Hydrogels based on crosslinked polymethacrylic acid were synthesized via free-radical polymerization in aqueous solution, using N,N'-methylene bisacrylamide as a crosslinking agent and 2,2'-azobis-[2-(2-imidazolin-2-yl)propane] dihydrochloride as an initiator. The influence of the reaction parameters (the neutralization degree of methacrylic acid and the initial monomer concentration) on the equilibrium swelling degree, the swelling kinetic parameters and the basic structural properties of xerogels was investigated. The change of synthesis parameters leads to the change of the basic structural parameters of xerogel, as well as the equilibrium swelling degree and the initial swelling rate of the hydrogels. It is found that there are power form relationships between the equilibrium swelling degree, the initial swelling rate and the structural xerogel's properties and the change of the neutralization degree of monomer, i.e. the monomer concentration. The examined correlations proved that ...the crosslinking density is the crucial parameter which determines all the other investigated structural and swelling parameters.
Source:
Russian Journal of Physical Chemistry A, 2009, 83, 9, 1558-1562
TY - CONF
AU - Panić, Vesna
AU - Jovanović, J.
AU - Adnađević, Borivoj
AU - Veličković, Jovan S.
PY - 2009
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1441
AB - Hydrogels based on crosslinked polymethacrylic acid were synthesized via free-radical polymerization in aqueous solution, using N,N'-methylene bisacrylamide as a crosslinking agent and 2,2'-azobis-[2-(2-imidazolin-2-yl)propane] dihydrochloride as an initiator. The influence of the reaction parameters (the neutralization degree of methacrylic acid and the initial monomer concentration) on the equilibrium swelling degree, the swelling kinetic parameters and the basic structural properties of xerogels was investigated. The change of synthesis parameters leads to the change of the basic structural parameters of xerogel, as well as the equilibrium swelling degree and the initial swelling rate of the hydrogels. It is found that there are power form relationships between the equilibrium swelling degree, the initial swelling rate and the structural xerogel's properties and the change of the neutralization degree of monomer, i.e. the monomer concentration. The examined correlations proved that the crosslinking density is the crucial parameter which determines all the other investigated structural and swelling parameters.
PB - Maik Nauka/Interperiodica/Springer, New York
C3 - Russian Journal of Physical Chemistry A
T1 - Effect of synthesis parameters on polymethacrylic acid xerogel structures and equilibrium swelling
EP - 1562
IS - 9
SP - 1558
VL - 83
DO - 10.1134/S003602440909026X
ER -
@conference{
author = "Panić, Vesna and Jovanović, J. and Adnađević, Borivoj and Veličković, Jovan S.",
year = "2009",
url = "http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1441",
abstract = "Hydrogels based on crosslinked polymethacrylic acid were synthesized via free-radical polymerization in aqueous solution, using N,N'-methylene bisacrylamide as a crosslinking agent and 2,2'-azobis-[2-(2-imidazolin-2-yl)propane] dihydrochloride as an initiator. The influence of the reaction parameters (the neutralization degree of methacrylic acid and the initial monomer concentration) on the equilibrium swelling degree, the swelling kinetic parameters and the basic structural properties of xerogels was investigated. The change of synthesis parameters leads to the change of the basic structural parameters of xerogel, as well as the equilibrium swelling degree and the initial swelling rate of the hydrogels. It is found that there are power form relationships between the equilibrium swelling degree, the initial swelling rate and the structural xerogel's properties and the change of the neutralization degree of monomer, i.e. the monomer concentration. The examined correlations proved that the crosslinking density is the crucial parameter which determines all the other investigated structural and swelling parameters.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Russian Journal of Physical Chemistry A",
title = "Effect of synthesis parameters on polymethacrylic acid xerogel structures and equilibrium swelling",
pages = "1562-1558",
number = "9",
volume = "83",
doi = "10.1134/S003602440909026X"
}
Panić, V., Jovanović, J., Adnađević, B.,& Veličković, J. S. (2009). Effect of synthesis parameters on polymethacrylic acid xerogel structures and equilibrium swelling.
Russian Journal of Physical Chemistry A
Maik Nauka/Interperiodica/Springer, New York., 83(9), 1558-1562.
https://doi.org/10.1134/S003602440909026X
Panić V, Jovanović J, Adnađević B, Veličković JS. Effect of synthesis parameters on polymethacrylic acid xerogel structures and equilibrium swelling. Russian Journal of Physical Chemistry A. 2009;83(9):1558-1562
Panić Vesna, Jovanović J., Adnađević Borivoj, Veličković Jovan S., "Effect of synthesis parameters on polymethacrylic acid xerogel structures and equilibrium swelling" Russian Journal of Physical Chemistry A, 83, no. 9 (2009):1558-1562,
https://doi.org/10.1134/S003602440909026X .
