Electrochemical study of corrosion behavior of graphene coatings on copper and aluminum in a chloride solution
Само за регистроване кориснике
2014
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Electrochemical characteristics and corrosion behavior of graphene coatings on Cu and Al in a 0.1 M NaCl solution were investigated. The graphene coatings were deposited on a Cu surface by chemical vapor deposition. Multiple graphene layers were then mechanically transferred from the growth substrate, Cu, onto Al surface by a transfer technique. The corrosion stability of graphene coatings was determined by electrochemical impedance spectroscopy and open circuit potential, while the corrosion rate was evaluated using potentiodynamic sweep measurements. Surface morphologies of the graphene coatings were analyzed by scanning electron microscopy and energy dispersive spectroscopy. Obtained results indicate that Cu coated with graphene grown using chemical vapor deposition shows corrosion-inhibiting properties in 0.1 M NaCl. On the other hand, Al coated with a multilayer graphene film mechanically transferred from the Cu surface exhibits electrochemical characteristics similar to an Al oxi...de on bare Al. Better protective properties of graphene coating on Cu compared to the graphene coating on Al were observed, probably due to the breakage of Al oxide film, causing the corrosion of Al to proceed rapidly in the presence of chloride electrolyte.
Извор:
Carbon, 2014, 75, 335-344Издавач:
- Pergamon-Elsevier Science Ltd, Oxford
Финансирање / пројекти:
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education, Science and Technology [2013R1A1A2A10063466]
- Синтеза, развој технологија добијања и примена наноструктурних мултифункционалних материјала дефинисаних својстава (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45019)
DOI: 10.1016/j.carbon.2014.04.012
ISSN: 0008-6223
WoS: 000336877600035
Scopus: 2-s2.0-84900792514
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Mišković-Stanković, Vesna AU - Jevremović, Ivana AU - Jung, Inhwa AU - Rhee, Kyong Yop PY - 2014 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2824 AB - Electrochemical characteristics and corrosion behavior of graphene coatings on Cu and Al in a 0.1 M NaCl solution were investigated. The graphene coatings were deposited on a Cu surface by chemical vapor deposition. Multiple graphene layers were then mechanically transferred from the growth substrate, Cu, onto Al surface by a transfer technique. The corrosion stability of graphene coatings was determined by electrochemical impedance spectroscopy and open circuit potential, while the corrosion rate was evaluated using potentiodynamic sweep measurements. Surface morphologies of the graphene coatings were analyzed by scanning electron microscopy and energy dispersive spectroscopy. Obtained results indicate that Cu coated with graphene grown using chemical vapor deposition shows corrosion-inhibiting properties in 0.1 M NaCl. On the other hand, Al coated with a multilayer graphene film mechanically transferred from the Cu surface exhibits electrochemical characteristics similar to an Al oxide on bare Al. Better protective properties of graphene coating on Cu compared to the graphene coating on Al were observed, probably due to the breakage of Al oxide film, causing the corrosion of Al to proceed rapidly in the presence of chloride electrolyte. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Carbon T1 - Electrochemical study of corrosion behavior of graphene coatings on copper and aluminum in a chloride solution EP - 344 SP - 335 VL - 75 DO - 10.1016/j.carbon.2014.04.012 ER -
@article{ author = "Mišković-Stanković, Vesna and Jevremović, Ivana and Jung, Inhwa and Rhee, Kyong Yop", year = "2014", abstract = "Electrochemical characteristics and corrosion behavior of graphene coatings on Cu and Al in a 0.1 M NaCl solution were investigated. The graphene coatings were deposited on a Cu surface by chemical vapor deposition. Multiple graphene layers were then mechanically transferred from the growth substrate, Cu, onto Al surface by a transfer technique. The corrosion stability of graphene coatings was determined by electrochemical impedance spectroscopy and open circuit potential, while the corrosion rate was evaluated using potentiodynamic sweep measurements. Surface morphologies of the graphene coatings were analyzed by scanning electron microscopy and energy dispersive spectroscopy. Obtained results indicate that Cu coated with graphene grown using chemical vapor deposition shows corrosion-inhibiting properties in 0.1 M NaCl. On the other hand, Al coated with a multilayer graphene film mechanically transferred from the Cu surface exhibits electrochemical characteristics similar to an Al oxide on bare Al. Better protective properties of graphene coating on Cu compared to the graphene coating on Al were observed, probably due to the breakage of Al oxide film, causing the corrosion of Al to proceed rapidly in the presence of chloride electrolyte.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Carbon", title = "Electrochemical study of corrosion behavior of graphene coatings on copper and aluminum in a chloride solution", pages = "344-335", volume = "75", doi = "10.1016/j.carbon.2014.04.012" }
Mišković-Stanković, V., Jevremović, I., Jung, I.,& Rhee, K. Y.. (2014). Electrochemical study of corrosion behavior of graphene coatings on copper and aluminum in a chloride solution. in Carbon Pergamon-Elsevier Science Ltd, Oxford., 75, 335-344. https://doi.org/10.1016/j.carbon.2014.04.012
Mišković-Stanković V, Jevremović I, Jung I, Rhee KY. Electrochemical study of corrosion behavior of graphene coatings on copper and aluminum in a chloride solution. in Carbon. 2014;75:335-344. doi:10.1016/j.carbon.2014.04.012 .
Mišković-Stanković, Vesna, Jevremović, Ivana, Jung, Inhwa, Rhee, Kyong Yop, "Electrochemical study of corrosion behavior of graphene coatings on copper and aluminum in a chloride solution" in Carbon, 75 (2014):335-344, https://doi.org/10.1016/j.carbon.2014.04.012 . .