In the present paper, a semi-empirical kinetic model for catalytic reforming has been developed. In the developed model, the component "lumping" strategy is based on a paraffins, olefins, naphthalenes, and aromatics (PONA) analysis. "Activation energy lumps" are introduced to take into account different values of activation energies within specific reaction classes. The parameters of the model have been estimated by bench marking with industrial data. Simulation results have been found to be in very close agreement with plant data. One of the advantages of the present kinetic model is that it predicts the concentration of hydrogen and light gases very well. Because it is formulated from basic principles, this kinetic model with some modification can be applied to any catalytic reformer.
TY - JOUR
AU - Stijepović, Mirko
AU - Vojvodić-Ostojić, Aleksandra
AU - Milenković, Ivan
AU - Linke, Patrick
PY - 2009
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1474
AB - In the present paper, a semi-empirical kinetic model for catalytic reforming has been developed. In the developed model, the component "lumping" strategy is based on a paraffins, olefins, naphthalenes, and aromatics (PONA) analysis. "Activation energy lumps" are introduced to take into account different values of activation energies within specific reaction classes. The parameters of the model have been estimated by bench marking with industrial data. Simulation results have been found to be in very close agreement with plant data. One of the advantages of the present kinetic model is that it predicts the concentration of hydrogen and light gases very well. Because it is formulated from basic principles, this kinetic model with some modification can be applied to any catalytic reformer.
PB - Amer Chemical Soc, Washington
T2 - Energy & Fuels
T1 - Development of a Kinetic Model for Catalytic Reforming of Naphtha and Parameter Estimation Using Industrial Plant Data
EP - 983
IS - 1-2
SP - 979
VL - 23
DO - 10.1021/ef800771x
UR - conv_3125
ER -
@article{
author = "Stijepović, Mirko and Vojvodić-Ostojić, Aleksandra and Milenković, Ivan and Linke, Patrick",
year = "2009",
abstract = "In the present paper, a semi-empirical kinetic model for catalytic reforming has been developed. In the developed model, the component "lumping" strategy is based on a paraffins, olefins, naphthalenes, and aromatics (PONA) analysis. "Activation energy lumps" are introduced to take into account different values of activation energies within specific reaction classes. The parameters of the model have been estimated by bench marking with industrial data. Simulation results have been found to be in very close agreement with plant data. One of the advantages of the present kinetic model is that it predicts the concentration of hydrogen and light gases very well. Because it is formulated from basic principles, this kinetic model with some modification can be applied to any catalytic reformer.",
publisher = "Amer Chemical Soc, Washington",
journal = "Energy & Fuels",
title = "Development of a Kinetic Model for Catalytic Reforming of Naphtha and Parameter Estimation Using Industrial Plant Data",
pages = "983-979",
number = "1-2",
volume = "23",
doi = "10.1021/ef800771x",
url = "conv_3125"
}
Stijepović, M., Vojvodić-Ostojić, A., Milenković, I.,& Linke, P.. (2009). Development of a Kinetic Model for Catalytic Reforming of Naphtha and Parameter Estimation Using Industrial Plant Data. in Energy & Fuels
Amer Chemical Soc, Washington., 23(1-2), 979-983.
https://doi.org/10.1021/ef800771x
conv_3125
Stijepović M, Vojvodić-Ostojić A, Milenković I, Linke P. Development of a Kinetic Model for Catalytic Reforming of Naphtha and Parameter Estimation Using Industrial Plant Data. in Energy & Fuels. 2009;23(1-2):979-983.
doi:10.1021/ef800771x
conv_3125 .
Stijepović, Mirko, Vojvodić-Ostojić, Aleksandra, Milenković, Ivan, Linke, Patrick, "Development of a Kinetic Model for Catalytic Reforming of Naphtha and Parameter Estimation Using Industrial Plant Data" in Energy & Fuels, 23, no. 1-2 (2009):979-983,
https://doi.org/10.1021/ef800771x .,
conv_3125 .
