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Mass transfer effect in electrochemical oxidation of methanol at platinum electrocatalysts
(Elsevier Science Sa, Lausanne, 2004)
The influence of the mass transfer on the electrochemical oxidation of methanol was investigated at a rotating disk electrode with smooth polycrystalline Pt and high area carbon supported Pt (Pt/C) as the electrocatalysts. ...
Electrochemically deposited iridium-oxide: Estimation of intrinsic activity and stability in oxygen evolution in acid solution
(Journal of Electroanalytical Chemistry, 2021)
Hydrated iridiumoxyhydroxide (IrOx) films were electrochemically deposited from an alkaline oxalic solution at constant anodic potentials and by applying a potential cycling protocol, in both cases with variation of the ...
Oxygen reduction on iron. Part III. An analysis of the rotating disk-ring electrode measurements in near neutral solutions
(Elsevier Science Sa, Lausanne, 1989)
The kinetics of oxygen reduction were studied on iron in borate and bicarbonate buffered solutions, pH 9.8, using the rotating disk-ring method. Under these conditions O2 reduction occurs both on the oxidized surface and ...
Kinetics of the oxygen evolution reaction on NiSn electrodes in alkaline solutions
(Elsevier Science Sa, Lausanne, 2015)
In order to examine the intrinsic catalytic activity and durability of the electrodeposited NiSn alloy electrodes and the electrodeposited Ni as a reference electrode material for the oxygen evolution reaction (OER) in ...
Kinetic study of formic acid oxidation on carbon-supported platinum electrocatalyst
(Elsevier Science Sa, Lausanne, 2005)
Oxidation of formic acid on the platinum catalyst supported on high area carbon was investigated by potent iodynamic and quasi-steady-state polarization measurements. It was found that the poisoning of the reaction occurred ...
The kinetics of the hydrogen evolution reaction on zinc in EDTA solutions in the pH 3-10 range
(Elsevier Science Sa, Lausanne, 2003)
Polarization curves of the hydrogen evolution reaction on zinc were obtained in Ethylenediaminetetraacetic acid (EDTA) solutions of different total molar concentrations (0.05, 0.10, 0.15 and 0.20 mol dm(-3)), the pH values ...
The electrochemical reduction of trinitrotoluene on a platinum wire modified by chemisorbed acetonitrile
(Elsevier, 2010)
The electrochemical reduction of 2,4,6-trinitrotoluene (TNT) was investigated by cyclic voltammetry on a platinum electrode in aqueous sodium chloride solutions with acetonitrile containing different concentrations of TNT. ...
The effect of hydrogen codeposition on the morphology of copper electrodeposits. 1. The concept of effective overpotential
(Elsevier, 2006)
The effect of hydrogen codeposition on the morphology of copper electrodeposits was studied. The dependences of the overall current and the volume of evolved hydrogen on the quantity of electricity used were plotted and ...
Palladium-copper bimetallic surfaces as electrocatalysts for the ethanol oxidation in an alkaline medium
(Elsevier B.V., 2023)
Two types of Cu-modified Pd catalysts supported on high area carbon were prepared: Pd nanoparticles modified with a sub-monolayer of underpotentially deposited Cu (Cu@Pd/C) and Pd-Cu alloy nanoparticles (Pd-Cu/C), and ...
Experimental study of zinc morphology in alkaline electrolyte at low direct and pulsating overpotentials
(Elsevier Sequoia SA, 2000)
A possible mechanism of the formation of spongy zinc electrodeposits is considered. The confirmation of the proposed semiquantitative mathematical model is performed in zinc electrodeposition onto copper wire from a 0.1 M ...