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Application of raw peach shell particles for removal of methylene blue

Authorized Users Only
2015
Authors
Marković, Smilja
Stanković, Ana
Lopičić, Zorica
Lazarević, Slavica
Stojanović, Mirjana
Uskoković, Dragan
Article (Published version)
Metadata
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Abstract
A possibility to apply raw, powdered peach shells ( PS) as a biosorbent for water purification was studied. The PSs are locally available as a solid waste in a fruit juice factory; methylene blue (MB) was chosen as representative of common pollutants in textile industry wastewater. The phase composition of prepared particles was identified by XRD. The particle morphology was characterized by FE-SEM, while the size distribution was measured by a laser light-scattering particle size analyzer. The BET specific surface area was determined from N-2 adsorption/desorption experiments. The effect of operating parameters: the biosorbent amount (50-1000 mg/100 mL), contact time (10-180 min), solution pH (2-12) and initial concentration (10-100 ppm) on biosorption efficiency was examined. Optimal conditions for MB removal were found to be: the biosorbent amount of 400 mg/100 mL and pH 5.5. A high efficiency of MB removal was established after 180 min: 99% for [MB](i) = 10 ppm and 76% for [MB](i) ...= 100 ppm. Biosorption is well described by the Freundlich- and BET-type isotherms, implicating heterogeneous adsorption sites and interconnections between adsorbed molecules. The FTIR spectroscopy results indicate hydrogen bonding between the dye and the biomass. The obtained results shown that raw peach shell particles could be used as an efficient low-cost biosorbent for dye removal from water.

Keywords:
Biomass / Peach shells / Biosorption / Methylene blue
Source:
Journal of Environmental Chemical Engineering, 2015, 3, 2, 716-724
Publisher:
  • Elsevier Sci Ltd, Oxford
Funding / projects:
  • Molecular designing of nanoparticles with controlled morphological and physicochemical characteristics and functional materials based on them (RS-45004)
  • Development of technologies and products based on mineral raw materials and waste biomass for protection of natural resources for safe food production (RS-31003)

DOI: 10.1016/j.jece.2015.04.002

ISSN: 2213-2929

WoS: 000217986800014

Scopus: 2-s2.0-84929612870
[ Google Scholar ]
66
63
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2918
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Marković, Smilja
AU  - Stanković, Ana
AU  - Lopičić, Zorica
AU  - Lazarević, Slavica
AU  - Stojanović, Mirjana
AU  - Uskoković, Dragan
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2918
AB  - A possibility to apply raw, powdered peach shells ( PS) as a biosorbent for water purification was studied. The PSs are locally available as a solid waste in a fruit juice factory; methylene blue (MB) was chosen as representative of common pollutants in textile industry wastewater. The phase composition of prepared particles was identified by XRD. The particle morphology was characterized by FE-SEM, while the size distribution was measured by a laser light-scattering particle size analyzer. The BET specific surface area was determined from N-2 adsorption/desorption experiments. The effect of operating parameters: the biosorbent amount (50-1000 mg/100 mL), contact time (10-180 min), solution pH (2-12) and initial concentration (10-100 ppm) on biosorption efficiency was examined. Optimal conditions for MB removal were found to be: the biosorbent amount of 400 mg/100 mL and pH 5.5. A high efficiency of MB removal was established after 180 min: 99% for [MB](i) = 10 ppm and 76% for [MB](i) = 100 ppm. Biosorption is well described by the Freundlich- and BET-type isotherms, implicating heterogeneous adsorption sites and interconnections between adsorbed molecules. The FTIR spectroscopy results indicate hydrogen bonding between the dye and the biomass. The obtained results shown that raw peach shell particles could be used as an efficient low-cost biosorbent for dye removal from water.
PB  - Elsevier Sci Ltd, Oxford
T2  - Journal of Environmental Chemical Engineering
T1  - Application of raw peach shell particles for removal of methylene blue
EP  - 724
IS  - 2
SP  - 716
VL  - 3
DO  - 10.1016/j.jece.2015.04.002
UR  - conv_2407
ER  - 
@article{
author = "Marković, Smilja and Stanković, Ana and Lopičić, Zorica and Lazarević, Slavica and Stojanović, Mirjana and Uskoković, Dragan",
year = "2015",
abstract = "A possibility to apply raw, powdered peach shells ( PS) as a biosorbent for water purification was studied. The PSs are locally available as a solid waste in a fruit juice factory; methylene blue (MB) was chosen as representative of common pollutants in textile industry wastewater. The phase composition of prepared particles was identified by XRD. The particle morphology was characterized by FE-SEM, while the size distribution was measured by a laser light-scattering particle size analyzer. The BET specific surface area was determined from N-2 adsorption/desorption experiments. The effect of operating parameters: the biosorbent amount (50-1000 mg/100 mL), contact time (10-180 min), solution pH (2-12) and initial concentration (10-100 ppm) on biosorption efficiency was examined. Optimal conditions for MB removal were found to be: the biosorbent amount of 400 mg/100 mL and pH 5.5. A high efficiency of MB removal was established after 180 min: 99% for [MB](i) = 10 ppm and 76% for [MB](i) = 100 ppm. Biosorption is well described by the Freundlich- and BET-type isotherms, implicating heterogeneous adsorption sites and interconnections between adsorbed molecules. The FTIR spectroscopy results indicate hydrogen bonding between the dye and the biomass. The obtained results shown that raw peach shell particles could be used as an efficient low-cost biosorbent for dye removal from water.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Journal of Environmental Chemical Engineering",
title = "Application of raw peach shell particles for removal of methylene blue",
pages = "724-716",
number = "2",
volume = "3",
doi = "10.1016/j.jece.2015.04.002",
url = "conv_2407"
}
Marković, S., Stanković, A., Lopičić, Z., Lazarević, S., Stojanović, M.,& Uskoković, D.. (2015). Application of raw peach shell particles for removal of methylene blue. in Journal of Environmental Chemical Engineering
Elsevier Sci Ltd, Oxford., 3(2), 716-724.
https://doi.org/10.1016/j.jece.2015.04.002
conv_2407
Marković S, Stanković A, Lopičić Z, Lazarević S, Stojanović M, Uskoković D. Application of raw peach shell particles for removal of methylene blue. in Journal of Environmental Chemical Engineering. 2015;3(2):716-724.
doi:10.1016/j.jece.2015.04.002
conv_2407 .
Marković, Smilja, Stanković, Ana, Lopičić, Zorica, Lazarević, Slavica, Stojanović, Mirjana, Uskoković, Dragan, "Application of raw peach shell particles for removal of methylene blue" in Journal of Environmental Chemical Engineering, 3, no. 2 (2015):716-724,
https://doi.org/10.1016/j.jece.2015.04.002 .,
conv_2407 .

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