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Investigation of the reactivity of 4-pyrimidinecarboxylic, 6-hydroxy-4-pyrimidinecarboxylic and 5-hydroxyorotic acids with diazodiphenylmethane in various alcohols: Part III

Ispitivanje reaktivnosti 4-pirimidinkarboksilne, 6-hidroksi-4-pirimidinkarboksilne i 5-hidroksiorotinske kiseline sa diazodifenilmetanom u različitim alkoholima

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Authors
Assaleh, Fathi H.
Marinković, Aleksandar
Drmanić, Saša
Jovanović, Bratislav Ž.
Article (Published version)
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Abstract
Rate constants for the reaction of diazodiphenylmethane (DDM) with 4-pyrimidinecarboxylic, 6-hydroxy-4-pyrimidinecarboxylic and 5-hydroxyorotic acids were determined in twelve protic solvents at 30 °C using the well known UV-spectrophotometric method. The second order rate contants for the examined acids were correlated using the appropriate solvent parameters by the equation log k = log k0 + af(e) + bs * + cngH were f(e) is the Kirkwood function of relative permittivity [(e-l)/(2e + 1 )], s * is the Taft polar constant for the alkyl group R in the alcohol ROH, and nyH is themumber of hydrogen atoms in the (-position in the alcohol. The results obtained for the investigated acids were compared with the corresponding results for benzoic, 2- and 3-hydroxybenzoic acids and the influence of the structure of the investigated acids on the reactivity in hydroxylic solvents is discussed. It was also possible to evaluate and distinguish the specific and non-specific solvent effects and their in...fluence on the reaction rate.

Konstante brzina reakcija diazodifenilmetana (DDM) sa 4-pirimidinkarboksilnom, 6-hidroksi-4-pirimidinkarboksilnom i 5-hidroksiorotinskom kiselinom su određene u dvanaest protičnih rastvarača na 30 °C korišćenjem poznate UV-spektrofotometrijske metode. Konstante brzina reakcija drugog reda su korelisane sa odgovarajućim parametrima rastvarača korišćenjem solvatohromne jednačine u sledećem obliku: k = log k0 + af(e) + bs * + cngH gde je broj f(e) Kirkwood-ova funkcija permittivity [(e-l)/(2e + 1 )] relativne permitivnosti,, s * je Taft-ova konstanta alkil-grupe R alkohola ROH, i nyH je broj (-vodonikovih atoma. Dobijeni rezultati su poređeni sa rezultatima korelacija za benzoevu, kao i 2- i 3-hidroksibenzoevu kiselinu kako bi se diskutovao uticaj strukture ispitivanih kiselina u hidroksilnim rastvaračima na njihovu reaktivnost. Takođe su procenjeni specifični i nespecifični efekti rastvarača i njihov uticaj na brzinu ispitivanih reakcija.
Keywords:
rate constants / 5-hydroxyorotic acid / 6-hydroxy-4-pyrimidinecarboxylicacid / 4-pyrimidinecarboxylic acid
Source:
Journal of the Serbian Chemical Society, 2007, 72, 3, 205-214
Publisher:
  • Serbian Chemical Society, Belgrade

ISSN: 0352-5139

WoS: 000246168500001

Scopus: 2-s2.0-34249101911
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URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1190
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Assaleh, Fathi H.
AU  - Marinković, Aleksandar
AU  - Drmanić, Saša
AU  - Jovanović, Bratislav Ž.
PY  - 2007
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1190
AB  - Rate constants for the reaction of diazodiphenylmethane (DDM) with 4-pyrimidinecarboxylic, 6-hydroxy-4-pyrimidinecarboxylic and 5-hydroxyorotic acids were determined in twelve protic solvents at 30 °C using the well known UV-spectrophotometric method. The second order rate contants for the examined acids were correlated using the appropriate solvent parameters by the equation log k = log k0 + af(e) + bs * + cngH were f(e) is the Kirkwood function of relative permittivity [(e-l)/(2e + 1 )], s * is the Taft polar constant for the alkyl group R in the alcohol ROH, and nyH is themumber of hydrogen atoms in the (-position in the alcohol. The results obtained for the investigated acids were compared with the corresponding results for benzoic, 2- and 3-hydroxybenzoic acids and the influence of the structure of the investigated acids on the reactivity in hydroxylic solvents is discussed. It was also possible to evaluate and distinguish the specific and non-specific solvent effects and their influence on the reaction rate.
AB  - Konstante brzina reakcija diazodifenilmetana (DDM) sa 4-pirimidinkarboksilnom, 6-hidroksi-4-pirimidinkarboksilnom i 5-hidroksiorotinskom kiselinom su određene u dvanaest protičnih rastvarača na 30 °C korišćenjem poznate UV-spektrofotometrijske metode. Konstante brzina reakcija drugog reda su korelisane sa odgovarajućim parametrima rastvarača korišćenjem solvatohromne jednačine u sledećem obliku: k = log k0 + af(e) + bs * + cngH gde je broj f(e) Kirkwood-ova funkcija permittivity [(e-l)/(2e + 1 )] relativne permitivnosti,, s * je Taft-ova konstanta alkil-grupe R alkohola ROH, i nyH je broj (-vodonikovih atoma. Dobijeni rezultati su poređeni sa rezultatima korelacija za benzoevu, kao i 2- i 3-hidroksibenzoevu kiselinu kako bi se diskutovao uticaj strukture ispitivanih kiselina u hidroksilnim rastvaračima na njihovu reaktivnost. Takođe su procenjeni specifični i nespecifični efekti rastvarača i njihov uticaj na brzinu ispitivanih reakcija.
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Investigation of the reactivity of 4-pyrimidinecarboxylic, 6-hydroxy-4-pyrimidinecarboxylic and 5-hydroxyorotic acids with diazodiphenylmethane in various alcohols: Part III
T1  - Ispitivanje reaktivnosti 4-pirimidinkarboksilne, 6-hidroksi-4-pirimidinkarboksilne i 5-hidroksiorotinske kiseline sa diazodifenilmetanom u različitim alkoholima
EP  - 214
IS  - 3
SP  - 205
VL  - 72
UR  - conv_608
ER  - 
@article{
author = "Assaleh, Fathi H. and Marinković, Aleksandar and Drmanić, Saša and Jovanović, Bratislav Ž.",
year = "2007",
abstract = "Rate constants for the reaction of diazodiphenylmethane (DDM) with 4-pyrimidinecarboxylic, 6-hydroxy-4-pyrimidinecarboxylic and 5-hydroxyorotic acids were determined in twelve protic solvents at 30 °C using the well known UV-spectrophotometric method. The second order rate contants for the examined acids were correlated using the appropriate solvent parameters by the equation log k = log k0 + af(e) + bs * + cngH were f(e) is the Kirkwood function of relative permittivity [(e-l)/(2e + 1 )], s * is the Taft polar constant for the alkyl group R in the alcohol ROH, and nyH is themumber of hydrogen atoms in the (-position in the alcohol. The results obtained for the investigated acids were compared with the corresponding results for benzoic, 2- and 3-hydroxybenzoic acids and the influence of the structure of the investigated acids on the reactivity in hydroxylic solvents is discussed. It was also possible to evaluate and distinguish the specific and non-specific solvent effects and their influence on the reaction rate., Konstante brzina reakcija diazodifenilmetana (DDM) sa 4-pirimidinkarboksilnom, 6-hidroksi-4-pirimidinkarboksilnom i 5-hidroksiorotinskom kiselinom su određene u dvanaest protičnih rastvarača na 30 °C korišćenjem poznate UV-spektrofotometrijske metode. Konstante brzina reakcija drugog reda su korelisane sa odgovarajućim parametrima rastvarača korišćenjem solvatohromne jednačine u sledećem obliku: k = log k0 + af(e) + bs * + cngH gde je broj f(e) Kirkwood-ova funkcija permittivity [(e-l)/(2e + 1 )] relativne permitivnosti,, s * je Taft-ova konstanta alkil-grupe R alkohola ROH, i nyH je broj (-vodonikovih atoma. Dobijeni rezultati su poređeni sa rezultatima korelacija za benzoevu, kao i 2- i 3-hidroksibenzoevu kiselinu kako bi se diskutovao uticaj strukture ispitivanih kiselina u hidroksilnim rastvaračima na njihovu reaktivnost. Takođe su procenjeni specifični i nespecifični efekti rastvarača i njihov uticaj na brzinu ispitivanih reakcija.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Investigation of the reactivity of 4-pyrimidinecarboxylic, 6-hydroxy-4-pyrimidinecarboxylic and 5-hydroxyorotic acids with diazodiphenylmethane in various alcohols: Part III, Ispitivanje reaktivnosti 4-pirimidinkarboksilne, 6-hidroksi-4-pirimidinkarboksilne i 5-hidroksiorotinske kiseline sa diazodifenilmetanom u različitim alkoholima",
pages = "214-205",
number = "3",
volume = "72",
url = "conv_608"
}
Assaleh, F. H., Marinković, A., Drmanić, S.,& Jovanović, B. Ž.. (2007). Investigation of the reactivity of 4-pyrimidinecarboxylic, 6-hydroxy-4-pyrimidinecarboxylic and 5-hydroxyorotic acids with diazodiphenylmethane in various alcohols: Part III. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 72(3), 205-214.
conv_608
Assaleh FH, Marinković A, Drmanić S, Jovanović BŽ. Investigation of the reactivity of 4-pyrimidinecarboxylic, 6-hydroxy-4-pyrimidinecarboxylic and 5-hydroxyorotic acids with diazodiphenylmethane in various alcohols: Part III. in Journal of the Serbian Chemical Society. 2007;72(3):205-214.
conv_608 .
Assaleh, Fathi H., Marinković, Aleksandar, Drmanić, Saša, Jovanović, Bratislav Ž., "Investigation of the reactivity of 4-pyrimidinecarboxylic, 6-hydroxy-4-pyrimidinecarboxylic and 5-hydroxyorotic acids with diazodiphenylmethane in various alcohols: Part III" in Journal of the Serbian Chemical Society, 72, no. 3 (2007):205-214,
conv_608 .

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