Приказ основних података о документу

dc.creatorMiladinović, Zoran P.
dc.creatorZakrzewska, Joanna
dc.creatorKovacević, Branimir T.
dc.creatorMiladinović, Jelena
dc.date.accessioned2021-03-10T12:33:40Z
dc.date.available2021-03-10T12:33:40Z
dc.date.issued2014
dc.identifier.issn1387-1811
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/2812
dc.description.abstractIn this study, in situ Al-27 NMR spectroscopy was used to gain detailed information concerning kinetics of zeolite A crystallization. Changes of relative intensity and width at half-height of NMR lines at 59 ppm ascribed to Al(OSi)(4) solid structures units and at 79 ppm to Al(OH) T ions in liquid phase during crystallization, were observed. Normalized curves for series of synthesis, performed under different batch molar composition, were used for kinetic analysis applying Sharp and Hancock approach. The influence of total batch Na2O concentration (H2O/Na20 was 20 and 32) for three specific batch SiO2/Al2O3 molar ratios (1.7, 2.0 and 2.5) on the kinetic parameters was investigated. Kinetic analysis of line at 79 ppm provided values of parameter n that ranged from 0.93 to 1.97 indicating contribution of both diffusion and phase boundary controlled mechanisms, depending on batch SiO2/Al2O3 molar composition. On the other hand, analysis of line at 59 ppm showed strong correlation to Na2O batch content. Values of n from 1.94 to 3.34 for syntheses performed at lower alkalinity conditions (H2O/Na2O = 32) indicate Avrami-Erofe'ev nucleation and crystal growth model. Almost dominant presence of diffusion mechanism for synthesis conducted at higher alkalinity conditions (H2O/Na2O = 20) was verified by obtained values of n gathered around 1.5.en
dc.publisherElsevier Science Bv, Amsterdam
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45019/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Technological Development (TD or TR)/34026/RS//
dc.rightsrestrictedAccess
dc.sourceMicroporous and Mesoporous Materials
dc.subjectIn situ Al-27 NMRen
dc.subjectZeolite Aen
dc.subjectCrystallizationen
dc.subjectSharp-Hancocken
dc.subjectKinetic analysisen
dc.titleIn situ Al-27 NMR kinetic investigation of zeolite A crystallizationen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage142
dc.citation.other195: 131-142
dc.citation.rankaM21
dc.citation.spage131
dc.citation.volume195
dc.identifier.doi10.1016/j.micromeso.2014.04.022
dc.identifier.scopus2-s2.0-84899822700
dc.identifier.wos000337770900017
dc.type.versionpublishedVersion


Документи

Thumbnail

Овај документ се појављује у следећим колекцијама

Приказ основних података о документу