Приказ основних података о документу

dc.creatorVidaković-Koch, Tanja
dc.creatorPanić, Vladimir
dc.creatorAndrić, Milan
dc.creatorPetkovska, Menka
dc.creatorSundmacher, Kai
dc.date.accessioned2021-03-10T11:33:45Z
dc.date.available2021-03-10T11:33:45Z
dc.date.issued2011
dc.identifier.issn1932-7447
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/1866
dc.description.abstractIn this work, a nonlinear frequency response (NLFR) analysis was used for a first time in a theoretical study of nonlinear behavior of electrochemical (EC) ferrocyanide oxidation as a simple model reaction. Analytical expressions of the first- and second-order frequency response functions (FRFs) are derived. The first-order FRF is equivalent to the EC admittance and contains information about the linear behavior of the system, whereas the second-order FRF contains additional nonlinear information. The influence of different parameters, such as the heterogeneous rate constant, solution resistance, double-layer capacitance, diffusion coefficients of the reacting species, and electrode rotation rate on the characteristics of the first- and second-order FRFs was checked and discussed. It was found that the second-order FRF is more sensitive to the changes of the studied parameters than the first-order FRF. Experimental verification of the NLFR analysis of EC ferrocyanide oxidation is presented in Part II of this worken
dc.publisherAmer Chemical Soc, Washington
dc.relationMax Planck Society, GermanyMax Planck Society
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172060/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172022/RS//
dc.rightsrestrictedAccess
dc.sourceJournal of Physical Chemistry C
dc.titleNonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part I. A Theoretical Analysisen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage17351
dc.citation.issue35
dc.citation.other115(35): 17341-17351
dc.citation.rankaM21
dc.citation.spage17341
dc.citation.volume115
dc.identifier.doi10.1021/jp201297v
dc.identifier.scopus2-s2.0-80052331979
dc.identifier.wos000294386000016
dc.type.versionpublishedVersion


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Приказ основних података о документу