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Influence of the way of synthesis of poly(methyl methacrylate) in the presence of surface modified TiO2 nanoparticles on the properties of obtained nanocomposites

Uticaj načina sinteze poli(metil metakrilata) u prisustvu površinski modifikovanih TiO2 nanočestica na svojstva dobijenih nanokompozita

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2010
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Authors
Džunuzović, Enis
Marinović-Cincović, Milena
Džunuzović, Jasna
Jeremić, Katarina B.
Nedeljković, Jovan
Article (Published version)
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Abstract
Incorporation of inorganic nanoparticles can significantly affect the properties of the polymer matrix. The properties of polymer nanocomposites depend on the type of incorporated nanoparticles, their size and shape, their concentration, and interactions with the polymer matrix. Homogeneity of polymer nanocomposites is influenced very much by the preparation method. In this study, TiO2 nanoparticles surface modified with 6-palmitate ascorbic acid (6-PAA) were encapsulated in poly(methyl methacrylate) (PMMA) by in situ radical polymerization of methyl methacrylate initiated by 2,2'-azobisisobutyronitrile (AIBN). The surface modification of the TiO2 nanoparticles was achieved by the formation of a charge transfer complex between TiO2 nanoparticles and 6-palmitate ascorbic acid. The radical polymerization of MMA in the presence of TiO2-PAA nanoparticles was conducted in solution (PMMA/TiO2-PAA-R), in bulk (PMMA/TiO2-PAA-M) or in suspension (PMMA/TiO2-PAA-S). The main purpose of this study... was to investigate the influence of the preparation method on the molar masses and thermal properties of PMMA/TiO2-PAA nanocomposite. It was obtained that molar masses of PMMA extracted from the composites had smaller values compared to molar masses of pure PMMA synthesized in the same manner, which indicated that TiO2-PAA nanoparticles affected the reaction of termination. Thermal properties were investigated by DSC and TGA. The values of glass transition temperature, Tg, were influenced by the way the radical polymerization was conducted, even in the case of the pure PMMA. The Tg of composite samples was always smaller than the value of the corresponding PMMA sample and the smallest value was obtained for PMMA/TiO2-PAA-M since they contained the largest amount of low molar mass residue. The TGA results showed that thermal and thermooxidative stability of polymer composites obtained in solution and in suspension was better than for the pure PMMA obtained in the same way.

Predmet ovog rada je dobijanje i karakterizacija nanokompozita kod kojih polimernu matricu čini poli(metil metakrilat) (PMMA), a kao neorgansko punilo nanočestice titan-dioksida. Svi uzorci nanokompozita dobijeni su in situ polimerizacijom preko slobodnih radikala metil metakrilata (MMA) u prisustvu čestica punila. Površinska modifikacija korišćenih nanočestica titan-dioksida izvršena je palmitatom askorbinske kiseline. Uzorci nanokompozita su pripremljeni polimerizacijom metil metakrilata u rastvoru, u masi i suspenzionom polimerizacijom. Određene su vrednosti molarne mase PMMA ekstrahovanog iz kompozitnih uzoraka i dobijeno je da su one manje od vrednosti molarne mase čistog PMMA dobijenog na isti način, na osnovu čega se može zaključiti da nanočestice TiO2-PAA prisutne u toku polimerizacije u sva tri slučaja utiču na reakcije terminacije i dovode do smanjenja molarne mase PMMA matrice. Diferencijalnom skenirajućom kalorimetrijom i termogravimetrijskom analizom utvrđeno je i da način... sinteze polimerne matrice i koncentracija čestica punila utiču na termička svojstva dobijenih polimernih nanokompozita.

Keywords:
nanocomposites / poly-(methylmethacrylate) / TiO2 / radical polymerization / nanokompoziti / poli-(metil metakrilat) / TiO2 / radikalna polimerizacija
Source:
Hemijska industrija, 2010, 64, 6, 473-489
Publisher:
  • Association of Chemical Engineers of Serbia
Funding / projects:
  • Sinteza i karakterizacija nanočestica i nanokompozita (RS-142066)
  • Sinteza i karakterizacija polimera i polimernih (nano)kompozita definisane molekulske i nadmolekulske strukture (RS-142023)

DOI: 10.2298/HEMIND100923059D

ISSN: 0367-598X

WoS: 000287224600001

Scopus: 2-s2.0-78651230854
[ Google Scholar ]
6
3
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1668
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Džunuzović, Enis
AU  - Marinović-Cincović, Milena
AU  - Džunuzović, Jasna
AU  - Jeremić, Katarina B.
AU  - Nedeljković, Jovan
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1668
AB  - Incorporation of inorganic nanoparticles can significantly affect the properties of the polymer matrix. The properties of polymer nanocomposites depend on the type of incorporated nanoparticles, their size and shape, their concentration, and interactions with the polymer matrix. Homogeneity of polymer nanocomposites is influenced very much by the preparation method. In this study, TiO2 nanoparticles surface modified with 6-palmitate ascorbic acid (6-PAA) were encapsulated in poly(methyl methacrylate) (PMMA) by in situ radical polymerization of methyl methacrylate initiated by 2,2'-azobisisobutyronitrile (AIBN). The surface modification of the TiO2 nanoparticles was achieved by the formation of a charge transfer complex between TiO2 nanoparticles and 6-palmitate ascorbic acid. The radical polymerization of MMA in the presence of TiO2-PAA nanoparticles was conducted in solution (PMMA/TiO2-PAA-R), in bulk (PMMA/TiO2-PAA-M) or in suspension (PMMA/TiO2-PAA-S). The main purpose of this study was to investigate the influence of the preparation method on the molar masses and thermal properties of PMMA/TiO2-PAA nanocomposite. It was obtained that molar masses of PMMA extracted from the composites had smaller values compared to molar masses of pure PMMA synthesized in the same manner, which indicated that TiO2-PAA nanoparticles affected the reaction of termination. Thermal properties were investigated by DSC and TGA. The values of glass transition temperature, Tg, were influenced by the way the radical polymerization was conducted, even in the case of the pure PMMA. The Tg of composite samples was always smaller than the value of the corresponding PMMA sample and the smallest value was obtained for PMMA/TiO2-PAA-M since they contained the largest amount of low molar mass residue. The TGA results showed that thermal and thermooxidative stability of polymer composites obtained in solution and in suspension was better than for the pure PMMA obtained in the same way.
AB  - Predmet ovog rada je dobijanje i karakterizacija nanokompozita kod kojih polimernu matricu čini poli(metil metakrilat) (PMMA), a kao neorgansko punilo nanočestice titan-dioksida. Svi uzorci nanokompozita dobijeni su in situ polimerizacijom preko slobodnih radikala metil metakrilata (MMA) u prisustvu čestica punila. Površinska modifikacija korišćenih nanočestica titan-dioksida izvršena je palmitatom askorbinske kiseline. Uzorci nanokompozita su pripremljeni polimerizacijom metil metakrilata u rastvoru, u masi i suspenzionom polimerizacijom. Određene su vrednosti molarne mase PMMA ekstrahovanog iz kompozitnih uzoraka i dobijeno je da su one manje od vrednosti molarne mase čistog PMMA dobijenog na isti način, na osnovu čega se može zaključiti da nanočestice TiO2-PAA prisutne u toku polimerizacije u sva tri slučaja utiču na reakcije terminacije i dovode do smanjenja molarne mase PMMA matrice. Diferencijalnom skenirajućom kalorimetrijom i termogravimetrijskom analizom utvrđeno je i da način sinteze polimerne matrice i koncentracija čestica punila utiču na termička svojstva dobijenih polimernih nanokompozita.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Influence of the way of synthesis of poly(methyl methacrylate) in the presence of surface modified TiO2 nanoparticles on the properties of obtained nanocomposites
T1  - Uticaj načina sinteze poli(metil metakrilata) u prisustvu površinski modifikovanih TiO2 nanočestica na svojstva dobijenih nanokompozita
EP  - 489
IS  - 6
SP  - 473
VL  - 64
DO  - 10.2298/HEMIND100923059D
UR  - conv_1306
ER  - 
@article{
author = "Džunuzović, Enis and Marinović-Cincović, Milena and Džunuzović, Jasna and Jeremić, Katarina B. and Nedeljković, Jovan",
year = "2010",
abstract = "Incorporation of inorganic nanoparticles can significantly affect the properties of the polymer matrix. The properties of polymer nanocomposites depend on the type of incorporated nanoparticles, their size and shape, their concentration, and interactions with the polymer matrix. Homogeneity of polymer nanocomposites is influenced very much by the preparation method. In this study, TiO2 nanoparticles surface modified with 6-palmitate ascorbic acid (6-PAA) were encapsulated in poly(methyl methacrylate) (PMMA) by in situ radical polymerization of methyl methacrylate initiated by 2,2'-azobisisobutyronitrile (AIBN). The surface modification of the TiO2 nanoparticles was achieved by the formation of a charge transfer complex between TiO2 nanoparticles and 6-palmitate ascorbic acid. The radical polymerization of MMA in the presence of TiO2-PAA nanoparticles was conducted in solution (PMMA/TiO2-PAA-R), in bulk (PMMA/TiO2-PAA-M) or in suspension (PMMA/TiO2-PAA-S). The main purpose of this study was to investigate the influence of the preparation method on the molar masses and thermal properties of PMMA/TiO2-PAA nanocomposite. It was obtained that molar masses of PMMA extracted from the composites had smaller values compared to molar masses of pure PMMA synthesized in the same manner, which indicated that TiO2-PAA nanoparticles affected the reaction of termination. Thermal properties were investigated by DSC and TGA. The values of glass transition temperature, Tg, were influenced by the way the radical polymerization was conducted, even in the case of the pure PMMA. The Tg of composite samples was always smaller than the value of the corresponding PMMA sample and the smallest value was obtained for PMMA/TiO2-PAA-M since they contained the largest amount of low molar mass residue. The TGA results showed that thermal and thermooxidative stability of polymer composites obtained in solution and in suspension was better than for the pure PMMA obtained in the same way., Predmet ovog rada je dobijanje i karakterizacija nanokompozita kod kojih polimernu matricu čini poli(metil metakrilat) (PMMA), a kao neorgansko punilo nanočestice titan-dioksida. Svi uzorci nanokompozita dobijeni su in situ polimerizacijom preko slobodnih radikala metil metakrilata (MMA) u prisustvu čestica punila. Površinska modifikacija korišćenih nanočestica titan-dioksida izvršena je palmitatom askorbinske kiseline. Uzorci nanokompozita su pripremljeni polimerizacijom metil metakrilata u rastvoru, u masi i suspenzionom polimerizacijom. Određene su vrednosti molarne mase PMMA ekstrahovanog iz kompozitnih uzoraka i dobijeno je da su one manje od vrednosti molarne mase čistog PMMA dobijenog na isti način, na osnovu čega se može zaključiti da nanočestice TiO2-PAA prisutne u toku polimerizacije u sva tri slučaja utiču na reakcije terminacije i dovode do smanjenja molarne mase PMMA matrice. Diferencijalnom skenirajućom kalorimetrijom i termogravimetrijskom analizom utvrđeno je i da način sinteze polimerne matrice i koncentracija čestica punila utiču na termička svojstva dobijenih polimernih nanokompozita.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Influence of the way of synthesis of poly(methyl methacrylate) in the presence of surface modified TiO2 nanoparticles on the properties of obtained nanocomposites, Uticaj načina sinteze poli(metil metakrilata) u prisustvu površinski modifikovanih TiO2 nanočestica na svojstva dobijenih nanokompozita",
pages = "489-473",
number = "6",
volume = "64",
doi = "10.2298/HEMIND100923059D",
url = "conv_1306"
}
Džunuzović, E., Marinović-Cincović, M., Džunuzović, J., Jeremić, K. B.,& Nedeljković, J.. (2010). Influence of the way of synthesis of poly(methyl methacrylate) in the presence of surface modified TiO2 nanoparticles on the properties of obtained nanocomposites. in Hemijska industrija
Association of Chemical Engineers of Serbia., 64(6), 473-489.
https://doi.org/10.2298/HEMIND100923059D
conv_1306
Džunuzović E, Marinović-Cincović M, Džunuzović J, Jeremić KB, Nedeljković J. Influence of the way of synthesis of poly(methyl methacrylate) in the presence of surface modified TiO2 nanoparticles on the properties of obtained nanocomposites. in Hemijska industrija. 2010;64(6):473-489.
doi:10.2298/HEMIND100923059D
conv_1306 .
Džunuzović, Enis, Marinović-Cincović, Milena, Džunuzović, Jasna, Jeremić, Katarina B., Nedeljković, Jovan, "Influence of the way of synthesis of poly(methyl methacrylate) in the presence of surface modified TiO2 nanoparticles on the properties of obtained nanocomposites" in Hemijska industrija, 64, no. 6 (2010):473-489,
https://doi.org/10.2298/HEMIND100923059D .,
conv_1306 .

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