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Cubic equation of state models for liquid excess heat capacity calculations. II. Applicability of the PRSV-SR and PRSV-HVOS models to complex binary mixtures

dc.creatorKijevčanin, Mirjana
dc.creatorĐorđević, Bojan D.
dc.creatorAdamović, Milutin M.
dc.creatorŠerbanović, Slobodan P.
dc.date.accessioned2021-03-10T09:43:22Z
dc.date.available2021-03-10T09:43:22Z
dc.date.issued1998
dc.identifier.issn0352-5139
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/167
dc.description.abstractBinary liquid excess heat capacities C-p(E) for various kinds of complex binary systems measured by Conti and coworkers are well represented by the PRSV EOS modified van der Waals one fluid mixing rule proposed by Schwartzentruber and Renon (SR) and the Orbey-Sandler modification of the Huron-Vidal mixing rules (HVOS). The HVOS mixing rule is used with the NRTL excess free energy model. The binary parameters of both models (PRSV-SR and PRSV-HVOS) were assumed to be linear functions of temperature. Only for the system ethanol-cyclohexane the correlation obtained by the PRSV-SR model is not satisfactory.en
dc.publisherSerbian Chemical Society, Belgrade
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.sourceJournal of the Serbian Chemical Society
dc.subjectexcess heat capacityen
dc.subjectcubic equation of stateen
dc.subjectmixing ruleen
dc.subjectpolar compounden
dc.subjectbinary mixtureen
dc.titleCubic equation of state models for liquid excess heat capacity calculations. II. Applicability of the PRSV-SR and PRSV-HVOS models to complex binary mixturesen
dc.typearticle
dc.rights.licenseBY-NC-ND
dc.citation.epage256
dc.citation.issue4
dc.citation.other63(4): 251-256
dc.citation.spage251
dc.citation.volume63
dc.identifier.pmid
dc.identifier.rcubhttps://hdl.handle.net/21.15107/rcub_technorep_167
dc.identifier.scopus2-s2.0-0039657183
dc.identifier.wos000073095700002
dc.type.versionpublishedVersion


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