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Physical and mathematical models of an inert macroelectrode modified with active hemispherical microelectrodes
(Pergamon-Elsevier Science Ltd, Oxford, 2007)
The physical model of an inert electrode partially activated with hemispherical microelectrodes was formed by the deposition of silver grains on a graphite substrate. It is shown that the process on the microelectrodes can ...
Hydrogen evolution at Zn-Ni alloys
(Pergamon-Elsevier Science Ltd, Oxford, 1998)
Zn-Ni alloys were electrodeposited from a berate-citrate and TEPA bath in potentiostatic and galvanostatic regimes. Potential of electrodeposition or current density were varied and chemical composition and phase structure ...
Methanol electrooxidation on supported Pt and PtRu catalysts in acid and alkaline solutions
(Pergamon-Elsevier Science Ltd, Oxford, 2002)
The kinetics of methanol oxidation on supported 47.5 wt.% Pt and 54 wt.% Pt-Ru (with nominal Pt:Ru ratios of 2:3) catalysts are measured in 0.5 M H2SO4 and 0.1 NaOH at 295 and 333 K using thin-film rotating disk electrode ...
Corrosion protection of mild steel by polypyrrole coatings in acid sulfate solutions
(Pergamon-Elsevier Science Ltd, Oxford, 1997)
The corrosion behaviour of mild steel covered by the electrodeposited polypyrrole films was investigated by electrochemical impedance spectroscopy. Electrodeposition of polypyrrole was performed from aqueous solution of ...
UPD of Cu on Pt(100): effects of anions on adsorption isotherms and interface structures
(Pergamon-Elsevier Science Ltd, Oxford, 1998)
The results presented in this study show definitely that copper deposition in perchloric acid is a very slow, kinetically controlled process. In nearly halide free supporting electrolytes du appeared to be deposited at ...
Voltammetric and differential pulse determination of roxithromycin
(Pergamon-Elsevier Science Ltd, Oxford, 2010)
The oxidative behavior of antibiotic roxithromycin standard was studied at a gold electrode in 0.05 M NaHCO3 using cyclic linear sweep voltammetry and differential pulse voltammetry. It was found that the value of the ...
Comparative studies of chloride and chloride/citrate based electrolytes for zinc-polyaniline batteries
(Pergamon-Elsevier Science Ltd, Oxford, 2006)
Electrochemical behavior of zinc and thin polyaniline (PANI) polymerized from 0.1 M HCl to 0.1 M aniline on graphite electrode, in 0.2 M ZnCl(2) and 0.50 M NH(4)Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate ...
Effect of chemisorbed carbon monoxide on Pt/C electrode on the mechanism of the hydrogen oxidation reaction
(Elsevier, 2009)
The influence of poisoning of Pt catalyst by CO on the kinetics and mechanism of H2 oxidation reaction (HOR) at Pt/C electrode in 0.5 mol dm-3 HClO4, saturated with H2 containing 100 ppm CO, was examined with rotating disc ...
Catalysis of oxygen reduction on Au modified by Pd nanoislands in perchloric acid solution
(Pergamon-Elsevier Science Ltd, Oxford, 2012)
Oxygen reduction reaction (ORR) was studied on polycrystalline gold, Au(poly), modified by nanosized palladium islands in 0.1 M HClO4 solution using rotating disc electrode technique. Paladium was spontaneously deposited ...