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Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics
dc.creator | Panić, Vladimir | |
dc.creator | Vidaković-Koch, Tanja | |
dc.creator | Živković, Luka | |
dc.creator | Petkovska, Menka | |
dc.creator | Sundmacher, Kai | |
dc.date.accessioned | 2021-03-10T11:12:53Z | |
dc.date.available | 2021-03-10T11:12:53Z | |
dc.date.issued | 2010 | |
dc.identifier.isbn | 978-86-7132-044-3 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1545 | |
dc.description.abstract | In general, electrochemical (EC) systems are non-linear, which means they respond nonlinearly to a frequency-dependent periodic input perturbation of high amplitude imposed around a steady-state. In addition, the kinetics of EC reactions are quite complex and different rivalling model presentations can be formulated for certain EC reaction. While standard electrochemical methods (steady-state and electrochemical impedance spectroscopy) showed low sensitivity towards the model discrimination, non-linear frequency response analysis (NLFRA) of EC kinetics can appear advantageous for this purpose. In this work, NLFRA is applied in experimental and theoretical study of ferrocyanide oxidation as a model EC reaction. | en |
dc.publisher | Serbian Chemical Society, Belgrade | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.source | Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings | |
dc.subject | Electrochemical reactions | sr |
dc.subject | Kinetics | sr |
dc.subject | Ferrocyanide oxidation | sr |
dc.title | Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics | en |
dc.type | conferenceObject | |
dc.rights.license | BY | |
dc.citation.epage | 148 | |
dc.citation.other | : 145-148 | |
dc.citation.spage | 145 | |
dc.identifier.fulltext | http://TechnoRep.tmf.bg.ac.rs/bitstream/id/231/1542.pdf | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_technorep_1545 | |
dc.type.version | publishedVersion |