Mechanochemically synthesized CaO center dot ZnO catalyst for biodiesel production
Апстракт
The transesterification of triglycerides (vegetable oil) with methanol using CaO center dot ZnO mixed oxides catalyst were conducted to produce FAME (Fatty Acid Methyl Esters, i.e. biodiesel). Catalyst was synthesized by ball milling of CaO and ZnO powder mixture (using molar ratio of CaO and ZnO of 1:2 and 1:4) with the addition of water, as well as solely by ball milling (molar ratio of 1:2) of mentioned powders and subsequent. After ball milling prepared mixtures were calcinatied at 700 degrees C in air atmosphere. The samples of formed catalysts were characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA) and Fourier transform infrared (FTIR) spectroscopy. The particle size distribution as well as the base strength using Hammett indicator was determined, too. CaO. ZnO catalysts were used in the methanolysis of sunflower oil, at 60 degrees C and 1 bar, using molar ratio of sunflower oil to methanol of 1:10 and with 2 wt% of catalyst based on oil weight. All cataly...sts exhibited good activity in the methanolysis of sunflower oil, with the yield of FAME above 90 % after 4 hours of reaction.
Кључне речи:
Biodiesel / heterogeneous catalyst / CaO center dot ZnO catalyst / ball millingИзвор:
CHISA 2012, 2012, 42, 1169-1178Издавач:
- Elsevier Science Bv, Amsterdam
Финансирање / пројекти:
- Наноструктурни функционални и композитни материјали у каталитичким и сорпционим процесима (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
DOI: 10.1016/j.proeng.2012.07.509
ISSN: 1877-7058
WoS: 000392862500120
Scopus: 2-s2.0-84891711855
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Kesić, Željka AU - Lukić, Ivana AU - Zdujić, Miodrag AU - Liu, Hui AU - Skala, Dejan PY - 2012 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2247 AB - The transesterification of triglycerides (vegetable oil) with methanol using CaO center dot ZnO mixed oxides catalyst were conducted to produce FAME (Fatty Acid Methyl Esters, i.e. biodiesel). Catalyst was synthesized by ball milling of CaO and ZnO powder mixture (using molar ratio of CaO and ZnO of 1:2 and 1:4) with the addition of water, as well as solely by ball milling (molar ratio of 1:2) of mentioned powders and subsequent. After ball milling prepared mixtures were calcinatied at 700 degrees C in air atmosphere. The samples of formed catalysts were characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA) and Fourier transform infrared (FTIR) spectroscopy. The particle size distribution as well as the base strength using Hammett indicator was determined, too. CaO. ZnO catalysts were used in the methanolysis of sunflower oil, at 60 degrees C and 1 bar, using molar ratio of sunflower oil to methanol of 1:10 and with 2 wt% of catalyst based on oil weight. All catalysts exhibited good activity in the methanolysis of sunflower oil, with the yield of FAME above 90 % after 4 hours of reaction. PB - Elsevier Science Bv, Amsterdam T2 - CHISA 2012 T1 - Mechanochemically synthesized CaO center dot ZnO catalyst for biodiesel production EP - 1178 SP - 1169 VL - 42 DO - 10.1016/j.proeng.2012.07.509 ER -
@article{ author = "Kesić, Željka and Lukić, Ivana and Zdujić, Miodrag and Liu, Hui and Skala, Dejan", year = "2012", abstract = "The transesterification of triglycerides (vegetable oil) with methanol using CaO center dot ZnO mixed oxides catalyst were conducted to produce FAME (Fatty Acid Methyl Esters, i.e. biodiesel). Catalyst was synthesized by ball milling of CaO and ZnO powder mixture (using molar ratio of CaO and ZnO of 1:2 and 1:4) with the addition of water, as well as solely by ball milling (molar ratio of 1:2) of mentioned powders and subsequent. After ball milling prepared mixtures were calcinatied at 700 degrees C in air atmosphere. The samples of formed catalysts were characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA) and Fourier transform infrared (FTIR) spectroscopy. The particle size distribution as well as the base strength using Hammett indicator was determined, too. CaO. ZnO catalysts were used in the methanolysis of sunflower oil, at 60 degrees C and 1 bar, using molar ratio of sunflower oil to methanol of 1:10 and with 2 wt% of catalyst based on oil weight. All catalysts exhibited good activity in the methanolysis of sunflower oil, with the yield of FAME above 90 % after 4 hours of reaction.", publisher = "Elsevier Science Bv, Amsterdam", journal = "CHISA 2012", title = "Mechanochemically synthesized CaO center dot ZnO catalyst for biodiesel production", pages = "1178-1169", volume = "42", doi = "10.1016/j.proeng.2012.07.509" }
Kesić, Ž., Lukić, I., Zdujić, M., Liu, H.,& Skala, D.. (2012). Mechanochemically synthesized CaO center dot ZnO catalyst for biodiesel production. in CHISA 2012 Elsevier Science Bv, Amsterdam., 42, 1169-1178. https://doi.org/10.1016/j.proeng.2012.07.509
Kesić Ž, Lukić I, Zdujić M, Liu H, Skala D. Mechanochemically synthesized CaO center dot ZnO catalyst for biodiesel production. in CHISA 2012. 2012;42:1169-1178. doi:10.1016/j.proeng.2012.07.509 .
Kesić, Željka, Lukić, Ivana, Zdujić, Miodrag, Liu, Hui, Skala, Dejan, "Mechanochemically synthesized CaO center dot ZnO catalyst for biodiesel production" in CHISA 2012, 42 (2012):1169-1178, https://doi.org/10.1016/j.proeng.2012.07.509 . .