
@article{
author = "Nikolić, Vladimir and Veličković, Sava and Popović, Aleksandar R.",
year = "2012",
abstract = "The aim of this work was synthesis of grafted copolymers of poly(methacrylic acid) and starch (PMAA-graft-starch) with high percentage of grafting, G (%). The effect of temperature (55-75 degrees C), concentration of methacrylic acid monomer (0.775-1.452 mol/dm(3)), amount of initiator potassium persulfate (PPS) (0.00075-0.0025 mol), reaction time (30-270 min) and nature and amount (0.001-0.005 mol) of amine activator on percentage of grafting were investigated. The following amine activators were used: N,N-dimethylaminoethanol. N,N-diethylaminoethanol, triethylamine, propylamine, iso-butylamine, pentylamine, hexylamine, 4-(2-hidroxyethyl) morpholine and 1-(2-hidroxyethyl) piperazine. The graft copolymer was characterized by Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy. The highest G was 40.92%. Reaction conditions were as follows: 10.00 g of starch, monomer concentration was 0.775 mol/dm(3), temperature of 70 degrees C, the amount of PPS was 0.001 mol. The 4-(2-hidroxyethyl) morpholine was used as amine activator in amount of 0.001 mol. (C) 2012 Elsevier Ltd. All rights reserved.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Carbohydrate Polymers",
title = "Amine activators influence on grafting reaction between methacrylic acid and starch",
pages = "1413-1407",
number = "4",
volume = "88",
doi = "10.1016/j.carbpol.2012.02.027"
}
Nikolić, V., Veličković, S.,& Popović, A. R.. (2012). Amine activators influence on grafting reaction between methacrylic acid and starch. in Carbohydrate Polymers
Elsevier Sci Ltd, Oxford., 88(4), 1407-1413.
https://doi.org/10.1016/j.carbpol.2012.02.027
Nikolić V, Veličković S, Popović AR. Amine activators influence on grafting reaction between methacrylic acid and starch. in Carbohydrate Polymers. 2012;88(4):1407-1413.
doi:10.1016/j.carbpol.2012.02.027 .
Nikolić, Vladimir, Veličković, Sava, Popović, Aleksandar R., "Amine activators influence on grafting reaction between methacrylic acid and starch" in Carbohydrate Polymers, 88, no. 4 (2012):1407-1413,
https://doi.org/10.1016/j.carbpol.2012.02.027 . .
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