This paper reports the results of an FT-IR and NIR study of N-methylformamide in carbon tetrachloride solution in presence of ethers as the O-electron donors, i.e., diethyl ether (DEE), diisopropyl ether (DiPE), methyl t- -butyl ether (MtBE), dibutyl ether (DBE), dipentyl ether (DPE), tetrahydrofuran (THF) and tetrahydropyran (THP). The spectroscopic characteristics of the N-H···O hydrogen bonded complexes are given. In addition, the equilibrium constants for 1:1 complex formation were determined at 25°C using Mid-IR and NIR measurements.
Za karakterizaciju osobina molekulskih kompleksa N-metilformamida sa sedam različitih etara praćene su promene na osnovnoj valentnoj (istežućoj) traci NH vibracije i traci prvog višeg tona. Određene su spektroskopske karakteristike i konstante formiranja 1:1 molekulskih kompleksa na 25°C korišćenjem FT-IR i NIR tehnika.
TY - JOUR
AU - Jović, Branislav
AU - Nikolić, Aleksandar
AU - Davidović, Erna
AU - Petrović, Slobodan
PY - 2010
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1604
AB - This paper reports the results of an FT-IR and NIR study of N-methylformamide in carbon tetrachloride solution in presence of ethers as the O-electron donors, i.e., diethyl ether (DEE), diisopropyl ether (DiPE), methyl t- -butyl ether (MtBE), dibutyl ether (DBE), dipentyl ether (DPE), tetrahydrofuran (THF) and tetrahydropyran (THP). The spectroscopic characteristics of the N-H···O hydrogen bonded complexes are given. In addition, the equilibrium constants for 1:1 complex formation were determined at 25°C using Mid-IR and NIR measurements.
AB - Za karakterizaciju osobina molekulskih kompleksa N-metilformamida sa sedam različitih etara praćene su promene na osnovnoj valentnoj (istežućoj) traci NH vibracije i traci prvog višeg tona. Određene su spektroskopske karakteristike i konstante formiranja 1:1 molekulskih kompleksa na 25°C korišćenjem FT-IR i NIR tehnika.
PB - Serbian Chemical Society, Belgrade
T2 - Journal of the Serbian Chemical Society
T1 - N-H···O hydrogen bonding: An FT-IR, NIR study of N-methylformamide-ether systems
T1 - N-H···O vodonična veza - FT-IR i NIR spektroskopsko ispitivanje sistema N-metilformamid-etri
EP - 163
IS - 2
SP - 157
VL - 75
UR - conv_670
ER -
@article{
author = "Jović, Branislav and Nikolić, Aleksandar and Davidović, Erna and Petrović, Slobodan",
year = "2010",
abstract = "This paper reports the results of an FT-IR and NIR study of N-methylformamide in carbon tetrachloride solution in presence of ethers as the O-electron donors, i.e., diethyl ether (DEE), diisopropyl ether (DiPE), methyl t- -butyl ether (MtBE), dibutyl ether (DBE), dipentyl ether (DPE), tetrahydrofuran (THF) and tetrahydropyran (THP). The spectroscopic characteristics of the N-H···O hydrogen bonded complexes are given. In addition, the equilibrium constants for 1:1 complex formation were determined at 25°C using Mid-IR and NIR measurements., Za karakterizaciju osobina molekulskih kompleksa N-metilformamida sa sedam različitih etara praćene su promene na osnovnoj valentnoj (istežućoj) traci NH vibracije i traci prvog višeg tona. Određene su spektroskopske karakteristike i konstante formiranja 1:1 molekulskih kompleksa na 25°C korišćenjem FT-IR i NIR tehnika.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "N-H···O hydrogen bonding: An FT-IR, NIR study of N-methylformamide-ether systems, N-H···O vodonična veza - FT-IR i NIR spektroskopsko ispitivanje sistema N-metilformamid-etri",
pages = "163-157",
number = "2",
volume = "75",
url = "conv_670"
}
Jović, B., Nikolić, A., Davidović, E.,& Petrović, S.. (2010). N-H···O hydrogen bonding: An FT-IR, NIR study of N-methylformamide-ether systems. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 75(2), 157-163.
conv_670
Jović B, Nikolić A, Davidović E, Petrović S. N-H···O hydrogen bonding: An FT-IR, NIR study of N-methylformamide-ether systems. in Journal of the Serbian Chemical Society. 2010;75(2):157-163.
conv_670 .
Jović, Branislav, Nikolić, Aleksandar, Davidović, Erna, Petrović, Slobodan, "N-H···O hydrogen bonding: An FT-IR, NIR study of N-methylformamide-ether systems" in Journal of the Serbian Chemical Society, 75, no. 2 (2010):157-163,
conv_670 .
