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dc.creatorNikolić, Jasmina
dc.creatorUšćumlić, Gordana
dc.date.accessioned2021-03-10T12:14:53Z
dc.date.available2021-03-10T12:14:53Z
dc.date.issued2013
dc.identifier.issn0538-8066
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/2514
dc.description.abstractThe kinetics of the reaction of benzoic, 2-methylbenzoic, phenylacetic, cyclohex-1-enecarboxylic, 2-methylcyclohex-1-enecarboxylic, and cyclohex-1-eneacetic acids with diazodiphenylmethane was studied at 30, 33, 37, 40, and 45 degrees C in a set of 12 protic and aprotic solvents. The reactions were found to follow the second-order kinetics. The activation energy as well as the activation parameters, such as the standard entropy, the standard enthalpy, and the standard Gibbs energy of the activation, was calculated from the second-order rate constants. The solvent and structural effects on the activation energy and the standard Gibbs energy of activation, for each examined compound, were analyzed. The results of KamletTaft multiple correlation analysis show that the specific solventsolute interactions play a dominant role in the governing of the reaction. The signs of the equation coefficients support the proposed reaction mechanism.en
dc.publisherWiley-Blackwell, Hoboken
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172013/RS//
dc.rightsrestrictedAccess
dc.sourceInternational Journal of Chemical Kinetics
dc.titleSolvent and Structural Effects on the Activation Parameters of the Reaction of Carboxylic Acids with Diazodiphenylmethaneen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage265
dc.citation.issue4
dc.citation.other45(4): 256-265
dc.citation.rankM23
dc.citation.spage256
dc.citation.volume45
dc.identifier.doi10.1002/kin.20762
dc.identifier.rcubconv_4065
dc.identifier.scopus2-s2.0-84874441115
dc.identifier.wos000315352700006
dc.type.versionpublishedVersion


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