Experimental determination and modeling of densities and refractive indices of the binary systems alcohol plus dicyclohexylamine at T = (288.15-323.15)K
Само за регистроване кориснике
2011
Аутори
Kijevčanin, MirjanaRadović, Ivona
Đorđević, Bojan D.
Tasić, Aleksandat Z.
Šerbanović, Slobodan P.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The experimental density rho and refractive index n(D) data have been determined for the systems of dicyclohexilamine with 1-propanol, or 1-butanol, or 2-butanol, or 1-pentanol, in the temperature range (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15 and 323.15) K, and at (303.15, 308.15, 313.15, 318.15 and 323.15)K for the system 2-methyl-2-propanol + dicyclohexylamine. All measurements have been performed at atmospheric pressure, using an Anton Paar DMA 5000 digital vibrating tube densimeter and with a refractometer Anton Paar RXA 156. Excess molar volumes V-m(E) and deviations of refractive indices Delta n(D) were correlated by the Redlich-Kister equation. Also, correlation of V-m(E) have been performed with the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vdW1) and mixingrule introduced by Twu et al. (TCBT). In addition, several different mixing rules were employed for refractive index calculations: Lorentz-Lorenz, Dale-Glad...stone, Eykman, Arago-Biot, Newton and Oster.
Кључне речи:
Excess molar volume / Refractive index / Alcohols / Dicyclohexylamine / ModelingИзвор:
Thermochimica Acta, 2011, 525, 1-2, 114-128Издавач:
- Elsevier, Amsterdam
Финансирање / пројекти:
- Нови индустријски и еколошки аспекти примене хемијске термодинамике на унапређење хемијских процеса са вишефазним и вишекомпонентним системима (RS-MESTD-Basic Research (BR or ON)-172063)
- Faculty of Technology and Metallurgy, University of Belgrade
DOI: 10.1016/j.tca.2011.08.002
ISSN: 0040-6031
WoS: 000296824400015
Scopus: 2-s2.0-80053380945
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Kijevčanin, Mirjana AU - Radović, Ivona AU - Đorđević, Bojan D. AU - Tasić, Aleksandat Z. AU - Šerbanović, Slobodan P. PY - 2011 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1852 AB - The experimental density rho and refractive index n(D) data have been determined for the systems of dicyclohexilamine with 1-propanol, or 1-butanol, or 2-butanol, or 1-pentanol, in the temperature range (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15 and 323.15) K, and at (303.15, 308.15, 313.15, 318.15 and 323.15)K for the system 2-methyl-2-propanol + dicyclohexylamine. All measurements have been performed at atmospheric pressure, using an Anton Paar DMA 5000 digital vibrating tube densimeter and with a refractometer Anton Paar RXA 156. Excess molar volumes V-m(E) and deviations of refractive indices Delta n(D) were correlated by the Redlich-Kister equation. Also, correlation of V-m(E) have been performed with the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vdW1) and mixingrule introduced by Twu et al. (TCBT). In addition, several different mixing rules were employed for refractive index calculations: Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton and Oster. PB - Elsevier, Amsterdam T2 - Thermochimica Acta T1 - Experimental determination and modeling of densities and refractive indices of the binary systems alcohol plus dicyclohexylamine at T = (288.15-323.15)K EP - 128 IS - 1-2 SP - 114 VL - 525 DO - 10.1016/j.tca.2011.08.002 ER -
@article{ author = "Kijevčanin, Mirjana and Radović, Ivona and Đorđević, Bojan D. and Tasić, Aleksandat Z. and Šerbanović, Slobodan P.", year = "2011", abstract = "The experimental density rho and refractive index n(D) data have been determined for the systems of dicyclohexilamine with 1-propanol, or 1-butanol, or 2-butanol, or 1-pentanol, in the temperature range (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15 and 323.15) K, and at (303.15, 308.15, 313.15, 318.15 and 323.15)K for the system 2-methyl-2-propanol + dicyclohexylamine. All measurements have been performed at atmospheric pressure, using an Anton Paar DMA 5000 digital vibrating tube densimeter and with a refractometer Anton Paar RXA 156. Excess molar volumes V-m(E) and deviations of refractive indices Delta n(D) were correlated by the Redlich-Kister equation. Also, correlation of V-m(E) have been performed with the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vdW1) and mixingrule introduced by Twu et al. (TCBT). In addition, several different mixing rules were employed for refractive index calculations: Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton and Oster.", publisher = "Elsevier, Amsterdam", journal = "Thermochimica Acta", title = "Experimental determination and modeling of densities and refractive indices of the binary systems alcohol plus dicyclohexylamine at T = (288.15-323.15)K", pages = "128-114", number = "1-2", volume = "525", doi = "10.1016/j.tca.2011.08.002" }
Kijevčanin, M., Radović, I., Đorđević, B. D., Tasić, A. Z.,& Šerbanović, S. P.. (2011). Experimental determination and modeling of densities and refractive indices of the binary systems alcohol plus dicyclohexylamine at T = (288.15-323.15)K. in Thermochimica Acta Elsevier, Amsterdam., 525(1-2), 114-128. https://doi.org/10.1016/j.tca.2011.08.002
Kijevčanin M, Radović I, Đorđević BD, Tasić AZ, Šerbanović SP. Experimental determination and modeling of densities and refractive indices of the binary systems alcohol plus dicyclohexylamine at T = (288.15-323.15)K. in Thermochimica Acta. 2011;525(1-2):114-128. doi:10.1016/j.tca.2011.08.002 .
Kijevčanin, Mirjana, Radović, Ivona, Đorđević, Bojan D., Tasić, Aleksandat Z., Šerbanović, Slobodan P., "Experimental determination and modeling of densities and refractive indices of the binary systems alcohol plus dicyclohexylamine at T = (288.15-323.15)K" in Thermochimica Acta, 525, no. 1-2 (2011):114-128, https://doi.org/10.1016/j.tca.2011.08.002 . .