DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass
Само за регистроване кориснике
2015
Аутори
Živanović, Vladimir D.Tošić, Mihajlo B.
Grujić, Snežana
Matijašević, Srđan D.
Stojanović, Jovica
Nikolić, J. D.
Smiljanić, Sonja
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
In this study, the crystallization of 30Li(2)O center dot 15Nb(2)O(5)center dot 50SiO(2)center dot 5TiO(2) (mol%) glass was examined. The parent glass was prepared by the standard melt quenching method, and the investigations were performed under non-isothermal and isothermal conditions using the DTA, XRD, SEM and EDS methods. The results revealed primary crystallization of this glass and the dendritic morphology of crystal growth. Three crystalline phases were formed in the glass matrix during crystallization, whereby LiNbO3 was formed as the primary phase, followed by Li2Si2O5 and SiO2 as the secondary. The surface and volume mechanisms of crystallization occur. The condition that both the mechanisms were dominant was determined. In the case of volume crystallization, the characteristics of the nucleation process were examined. The kinetic parameters of crystallization under different mechanisms of crystallization were determined.
Кључне речи:
Glass / Crystallization / LiNbO3 / DTAИзвор:
Journal of Thermal Analysis and Calorimetry, 2015, 119, 3, 1653-1661Издавач:
- Springer, Dordrecht
Финансирање / пројекти:
- Развој стакала са контролисаним отпуштањем јона за примену у пољопривреди и медицини (RS-MESTD-Technological Development (TD or TR)-34001)
- Феномени и процеси синтезе нових стакластих и наноструктурних стакло-керамичких материјала (RS-MESTD-Basic Research (BR or ON)-172004)
DOI: 10.1007/s10973-015-4390-x
ISSN: 1388-6150
WoS: 000350225500014
Scopus: 2-s2.0-84925504135
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Živanović, Vladimir D. AU - Tošić, Mihajlo B. AU - Grujić, Snežana AU - Matijašević, Srđan D. AU - Stojanović, Jovica AU - Nikolić, J. D. AU - Smiljanić, Sonja PY - 2015 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3034 AB - In this study, the crystallization of 30Li(2)O center dot 15Nb(2)O(5)center dot 50SiO(2)center dot 5TiO(2) (mol%) glass was examined. The parent glass was prepared by the standard melt quenching method, and the investigations were performed under non-isothermal and isothermal conditions using the DTA, XRD, SEM and EDS methods. The results revealed primary crystallization of this glass and the dendritic morphology of crystal growth. Three crystalline phases were formed in the glass matrix during crystallization, whereby LiNbO3 was formed as the primary phase, followed by Li2Si2O5 and SiO2 as the secondary. The surface and volume mechanisms of crystallization occur. The condition that both the mechanisms were dominant was determined. In the case of volume crystallization, the characteristics of the nucleation process were examined. The kinetic parameters of crystallization under different mechanisms of crystallization were determined. PB - Springer, Dordrecht T2 - Journal of Thermal Analysis and Calorimetry T1 - DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass EP - 1661 IS - 3 SP - 1653 VL - 119 DO - 10.1007/s10973-015-4390-x ER -
@article{ author = "Živanović, Vladimir D. and Tošić, Mihajlo B. and Grujić, Snežana and Matijašević, Srđan D. and Stojanović, Jovica and Nikolić, J. D. and Smiljanić, Sonja", year = "2015", abstract = "In this study, the crystallization of 30Li(2)O center dot 15Nb(2)O(5)center dot 50SiO(2)center dot 5TiO(2) (mol%) glass was examined. The parent glass was prepared by the standard melt quenching method, and the investigations were performed under non-isothermal and isothermal conditions using the DTA, XRD, SEM and EDS methods. The results revealed primary crystallization of this glass and the dendritic morphology of crystal growth. Three crystalline phases were formed in the glass matrix during crystallization, whereby LiNbO3 was formed as the primary phase, followed by Li2Si2O5 and SiO2 as the secondary. The surface and volume mechanisms of crystallization occur. The condition that both the mechanisms were dominant was determined. In the case of volume crystallization, the characteristics of the nucleation process were examined. The kinetic parameters of crystallization under different mechanisms of crystallization were determined.", publisher = "Springer, Dordrecht", journal = "Journal of Thermal Analysis and Calorimetry", title = "DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass", pages = "1661-1653", number = "3", volume = "119", doi = "10.1007/s10973-015-4390-x" }
Živanović, V. D., Tošić, M. B., Grujić, S., Matijašević, S. D., Stojanović, J., Nikolić, J. D.,& Smiljanić, S.. (2015). DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass. in Journal of Thermal Analysis and Calorimetry Springer, Dordrecht., 119(3), 1653-1661. https://doi.org/10.1007/s10973-015-4390-x
Živanović VD, Tošić MB, Grujić S, Matijašević SD, Stojanović J, Nikolić JD, Smiljanić S. DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass. in Journal of Thermal Analysis and Calorimetry. 2015;119(3):1653-1661. doi:10.1007/s10973-015-4390-x .
Živanović, Vladimir D., Tošić, Mihajlo B., Grujić, Snežana, Matijašević, Srđan D., Stojanović, Jovica, Nikolić, J. D., Smiljanić, Sonja, "DTA study of the crystallization of Li2O-Nb2O5-SiO2-TiO2 glass" in Journal of Thermal Analysis and Calorimetry, 119, no. 3 (2015):1653-1661, https://doi.org/10.1007/s10973-015-4390-x . .