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The origin of high activity of Pt-Au surfaces in the formic acid oxidation
(Pergamon-Elsevier Science Ltd, Oxford, 2009)
We have investigated the oxidation of HCOOH on Au-modified Pt (Au"Pt) and Pt-modified Au (Pt")/Au) electrodes to establish the role of the ensemble and the electronic effect in the catalysis of this reaction. The surfaces ...
The effect of the electrode surface roughness at low level of coarseness on the polarization characteristics of electrochemical processes
(Pergamon-Elsevier Science Ltd, Oxford, 2010)
In this study, it is considered: (a) the effect of the exchange current density to the limiting diffusion current density ratio (J(0)/J(L)) at low level of surface coarseness on the polarization characteristics of the ...
Hydrogen peroxide oxidation on passive iron in alkaline solutions
(Pergamon-Elsevier Science Ltd, Oxford, 1992)
The kinetics of hydrogen peroxide oxidation were studied on passive iron in alkaline solutions of pH ranging from 9.8 to 13.8, using the rotating disk electrode. Measurements were taken using the linear sweep technique. ...
Kinetics of the hydrogen evolution reaction on Fe-Mo film deposited on mild steel support in alkaline solution
(Pergamon-Elsevier Science Ltd, Oxford, 2005)
The mechanism and kinetics of the hydrogen evolution reaction were studied. in 1.0 mol dm(-3) NaOH solution on Fe-Mo alloy electrodes prepared by electrodeposition at constant current densities from a pyrophosphate bath. ...
Pt supported on nano-tungsten carbide as a beneficial catalyst for the oxygen reduction reaction in alkaline solution
(Elsevier, 2012)
Platinum nanocatalyst at nano-tungsten carbide was synthesized, characterized and tested for oxygen reduction reaction (ORR) in 0.1 mol dm−3 NaOH, at 25 °C. Tungsten-carbide islands on nano-tungsten particles (WC) was ...
Voltammetric and differential pulse determination of roxithromycin
(Pergamon-Elsevier Science Ltd, Oxford, 2010)
The oxidative behavior of antibiotic roxithromycin standard was studied at a gold electrode in 0.05 M NaHCO3 using cyclic linear sweep voltammetry and differential pulse voltammetry. It was found that the value of the ...
Electrooxidation of H-2, CO and H-2/CO mixtures on a well-characterized Pt-Re bulk alloy electrode and comparison with other Pt binary alloys
(Pergamon-Elsevier Science Ltd, Oxford, 1998)
We report new results for the electrooxidation of Hz, CO and H-2/CO mixtures on a Pt75Re25 bulk alloy using surface preparation in a UHV chamber and characterization by X-ray photoelectron spectroscopy (XPS). Sputter-cleaned ...
UPD of Cu on Pt(100): effects of anions on adsorption isotherms and interface structures
(Pergamon-Elsevier Science Ltd, Oxford, 1998)
The results presented in this study show definitely that copper deposition in perchloric acid is a very slow, kinetically controlled process. In nearly halide free supporting electrolytes du appeared to be deposited at ...
Corrosion protection of mild steel by polypyrrole coatings in acid sulfate solutions
(Pergamon-Elsevier Science Ltd, Oxford, 1997)
The corrosion behaviour of mild steel covered by the electrodeposited polypyrrole films was investigated by electrochemical impedance spectroscopy. Electrodeposition of polypyrrole was performed from aqueous solution of ...
Hydrogen evolution at Zn-Ni alloys
(Pergamon-Elsevier Science Ltd, Oxford, 1998)
Zn-Ni alloys were electrodeposited from a berate-citrate and TEPA bath in potentiostatic and galvanostatic regimes. Potential of electrodeposition or current density were varied and chemical composition and phase structure ...