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Transition metal complexes with thiosemicarbazide-based ligands. LIII. [4-(2-Diphenylphosphino-a-ethoxybenzyl-κP)-S-methyl-1-(4-oxidopent-3-en-4- ylidene-κO)-thiosemicarbazido-κ 2 N 1 ,N 4 ]nickel(II)
(International Union of Crystallography, 2006)
The title compound, [Ni(C 28 H 30 N 3 O 2 PS)], crystallizes with two independent molecules in the asymmetric unit. The Ni II atoms are in significantly deformed square-planar environments formed by an ONNP donor set from ...