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dc.creatorTodić, Branislav
dc.creatorOlewski, Tomasz
dc.creatorNikačević, Nikola
dc.creatorBukur, Dragomir B.
dc.date.accessioned2021-03-10T12:11:03Z
dc.date.available2021-03-10T12:11:03Z
dc.date.issued2013
dc.identifier.issn1974-9791
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/2453
dc.description.abstractThe kinetic models of Fischer-Tropsch synthesis (FTS) product distribution can be classified into two major groups: hydrocarbon selectivity models and detailed Langmuir-Hinshelwood-Hougen-Watson (LHHW) kinetic models. In this study the two approaches to FTS product distribution modeling are presented and compared using the experimental data obtained in a stirred tank slurry reactor with promoted iron catalyst over a wide range of process conditions. Positive deviations from the classical Anderson-Schulz-Flory distribution and an exponential decrease in olefin-to-paraffin ratio with carbon number are predicted by the inclusion of solubility-enhanced 1-olefin readsorption and/or chain length dependent 1-olefin desorption concepts. In general the agreement between the model predictions and experimental data was very good, and modeling approaches are discussed in terms of fit quality, physical meaningfulness and practical utility.en
dc.publisherAidic Servizi Srl, Milano
dc.rightsrestrictedAccess
dc.sourceICHEAP-11: 11th International Conference on Chemical and Process Engineering, Pts 1-4
dc.titleModeling of Fischer-Tropsch Product Distribution over Fe-based Catalysten
dc.typearticle
dc.rights.licenseARR
dc.citation.epage798
dc.citation.other32: 793-798
dc.citation.spage793
dc.citation.volume32
dc.identifier.doi10.3303/CET1332133
dc.identifier.scopus2-s2.0-84879222957
dc.identifier.wos000335952100133
dc.type.versionpublishedVersion


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