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Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices

Authorized Users Only
2008
Authors
Radović, Ivona
Kijevčanin, Mirjana
Gabrijel, Marijan Z.
Šerbanović, Slobodan P.
Đorđević, Bojan D.
Conference object (Published version)
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Abstract
The excess molar volumes of 51 binary mixtures containing diverse groups of organic compounds: alcohols (methanol, ethanol, propan-1-ol, butan-1-ol, pentan-1-ol, hexan-1-ol, and heptan-1-ol), (cyclo-) alkanes (hexane, heptane, octane, nonane, decane, undecane, dodecane, and cyclohexane), esters (diethyl carbonate and ethyl chloroacetate), aromatics (o-xylene, m-xylene, p-xylene, and ethylbenzene), ketones (acetone), and ethers (anisole), were predicted from the refractive index data, using three types of equations coupled with several different mixing rules for refractive index calculations: the Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton, and the Oster. These systems were chosen since they belong to different classes of organic species forming molecular interactions and intermolecular forces during mixing resulting in positive or negative, smaller or larger deviations from ideal behaviour. The obtained results were analysed in terms of the applied equation and mixing ru...le, the nature of compounds of the mixtures and the influence of alkyl chain length of the alkane or alcohol molecule.

Keywords:
excess molar volume / refractive index / prediction / binary systems
Source:
Chemical Papers, 2008, 62, 3, 302-312
Publisher:
  • Versita, Warsaw
Funding / projects:
  • Primena hemijske termodinamike u fenomenima prenosa višefaznih višekomponentnih sistema (RS-142064)

DOI: 10.2478/s11696-008-0027-x

ISSN: 0366-6352

WoS: 000256026900012

Scopus: 2-s2.0-44149091498
[ Google Scholar ]
6
6
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1299
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - CONF
AU  - Radović, Ivona
AU  - Kijevčanin, Mirjana
AU  - Gabrijel, Marijan Z.
AU  - Šerbanović, Slobodan P.
AU  - Đorđević, Bojan D.
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1299
AB  - The excess molar volumes of 51 binary mixtures containing diverse groups of organic compounds: alcohols (methanol, ethanol, propan-1-ol, butan-1-ol, pentan-1-ol, hexan-1-ol, and heptan-1-ol), (cyclo-) alkanes (hexane, heptane, octane, nonane, decane, undecane, dodecane, and cyclohexane), esters (diethyl carbonate and ethyl chloroacetate), aromatics (o-xylene, m-xylene, p-xylene, and ethylbenzene), ketones (acetone), and ethers (anisole), were predicted from the refractive index data, using three types of equations coupled with several different mixing rules for refractive index calculations: the Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton, and the Oster. These systems were chosen since they belong to different classes of organic species forming molecular interactions and intermolecular forces during mixing resulting in positive or negative, smaller or larger deviations from ideal behaviour. The obtained results were analysed in terms of the applied equation and mixing rule, the nature of compounds of the mixtures and the influence of alkyl chain length of the alkane or alcohol molecule.
PB  - Versita, Warsaw
C3  - Chemical Papers
T1  - Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices
EP  - 312
IS  - 3
SP  - 302
VL  - 62
DO  - 10.2478/s11696-008-0027-x
UR  - conv_3014
ER  - 
@conference{
author = "Radović, Ivona and Kijevčanin, Mirjana and Gabrijel, Marijan Z. and Šerbanović, Slobodan P. and Đorđević, Bojan D.",
year = "2008",
abstract = "The excess molar volumes of 51 binary mixtures containing diverse groups of organic compounds: alcohols (methanol, ethanol, propan-1-ol, butan-1-ol, pentan-1-ol, hexan-1-ol, and heptan-1-ol), (cyclo-) alkanes (hexane, heptane, octane, nonane, decane, undecane, dodecane, and cyclohexane), esters (diethyl carbonate and ethyl chloroacetate), aromatics (o-xylene, m-xylene, p-xylene, and ethylbenzene), ketones (acetone), and ethers (anisole), were predicted from the refractive index data, using three types of equations coupled with several different mixing rules for refractive index calculations: the Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton, and the Oster. These systems were chosen since they belong to different classes of organic species forming molecular interactions and intermolecular forces during mixing resulting in positive or negative, smaller or larger deviations from ideal behaviour. The obtained results were analysed in terms of the applied equation and mixing rule, the nature of compounds of the mixtures and the influence of alkyl chain length of the alkane or alcohol molecule.",
publisher = "Versita, Warsaw",
journal = "Chemical Papers",
title = "Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices",
pages = "312-302",
number = "3",
volume = "62",
doi = "10.2478/s11696-008-0027-x",
url = "conv_3014"
}
Radović, I., Kijevčanin, M., Gabrijel, M. Z., Šerbanović, S. P.,& Đorđević, B. D.. (2008). Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices. in Chemical Papers
Versita, Warsaw., 62(3), 302-312.
https://doi.org/10.2478/s11696-008-0027-x
conv_3014
Radović I, Kijevčanin M, Gabrijel MZ, Šerbanović SP, Đorđević BD. Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices. in Chemical Papers. 2008;62(3):302-312.
doi:10.2478/s11696-008-0027-x
conv_3014 .
Radović, Ivona, Kijevčanin, Mirjana, Gabrijel, Marijan Z., Šerbanović, Slobodan P., Đorđević, Bojan D., "Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices" in Chemical Papers, 62, no. 3 (2008):302-312,
https://doi.org/10.2478/s11696-008-0027-x .,
conv_3014 .

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