Adsorptive Removal of Technetium-99 Using Macroporous Poly(GMA-co-EGDMA) Modified with Diethylene Triamine
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2012
Authors
Hercigonja, RadmilaMaksin, Danijela
Nastasović, Aleksandra
Trifunović, Snežana
Glodić, Pavle B.
Onjia, Antonije
Article (Published version)
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dThe possibility of sorption of technetium-99 in the form of pertechnetate anion (TcO(4)(-)) and the sorption kinetics for removing TcO(4)(-) from aqueous solution by chelating polymers based on glycidyl methacrylate (GMA) were investigated. Two samples of macroporous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME), with different amount of the crosslinker (ethylene glycol dimethacrylate, EGDMA), were synthesized by suspension copolymerization and functionalized with diethylene triamine (deta). We propose that nonspecific sorption of pertechnetate anion via electrostatic interactions takes place at the protonated amino groups of macroporous crosslinked copolymer. The results of batch experiments per-formed at pH 1-14 showed fast sorption kinetics for removing TcO(4)(-) by amino-functionalized PGME-deta in a wide range of pH, that is, from 1.0 to 9.0. Almost complete removal of TcO(4)(-) (91-98%) was reached within 180 min in the stated pH range (1.0-9.0...), with the sorption half-times of under 25 min. The partitioning coefficients of linear adsorption isotherms, with 180-min equilibrium time, reach the high values of 2130 mL g(-1) and 1698 mL g(-1) for the two samples of synthesized PGME-deta.
Keywords:
macroporous polymers / glycidyl methacrylate based / pertechnetate / adsorption / FTIRSource:
Journal of Applied Polymer Science, 2012, 123, 2, 1273-1282Publisher:
- Wiley-Blackwell, Malden
Funding / projects:
- Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43009)
- Oxide-based environmentally-friendly porous materials for genotoxic substances removal (RS-MESTD-Basic Research (BR or ON)-172018)
- Research and verification of the multidisciplinary forensic methods in (RS-MESTD-Technological Development (TD or TR)-37021)
DOI: 10.1002/app.34693
ISSN: 0021-8995
WoS: 000296859200075
Scopus: 2-s2.0-80255127345
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Hercigonja, Radmila AU - Maksin, Danijela AU - Nastasović, Aleksandra AU - Trifunović, Snežana AU - Glodić, Pavle B. AU - Onjia, Antonije PY - 2012 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2241 AB - dThe possibility of sorption of technetium-99 in the form of pertechnetate anion (TcO(4)(-)) and the sorption kinetics for removing TcO(4)(-) from aqueous solution by chelating polymers based on glycidyl methacrylate (GMA) were investigated. Two samples of macroporous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME), with different amount of the crosslinker (ethylene glycol dimethacrylate, EGDMA), were synthesized by suspension copolymerization and functionalized with diethylene triamine (deta). We propose that nonspecific sorption of pertechnetate anion via electrostatic interactions takes place at the protonated amino groups of macroporous crosslinked copolymer. The results of batch experiments per-formed at pH 1-14 showed fast sorption kinetics for removing TcO(4)(-) by amino-functionalized PGME-deta in a wide range of pH, that is, from 1.0 to 9.0. Almost complete removal of TcO(4)(-) (91-98%) was reached within 180 min in the stated pH range (1.0-9.0), with the sorption half-times of under 25 min. The partitioning coefficients of linear adsorption isotherms, with 180-min equilibrium time, reach the high values of 2130 mL g(-1) and 1698 mL g(-1) for the two samples of synthesized PGME-deta. PB - Wiley-Blackwell, Malden T2 - Journal of Applied Polymer Science T1 - Adsorptive Removal of Technetium-99 Using Macroporous Poly(GMA-co-EGDMA) Modified with Diethylene Triamine EP - 1282 IS - 2 SP - 1273 VL - 123 DO - 10.1002/app.34693 ER -
@article{ author = "Hercigonja, Radmila and Maksin, Danijela and Nastasović, Aleksandra and Trifunović, Snežana and Glodić, Pavle B. and Onjia, Antonije", year = "2012", abstract = "dThe possibility of sorption of technetium-99 in the form of pertechnetate anion (TcO(4)(-)) and the sorption kinetics for removing TcO(4)(-) from aqueous solution by chelating polymers based on glycidyl methacrylate (GMA) were investigated. Two samples of macroporous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME), with different amount of the crosslinker (ethylene glycol dimethacrylate, EGDMA), were synthesized by suspension copolymerization and functionalized with diethylene triamine (deta). We propose that nonspecific sorption of pertechnetate anion via electrostatic interactions takes place at the protonated amino groups of macroporous crosslinked copolymer. The results of batch experiments per-formed at pH 1-14 showed fast sorption kinetics for removing TcO(4)(-) by amino-functionalized PGME-deta in a wide range of pH, that is, from 1.0 to 9.0. Almost complete removal of TcO(4)(-) (91-98%) was reached within 180 min in the stated pH range (1.0-9.0), with the sorption half-times of under 25 min. The partitioning coefficients of linear adsorption isotherms, with 180-min equilibrium time, reach the high values of 2130 mL g(-1) and 1698 mL g(-1) for the two samples of synthesized PGME-deta.", publisher = "Wiley-Blackwell, Malden", journal = "Journal of Applied Polymer Science", title = "Adsorptive Removal of Technetium-99 Using Macroporous Poly(GMA-co-EGDMA) Modified with Diethylene Triamine", pages = "1282-1273", number = "2", volume = "123", doi = "10.1002/app.34693" }
Hercigonja, R., Maksin, D., Nastasović, A., Trifunović, S., Glodić, P. B.,& Onjia, A.. (2012). Adsorptive Removal of Technetium-99 Using Macroporous Poly(GMA-co-EGDMA) Modified with Diethylene Triamine. in Journal of Applied Polymer Science Wiley-Blackwell, Malden., 123(2), 1273-1282. https://doi.org/10.1002/app.34693
Hercigonja R, Maksin D, Nastasović A, Trifunović S, Glodić PB, Onjia A. Adsorptive Removal of Technetium-99 Using Macroporous Poly(GMA-co-EGDMA) Modified with Diethylene Triamine. in Journal of Applied Polymer Science. 2012;123(2):1273-1282. doi:10.1002/app.34693 .
Hercigonja, Radmila, Maksin, Danijela, Nastasović, Aleksandra, Trifunović, Snežana, Glodić, Pavle B., Onjia, Antonije, "Adsorptive Removal of Technetium-99 Using Macroporous Poly(GMA-co-EGDMA) Modified with Diethylene Triamine" in Journal of Applied Polymer Science, 123, no. 2 (2012):1273-1282, https://doi.org/10.1002/app.34693 . .