Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution
Само за регистроване кориснике
2013
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Hydrogen evolution reaction (HER) was studied on Pd/Au(1 1 1) bimetallic surfaces in alkaline solution. Au(1 1 1) was modified by palladium nanoislands spontaneously deposited using PdSO4 center dot 2H(2)O and PdCl2 salts. As revealed from both surface topography Atomic Force Microscopy (AFM) and phase AFM images, for the same deposition conditions, the obtained Pd/Au(1 1 1) nanostructures differ depending on the counter anion in the depositing palladium salt. These differences are reflected on their catalytic activity toward HER, which occurs between the potentials for pure consisting metals. HER proceeded with the same mechanism, but it is shifted to more positive potentials for Pd/Au(1 1 1) nanostructures obtained using PdCl2 salt with respect to ones obtained using PdSO4 salt. Better catalytic activity of Pd/Au(1 1 1) nanostructures obtained using PdCl2 salt can be explained by their surface structure consisting of smaller and thinner Pd nanoislands, preferentially deposited at ste...ps, which provides more Pd and Pd/Au sites suitable for hydrogen evolution reaction.
Кључне речи:
Au(111) / Palladium / AFM / Hydrogen evolution / Alkaline solutionИзвор:
Electrochimica Acta, 2013, 88, 589-596Издавач:
- Pergamon-Elsevier Science Ltd, Oxford
Финансирање / пројекти:
DOI: 10.1016/j.electacta.2012.10.128
ISSN: 0013-4686
WoS: 000315076300079
Scopus: 2-s2.0-84870704364
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Smiljanić, Milutin Lj. AU - Srejić, Irina AU - Grgur, Branimir AU - Rakočević, Zlatko Lj. AU - Štrbac, Svetlana PY - 2013 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2511 AB - Hydrogen evolution reaction (HER) was studied on Pd/Au(1 1 1) bimetallic surfaces in alkaline solution. Au(1 1 1) was modified by palladium nanoislands spontaneously deposited using PdSO4 center dot 2H(2)O and PdCl2 salts. As revealed from both surface topography Atomic Force Microscopy (AFM) and phase AFM images, for the same deposition conditions, the obtained Pd/Au(1 1 1) nanostructures differ depending on the counter anion in the depositing palladium salt. These differences are reflected on their catalytic activity toward HER, which occurs between the potentials for pure consisting metals. HER proceeded with the same mechanism, but it is shifted to more positive potentials for Pd/Au(1 1 1) nanostructures obtained using PdCl2 salt with respect to ones obtained using PdSO4 salt. Better catalytic activity of Pd/Au(1 1 1) nanostructures obtained using PdCl2 salt can be explained by their surface structure consisting of smaller and thinner Pd nanoislands, preferentially deposited at steps, which provides more Pd and Pd/Au sites suitable for hydrogen evolution reaction. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Electrochimica Acta T1 - Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution EP - 596 SP - 589 VL - 88 DO - 10.1016/j.electacta.2012.10.128 ER -
@article{ author = "Smiljanić, Milutin Lj. and Srejić, Irina and Grgur, Branimir and Rakočević, Zlatko Lj. and Štrbac, Svetlana", year = "2013", abstract = "Hydrogen evolution reaction (HER) was studied on Pd/Au(1 1 1) bimetallic surfaces in alkaline solution. Au(1 1 1) was modified by palladium nanoislands spontaneously deposited using PdSO4 center dot 2H(2)O and PdCl2 salts. As revealed from both surface topography Atomic Force Microscopy (AFM) and phase AFM images, for the same deposition conditions, the obtained Pd/Au(1 1 1) nanostructures differ depending on the counter anion in the depositing palladium salt. These differences are reflected on their catalytic activity toward HER, which occurs between the potentials for pure consisting metals. HER proceeded with the same mechanism, but it is shifted to more positive potentials for Pd/Au(1 1 1) nanostructures obtained using PdCl2 salt with respect to ones obtained using PdSO4 salt. Better catalytic activity of Pd/Au(1 1 1) nanostructures obtained using PdCl2 salt can be explained by their surface structure consisting of smaller and thinner Pd nanoislands, preferentially deposited at steps, which provides more Pd and Pd/Au sites suitable for hydrogen evolution reaction.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Electrochimica Acta", title = "Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution", pages = "596-589", volume = "88", doi = "10.1016/j.electacta.2012.10.128" }
Smiljanić, M. Lj., Srejić, I., Grgur, B., Rakočević, Z. Lj.,& Štrbac, S.. (2013). Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution. in Electrochimica Acta Pergamon-Elsevier Science Ltd, Oxford., 88, 589-596. https://doi.org/10.1016/j.electacta.2012.10.128
Smiljanić ML, Srejić I, Grgur B, Rakočević ZL, Štrbac S. Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution. in Electrochimica Acta. 2013;88:589-596. doi:10.1016/j.electacta.2012.10.128 .
Smiljanić, Milutin Lj., Srejić, Irina, Grgur, Branimir, Rakočević, Zlatko Lj., Štrbac, Svetlana, "Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution" in Electrochimica Acta, 88 (2013):589-596, https://doi.org/10.1016/j.electacta.2012.10.128 . .