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dc.creatorMilosavljević, Milutin M.
dc.creatorVuković, Goran D.
dc.creatorMarinković, Aleksandar
dc.creatorAleksić, Radoslav
dc.creatorUskoković, Petar
dc.date.accessioned2021-03-10T11:36:00Z
dc.date.available2021-03-10T11:36:00Z
dc.date.issued2011
dc.identifier.issn0026-9247
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/1901
dc.description.abstractTwelve N-(3- and 4-substituted phenyl)-O-isobutyl thionocarbamates, eight of which are novel, were synthesized from O-isobutyl xanthate and 3- and 4-substituted anilines in the presence of a nano-platinum aminophenyl modified multi-walled carbon nanotube catalyst. The nano-Pt catalyst was prepared on a carbon nanotube support modified by diazotization, nitro group reduction, and subsequent microwave-assisted nano-Pt precipitation. The catalyst was characterized by Fourier transform infrared (FT-IR) spectroscopy, elemental analysis, thermogravimetric analysis, and transmission electron microscopy. The nano-platinum/modified carbon nanotube catalyst was compared with a commercial Pt/active carbon catalyst in terms of product purity and yield. The results obtained by the use of the catalysts were additionally compared with those obtained by reaction of sodium isobutyl xanthogenacetate and 3- and 4-substituted anilines. Full structure characterization of the synthesized N-(substituted phenyl)-O-isobutyl thionocarbamates was achieved using FT-IR, H-1 and C-13 NMR, and mass spectrometric methods, and their purity was proved by elemental analysis and gas chromatography. The new catalytic method offers advantages over the commercial method, such as higher yields and no product purification is required, thus conforming to the principles of ecologically friendly syntheses.en
dc.publisherSpringer Wien, Wien
dc.relationUS Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and EngineeringUnited States Department of Energy (DOE) [DE-AC02 05CH11231]
dc.relationinfo:eu-repo/grantAgreement/EC/FP7/245916/EU//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172013/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45019/RS//
dc.rightsrestrictedAccess
dc.sourceMonatshefte Fur Chemie
dc.subjectAminesen
dc.subjectNanostructureen
dc.subjectNucleophilic substitutionsen
dc.subjectHeterogeneous catalysisen
dc.subjectThionocarbamatesen
dc.subjectNano-Pt/NH2Ph-MWCNTen
dc.titleSynthesis of N-(3-and 4-substituted phenyl)-O-isobutyl thionocarbamates from O-isobutyl xanthate and amines using a nano-platinum multi-walled carbon nanotube catalysten
dc.typearticle
dc.rights.licenseARR
dc.citation.epage1053
dc.citation.issue10
dc.citation.other142(10): 1045-1053
dc.citation.rankM22
dc.citation.spage1045
dc.citation.volume142
dc.identifier.doi10.1007/s00706-011-0568-5
dc.identifier.scopus2-s2.0-80054035920
dc.identifier.wos000297216000011
dc.type.versionpublishedVersion


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Приказ основних података о документу