Претраживање
Приказ резултата 1-10 од 54
Hydrogen peroxide oxidation on passive iron in alkaline solutions
(Pergamon-Elsevier Science Ltd, Oxford, 1992)
The kinetics of hydrogen peroxide oxidation were studied on passive iron in alkaline solutions of pH ranging from 9.8 to 13.8, using the rotating disk electrode. Measurements were taken using the linear sweep technique. ...
Kinetics of the hydrogen evolution reaction on Fe-Mo film deposited on mild steel support in alkaline solution
(Pergamon-Elsevier Science Ltd, Oxford, 2005)
The mechanism and kinetics of the hydrogen evolution reaction were studied. in 1.0 mol dm(-3) NaOH solution on Fe-Mo alloy electrodes prepared by electrodeposition at constant current densities from a pyrophosphate bath. ...
Oxygen reduction on iron-IV. The reduction of hydrogen peroxide as the intermediate in oxygen reduction reaction in alkaline solutions
(Pergamon-Elsevier Science Ltd, Oxford, 1991)
The kinetics of hydrogen peroxide reduction were studied on iron in borate buffered and unbuffered solutions of pH ranging from 8.6 to 13.8, with and without the presence of chloride ions. A rotating disk electrode was ...
The effect of the electrode surface roughness at low level of coarseness on the polarization characteristics of electrochemical processes
(Pergamon-Elsevier Science Ltd, Oxford, 2010)
In this study, it is considered: (a) the effect of the exchange current density to the limiting diffusion current density ratio (J(0)/J(L)) at low level of surface coarseness on the polarization characteristics of the ...
The origin of high activity of Pt-Au surfaces in the formic acid oxidation
(Pergamon-Elsevier Science Ltd, Oxford, 2009)
We have investigated the oxidation of HCOOH on Au-modified Pt (Au"Pt) and Pt-modified Au (Pt")/Au) electrodes to establish the role of the ensemble and the electronic effect in the catalysis of this reaction. The surfaces ...
Ti substrate coated with composite Cr–MoO2 coatings as highly selective cathode materials in hypochlorite production
(Elsevier, 2013)
The aim of this work was to investigate the possibility of preparation of the composite Cr–MoO2 coatings onto steel and titanium substrates as cathode materials with high selective properties which imply the suppression ...
Oxygen reduction on iron-Part VI. Processes in alkaline solutions
(Pergamon-Elsevier Science Ltd, Oxford, 1994)
The kinetics of oxygen reduction were studied on passivated iron in borate buffered and unbuffered solutions of pH ranging from 7.4 to 13.8. A rotating disk electrode was employed. The O2 reduction on iron under these ...
Pt supported on nano-tungsten carbide as a beneficial catalyst for the oxygen reduction reaction in alkaline solution
(Elsevier, 2012)
Platinum nanocatalyst at nano-tungsten carbide was synthesized, characterized and tested for oxygen reduction reaction (ORR) in 0.1 mol dm−3 NaOH, at 25 °C. Tungsten-carbide islands on nano-tungsten particles (WC) was ...
Electrooxidation of H-2, CO and H-2/CO mixtures on a well-characterized Pt-Re bulk alloy electrode and comparison with other Pt binary alloys
(Pergamon-Elsevier Science Ltd, Oxford, 1998)
We report new results for the electrooxidation of Hz, CO and H-2/CO mixtures on a Pt75Re25 bulk alloy using surface preparation in a UHV chamber and characterization by X-ray photoelectron spectroscopy (XPS). Sputter-cleaned ...
Methanol electrooxidation on supported Pt and PtRu catalysts in acid and alkaline solutions
(Pergamon-Elsevier Science Ltd, Oxford, 2002)
The kinetics of methanol oxidation on supported 47.5 wt.% Pt and 54 wt.% Pt-Ru (with nominal Pt:Ru ratios of 2:3) catalysts are measured in 0.5 M H2SO4 and 0.1 NaOH at 295 and 333 K using thin-film rotating disk electrode ...