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Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate

Authorized Users Only
2014
Authors
Radovanović, Filip
Nastasović, Aleksandra
Tomković, Tanja
Vasiljević-Radović, Dana
Nešić, Aleksandra
Veličković, Sava
Onjia, Antonije
Article (Published version)
Metadata
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Abstract
Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked glycidyl methacrylate copolymer were prepared by a combination of a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. As the concentration of polymerizable monomers increased the original macrovoid structure was replaced by a hybrid morphology with microglobules typical of macroporous methacrylate adsorbers embedded within microporous structure with no significant effects on water permeability. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of Orange G solution at low transmembrane pressures was used to demonstrate suitability of these novel membranes for membrane adsorption.
Keywords:
Membrane formation / Photoirradiation / Membrane adsorber / Epoxide functionality / Amination
Source:
Reactive & Functional Polymers, 2014, 77, 1-10
Publisher:
  • Elsevier Science Bv, Amsterdam
Funding / projects:
  • Micro- Nanosystems and Sensors for Electric Power and Process Industry and Environmental Protection (RS-32008)
  • Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden (RS-43009)
  • Synthesis and characterization of novel functional polymers and polymeric nanocomposites (RS-172062)

DOI: 10.1016/j.reactfunctpolym.2014.01.007

ISSN: 1381-5148

WoS: 000334140000001

Scopus: 2-s2.0-84894573179
[ Google Scholar ]
12
11
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2836
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Radovanović, Filip
AU  - Nastasović, Aleksandra
AU  - Tomković, Tanja
AU  - Vasiljević-Radović, Dana
AU  - Nešić, Aleksandra
AU  - Veličković, Sava
AU  - Onjia, Antonije
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2836
AB  - Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked glycidyl methacrylate copolymer were prepared by a combination of a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. As the concentration of polymerizable monomers increased the original macrovoid structure was replaced by a hybrid morphology with microglobules typical of macroporous methacrylate adsorbers embedded within microporous structure with no significant effects on water permeability. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of Orange G solution at low transmembrane pressures was used to demonstrate suitability of these novel membranes for membrane adsorption.
PB  - Elsevier Science Bv, Amsterdam
T2  - Reactive & Functional Polymers
T1  - Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate
EP  - 10
SP  - 1
VL  - 77
DO  - 10.1016/j.reactfunctpolym.2014.01.007
UR  - conv_4399
ER  - 
@article{
author = "Radovanović, Filip and Nastasović, Aleksandra and Tomković, Tanja and Vasiljević-Radović, Dana and Nešić, Aleksandra and Veličković, Sava and Onjia, Antonije",
year = "2014",
abstract = "Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked glycidyl methacrylate copolymer were prepared by a combination of a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. As the concentration of polymerizable monomers increased the original macrovoid structure was replaced by a hybrid morphology with microglobules typical of macroporous methacrylate adsorbers embedded within microporous structure with no significant effects on water permeability. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of Orange G solution at low transmembrane pressures was used to demonstrate suitability of these novel membranes for membrane adsorption.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Reactive & Functional Polymers",
title = "Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate",
pages = "10-1",
volume = "77",
doi = "10.1016/j.reactfunctpolym.2014.01.007",
url = "conv_4399"
}
Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S.,& Onjia, A.. (2014). Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. in Reactive & Functional Polymers
Elsevier Science Bv, Amsterdam., 77, 1-10.
https://doi.org/10.1016/j.reactfunctpolym.2014.01.007
conv_4399
Radovanović F, Nastasović A, Tomković T, Vasiljević-Radović D, Nešić A, Veličković S, Onjia A. Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. in Reactive & Functional Polymers. 2014;77:1-10.
doi:10.1016/j.reactfunctpolym.2014.01.007
conv_4399 .
Radovanović, Filip, Nastasović, Aleksandra, Tomković, Tanja, Vasiljević-Radović, Dana, Nešić, Aleksandra, Veličković, Sava, Onjia, Antonije, "Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate" in Reactive & Functional Polymers, 77 (2014):1-10,
https://doi.org/10.1016/j.reactfunctpolym.2014.01.007 .,
conv_4399 .

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