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Rhizopus arrhizus lipase-catalyzed interesterification of palm oil midfraction in a gas-lift reactor
(Elsevier Science Inc, New York, 1994)
Celite-immobilized lipase from Rhizopus arrhizus was encapsulated in lecithin reverse micelles and used to interesterify triacylglycerols of palm oil midfraction with stearic acid in n-hexane. The reaction kinetics were ...
CdS nanoclusters: Synthesis, characterization, size dependent oscillator strength, temperature shift of the excitonic transition energy, and reversible absorbance shift
(Journal of Physical Chemistry, 1994)
Improved synthetic routes and size-selective precipitation have enabled the preparation of almost monodisperse CdS clusters. Six samples of 1-thioglycerol stabilized clusters with diameters of approximately 13, 14, 16, 19, ...
The homogeneous photopolymerization of methyl methacrylate by colloidal cadmium sulfide
(Wiley-VCH Verlag Gmbh, Weinheim, 1994)
A completely new method of initiating the homogeneous radical polymerization of methyl methacrylate in bulk or in solution via the photogeneration of an electron hole pair in colloidal cadmium sulfide is presented. A ...
The photopolymerisation of methacrylic acid by colloidal semiconductors
(Springer, New York, 1994)
Methacrylic acid was photopolymerised using CdS and composite, CdS/HgS and CdS/TiO2, colloidal semiconductor particles as initiators. The previously proposed photoinitiation mechanism involving the photogenerated positive ...
Microscopic modelling of electrothermal desorption
(The Chemical Engineering Journal and The Biochemical Engineering Journal, 1994)
A mathematical model of thermal desorption with internal electroresistive heating of the adsorbent is postulated for a single particle. Three parallel mechanisms are considered: surface diffusion, pore diffusion and thermal ...
Local and overall mixing characteristics of the gas-liquid-solid air-lift reactor
(Amer Chemical Soc, Washington, 1994)
Local and overall mixing characteristics were studied for the gas-liquid-solid reactor operating with an internal draft tube and low-density particles. The experimental reactor had a working volume of 7.6 L, column diameter ...
On the possibility of the direct preparation of the sodium salt of copper phthalocyanine-4-sulfonic acid
(Serbian Chemical Society, 1994)
The reaction of a 1:3 molar mixture of the monosodium salt of 4-sulfophthalic acid and phthalic acod, carried out in the presence of NH4Cl, urea, CuSO4 5H2O, and (NH4)2MoO4, does not yield the mono-substituted derivative, ...
A cobalt(II) complex with ethylenediamine inside zeolite A
(Slovenian Chemical Society, 1994)
Reaction of the partially dehydrated cobalt(II)-exchanged zeolite A (Co-A) with ethylenediamine (en) at 130 C in an autoclave yields after 24 h a product (Coen-A) in which entire Co(II) content (tetrahedrally coordinated ...
Infinite dilution activity coefficients of organic solutes in N,N-diethyldodecanamide
(Amer Chemical Soc, Washington, 1994)
Infinite dilution activity coefficients of pentane, hexane, heptane, cyclohexane, benzene, tetrachloromethane, dichloromethane, diethyl ether, tetrahydrofuran, acetone, ethyl acetate and methanol in N,N-diethyldodecanamide ...
Oxygen reduction on iron-Part VI. Processes in alkaline solutions
(Pergamon-Elsevier Science Ltd, Oxford, 1994)
The kinetics of oxygen reduction were studied on passivated iron in borate buffered and unbuffered solutions of pH ranging from 7.4 to 13.8. A rotating disk electrode was employed. The O2 reduction on iron under these ...