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Volumetric and thermodynamic properties of binary mixtures of p-cymene with alpha-pinene, limonene and citral at atmospheric pressure and temperatures up to 323.15 K
(Journal of Molecular Liquids, 2021)
An experimental analysis of density, refractive index, speed of sound and the viscosity at atmospheric pressure and temperatures T = (288.15 to 323.15) K has been carried out for the three binary systems, i.e. (p-cymene + ...
Isopiestic determination of osmotic coefficients in the ionic strength range Im = (0.9670–2.2160) mol⋅kg−1 and activity coefficients determined by electromotive force measurements in the range Im = (0.0897–1.0054) mol⋅kg−1 of the {yKCl + (1 – y) K2HPO4}(aq) system at T = 298.15 K
(Elsevier B.V., 2022)
The mean activity coefficients of KCl in the ternary system {y KCl + (1 – y) K2HPO4}(aq) were experimentally determined at T = (298.15 ± 0.01) K by the electromotive force measurement (EMF method) using the cell of the ...
Introducing the azocinnamic acid scaffold into bent-core liquid crystal design: A structure–property relationship study
(Elsevier B.V., 2022)
A series of bent-core liquid crystals possessing the azocinnamoyl unit in both elongating side arms was synthesized. The chain length was kept fixed for each molecule (C12H25), whereas the substituents at the central and ...
Free volume theory and extended mixing rule implementation for estimation of liquid viscosity of flue gas desulphurization candidate solvents
(Journal of Molecular LiquidsJournal of Molecular Liquids, 2022)
The free volume theory model was used to estimate viscosity of eight pure substances and their twenty-three binary mixtures. The selected viscosity data included compounds such as alcohol, ether, lactam, amine and polymer, ...
Liquid-liquid equilibria of the ternary systems water + C1 – C3 alcohols + dimethyl adipate at 298.15 K and atmospheric pressure: Experimental data and modeling
(Elsevier B.V., 2023)
The aim of this study was to examine the possibility of using a green organic solvent, dimethyl adipate (DMA), as a separation agent in the extraction of different alcohols from aqueous solutions. For that purpose, the ...
Improving ethylene glycol transport properties by caffeine - Thermodynamic and computational evidence
(Journal of Molecular Liquids, 2021)
In this article, detailed physicochemical characterization of ethylene glycol and caffeine + ethylene glycol mixtures is performed based on density, viscosity and refractive indices measurements in temperature range from ...
A new group contribution model for prediction liquid hydrocarbon viscosity based on free-volume theory
(Elsevier B.V., 2023)
In this paper a group contribution model for predicting the viscosity values of n-alkanes and iso-alkanes in the liquid phase based on Free-Volume Theory was developed. A database with 2129 experimental data with a temperature ...
A new setup for speed of sound measurements and experimental data for nanofluids Al2O3 or Ag with water or ethylene glycol
(Elsevier B.V., 2023)
The speed of sound of four different nanofluids consisting of Ag or Al2O3 nanoparticles and water or ethylene glycol base fluid is measured in the temperature range (298.15–343.15) K and at atmospheric pressure. One aim ...
Interactions of caffeine and 1-butyl-3-methylimidazolium salicylate ionic liquid in water – Solubility, volumetric, acoustic, viscometric and refractometric studies supported by MD simulation
(Elsevier B.V., 2024)
In this study, a detailed physicochemical characterization of caffeine in 0.1 mol∙kg−1 of 1-butyl-3-methylimidazolium salicylate (abbreviation [Bmim][Sal]) aqueous solutions is performed based on density, speed of sound, ...
Volumetric properties of binary mixtures of tetrahydrofuran, dimethyl adipate, 1-butanol and 2-butanol from (288.15 to 323.15) K and modeling by Prigogine-Flory-Patterson (PFP) and Extended Real Association Solution (ERAS) models
(Journal of Molecular Liquids, 2021)
In this work, experimental densities data of the binary system tetrahydrofuran + 2-butanol have been determined at eight temperatures, T=(288.15-323.15) K and atmospheric pressure and used for excess molar volume calculations. ...