Removal of Pb2+ Ions from Water by Poly(Acrylamide-co-Sodium Methacrylate) Hydrogels
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2012
Authors
Kalagasidis Krušić, MelinaMilosavljević, Nedeljko
Debeljković, Aleksandra
Uzum, O. B.
Karadag, E.
Article (Published version)
Metadata
Show full item recordAbstract
The application of poly(acrylamide-co-sodium methacrylate) (AAm/SMA) hydrogel for the removal of Pb2+ ions from aqueous solutions has been investigated using batch adsorption technique. The extent of adsorption was investigated as a function of pH, adsorbent dose, and temperature. The Fourier transform infrared (FTIR) spectra showed that -NH2 and -COOH groups are involved in Pb2+ ion adsorption. The obtained results were analyzed by pseudo-first-order, pseudo-second-order, and intraparticle diffusion models using both linear and nonlinear methods. It was found that the Pb2+ ion adsorption followed pseudo-first-order kinetics. Nonlinear regression analysis of six isotherms, Langmuir, Freundlich, Redlich-Peterson, Toth, Dubinin-Radushkevich, and Sips, have been applied to the sorption data, while the best interpretation was given by Redlich-Peterson. Based on the separation factor, R (L), the Pb2+ ion adsorption is favorable, while the negative values of a dagger G indicates that the Pb2...+ ion adsorption on the investigated hydrogel is spontaneous.
Keywords:
Hydrogel / Pb2+ adsorption / Adsorption isotherm / Kinetic modelSource:
Water Air and Soil Pollution, 2012, 223, 7, 4355-4368Publisher:
- Springer, Dordrecht
Funding / projects:
- Synthesis and characterization of novel functional polymers and polymeric nanocomposites (RS-MESTD-Basic Research (BR or ON)-172062)
- Adnan Menderes University Research FundAdnan Menderes University [FEF 08 034]
DOI: 10.1007/s11270-012-1200-y
ISSN: 0049-6979
WoS: 000307276400063
Scopus: 2-s2.0-84865458864
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Kalagasidis Krušić, Melina AU - Milosavljević, Nedeljko AU - Debeljković, Aleksandra AU - Uzum, O. B. AU - Karadag, E. PY - 2012 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2107 AB - The application of poly(acrylamide-co-sodium methacrylate) (AAm/SMA) hydrogel for the removal of Pb2+ ions from aqueous solutions has been investigated using batch adsorption technique. The extent of adsorption was investigated as a function of pH, adsorbent dose, and temperature. The Fourier transform infrared (FTIR) spectra showed that -NH2 and -COOH groups are involved in Pb2+ ion adsorption. The obtained results were analyzed by pseudo-first-order, pseudo-second-order, and intraparticle diffusion models using both linear and nonlinear methods. It was found that the Pb2+ ion adsorption followed pseudo-first-order kinetics. Nonlinear regression analysis of six isotherms, Langmuir, Freundlich, Redlich-Peterson, Toth, Dubinin-Radushkevich, and Sips, have been applied to the sorption data, while the best interpretation was given by Redlich-Peterson. Based on the separation factor, R (L), the Pb2+ ion adsorption is favorable, while the negative values of a dagger G indicates that the Pb2+ ion adsorption on the investigated hydrogel is spontaneous. PB - Springer, Dordrecht T2 - Water Air and Soil Pollution T1 - Removal of Pb2+ Ions from Water by Poly(Acrylamide-co-Sodium Methacrylate) Hydrogels EP - 4368 IS - 7 SP - 4355 VL - 223 DO - 10.1007/s11270-012-1200-y ER -
@article{ author = "Kalagasidis Krušić, Melina and Milosavljević, Nedeljko and Debeljković, Aleksandra and Uzum, O. B. and Karadag, E.", year = "2012", abstract = "The application of poly(acrylamide-co-sodium methacrylate) (AAm/SMA) hydrogel for the removal of Pb2+ ions from aqueous solutions has been investigated using batch adsorption technique. The extent of adsorption was investigated as a function of pH, adsorbent dose, and temperature. The Fourier transform infrared (FTIR) spectra showed that -NH2 and -COOH groups are involved in Pb2+ ion adsorption. The obtained results were analyzed by pseudo-first-order, pseudo-second-order, and intraparticle diffusion models using both linear and nonlinear methods. It was found that the Pb2+ ion adsorption followed pseudo-first-order kinetics. Nonlinear regression analysis of six isotherms, Langmuir, Freundlich, Redlich-Peterson, Toth, Dubinin-Radushkevich, and Sips, have been applied to the sorption data, while the best interpretation was given by Redlich-Peterson. Based on the separation factor, R (L), the Pb2+ ion adsorption is favorable, while the negative values of a dagger G indicates that the Pb2+ ion adsorption on the investigated hydrogel is spontaneous.", publisher = "Springer, Dordrecht", journal = "Water Air and Soil Pollution", title = "Removal of Pb2+ Ions from Water by Poly(Acrylamide-co-Sodium Methacrylate) Hydrogels", pages = "4368-4355", number = "7", volume = "223", doi = "10.1007/s11270-012-1200-y" }
Kalagasidis Krušić, M., Milosavljević, N., Debeljković, A., Uzum, O. B.,& Karadag, E.. (2012). Removal of Pb2+ Ions from Water by Poly(Acrylamide-co-Sodium Methacrylate) Hydrogels. in Water Air and Soil Pollution Springer, Dordrecht., 223(7), 4355-4368. https://doi.org/10.1007/s11270-012-1200-y
Kalagasidis Krušić M, Milosavljević N, Debeljković A, Uzum OB, Karadag E. Removal of Pb2+ Ions from Water by Poly(Acrylamide-co-Sodium Methacrylate) Hydrogels. in Water Air and Soil Pollution. 2012;223(7):4355-4368. doi:10.1007/s11270-012-1200-y .
Kalagasidis Krušić, Melina, Milosavljević, Nedeljko, Debeljković, Aleksandra, Uzum, O. B., Karadag, E., "Removal of Pb2+ Ions from Water by Poly(Acrylamide-co-Sodium Methacrylate) Hydrogels" in Water Air and Soil Pollution, 223, no. 7 (2012):4355-4368, https://doi.org/10.1007/s11270-012-1200-y . .