Electrodeposition of silver from nitrate solution: Part II. Mechanism of the effect of phosphate ions
Abstract
The mechanism of compact Ag-film formation by electrolysis from nitrate solution with addition of small amounts of phosphate ions is elucidated. It is shown that the phosphate ions exert their effect by lowering the exchange current density. Consequently, the radii of nucleation exclusion zones also diminishes, thus producing conditions stimulating electrodeposition of continuous thin Ag-film.
Keywords:
electrodeposition / nitrate solution / phosphate ion addition / silverSource:
Journal of Applied Electrochemistry, 1998, 28, 8, 797-801Publisher:
- Springer, Dordrecht
DOI: 10.1023/A:1003450604118
ISSN: 0021-891X
WoS: 000077463100005
Scopus: 2-s2.0-0032131536
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Popov, Konstantin I. AU - Pavlović, MG AU - Grgur, Branimir AU - Dimitrov, AT AU - Jordanov, SH PY - 1998 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/217 AB - The mechanism of compact Ag-film formation by electrolysis from nitrate solution with addition of small amounts of phosphate ions is elucidated. It is shown that the phosphate ions exert their effect by lowering the exchange current density. Consequently, the radii of nucleation exclusion zones also diminishes, thus producing conditions stimulating electrodeposition of continuous thin Ag-film. PB - Springer, Dordrecht T2 - Journal of Applied Electrochemistry T1 - Electrodeposition of silver from nitrate solution: Part II. Mechanism of the effect of phosphate ions EP - 801 IS - 8 SP - 797 VL - 28 DO - 10.1023/A:1003450604118 ER -
@article{ author = "Popov, Konstantin I. and Pavlović, MG and Grgur, Branimir and Dimitrov, AT and Jordanov, SH", year = "1998", abstract = "The mechanism of compact Ag-film formation by electrolysis from nitrate solution with addition of small amounts of phosphate ions is elucidated. It is shown that the phosphate ions exert their effect by lowering the exchange current density. Consequently, the radii of nucleation exclusion zones also diminishes, thus producing conditions stimulating electrodeposition of continuous thin Ag-film.", publisher = "Springer, Dordrecht", journal = "Journal of Applied Electrochemistry", title = "Electrodeposition of silver from nitrate solution: Part II. Mechanism of the effect of phosphate ions", pages = "801-797", number = "8", volume = "28", doi = "10.1023/A:1003450604118" }
Popov, K. I., Pavlović, M., Grgur, B., Dimitrov, A.,& Jordanov, S.. (1998). Electrodeposition of silver from nitrate solution: Part II. Mechanism of the effect of phosphate ions. in Journal of Applied Electrochemistry Springer, Dordrecht., 28(8), 797-801. https://doi.org/10.1023/A:1003450604118
Popov KI, Pavlović M, Grgur B, Dimitrov A, Jordanov S. Electrodeposition of silver from nitrate solution: Part II. Mechanism of the effect of phosphate ions. in Journal of Applied Electrochemistry. 1998;28(8):797-801. doi:10.1023/A:1003450604118 .
Popov, Konstantin I., Pavlović, MG, Grgur, Branimir, Dimitrov, AT, Jordanov, SH, "Electrodeposition of silver from nitrate solution: Part II. Mechanism of the effect of phosphate ions" in Journal of Applied Electrochemistry, 28, no. 8 (1998):797-801, https://doi.org/10.1023/A:1003450604118 . .