A Voltammetric Method for the Quantitative Determination of Midecamycin Compared to Its Simultaneous HPLC Determination
Само за регистроване кориснике
2011
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The aim of this study was to present the quantitative determination of midecamycin at a gold electrode in 0.05 M NaHCO3 using cyclic linear sweep voltammetry. It was found that the value of the oxidative peak of pure midecamycin at 0.85 V vs. SCE at a scan rate of 50 mV s(-1) is a linear function of the concentration in the range 0.1693-0.3289 mg cm(-3). The value of its reductive peak at 0.3 V vs. SCE is a linear function of the concentration in the range 0.11396-0.3802 mg cm(-3). HPLC analysis of the bulk of electrolyte confirmed the data obtained by analysis of the current peak values concerning the correlation with each investigated concentration of midecamycin. By MS spectrometry no degradation products were found in electrolyte during its quantitative determination.
Кључне речи:
midecamycin / gold electrode / quantitative determination / HPLC / MS spectrometryИзвор:
Russian Journal of Electrochemistry, 2011, 47, 7, 781-786Издавач:
- Pleiades Publishing Inc, Moscow
Финансирање / пројекти:
- Проучавање синтезе, структуре и активности органских једињења природног и синтетског порекла (RS-172013)
DOI: 10.1134/S1023193511070056
ISSN: 1023-1935
WoS: 000295530300003
Scopus: 2-s2.0-80052644417
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Drljević-Đurić, Katica AU - Avramov-Ivić, Milka AU - Petrović, Slobodan AU - Mijin, Dušan AU - Jadranin, Milka PY - 2011 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1871 AB - The aim of this study was to present the quantitative determination of midecamycin at a gold electrode in 0.05 M NaHCO3 using cyclic linear sweep voltammetry. It was found that the value of the oxidative peak of pure midecamycin at 0.85 V vs. SCE at a scan rate of 50 mV s(-1) is a linear function of the concentration in the range 0.1693-0.3289 mg cm(-3). The value of its reductive peak at 0.3 V vs. SCE is a linear function of the concentration in the range 0.11396-0.3802 mg cm(-3). HPLC analysis of the bulk of electrolyte confirmed the data obtained by analysis of the current peak values concerning the correlation with each investigated concentration of midecamycin. By MS spectrometry no degradation products were found in electrolyte during its quantitative determination. PB - Pleiades Publishing Inc, Moscow T2 - Russian Journal of Electrochemistry T1 - A Voltammetric Method for the Quantitative Determination of Midecamycin Compared to Its Simultaneous HPLC Determination EP - 786 IS - 7 SP - 781 VL - 47 DO - 10.1134/S1023193511070056 ER -
@article{ author = "Drljević-Đurić, Katica and Avramov-Ivić, Milka and Petrović, Slobodan and Mijin, Dušan and Jadranin, Milka", year = "2011", abstract = "The aim of this study was to present the quantitative determination of midecamycin at a gold electrode in 0.05 M NaHCO3 using cyclic linear sweep voltammetry. It was found that the value of the oxidative peak of pure midecamycin at 0.85 V vs. SCE at a scan rate of 50 mV s(-1) is a linear function of the concentration in the range 0.1693-0.3289 mg cm(-3). The value of its reductive peak at 0.3 V vs. SCE is a linear function of the concentration in the range 0.11396-0.3802 mg cm(-3). HPLC analysis of the bulk of electrolyte confirmed the data obtained by analysis of the current peak values concerning the correlation with each investigated concentration of midecamycin. By MS spectrometry no degradation products were found in electrolyte during its quantitative determination.", publisher = "Pleiades Publishing Inc, Moscow", journal = "Russian Journal of Electrochemistry", title = "A Voltammetric Method for the Quantitative Determination of Midecamycin Compared to Its Simultaneous HPLC Determination", pages = "786-781", number = "7", volume = "47", doi = "10.1134/S1023193511070056" }
Drljević-Đurić, K., Avramov-Ivić, M., Petrović, S., Mijin, D.,& Jadranin, M.. (2011). A Voltammetric Method for the Quantitative Determination of Midecamycin Compared to Its Simultaneous HPLC Determination. in Russian Journal of Electrochemistry Pleiades Publishing Inc, Moscow., 47(7), 781-786. https://doi.org/10.1134/S1023193511070056
Drljević-Đurić K, Avramov-Ivić M, Petrović S, Mijin D, Jadranin M. A Voltammetric Method for the Quantitative Determination of Midecamycin Compared to Its Simultaneous HPLC Determination. in Russian Journal of Electrochemistry. 2011;47(7):781-786. doi:10.1134/S1023193511070056 .
Drljević-Đurić, Katica, Avramov-Ivić, Milka, Petrović, Slobodan, Mijin, Dušan, Jadranin, Milka, "A Voltammetric Method for the Quantitative Determination of Midecamycin Compared to Its Simultaneous HPLC Determination" in Russian Journal of Electrochemistry, 47, no. 7 (2011):781-786, https://doi.org/10.1134/S1023193511070056 . .