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Investigation of supramolecular architectures of bent-shaped pyridine derivatives: from a three-ring crystalline compound towards five-ring mesogens

Authorized Users Only
2016
Authors
Trišović, Nemanja
Antanasijević, Jelena
Rogan, Jelena
Poleti, Dejan
Toth-Katona, Tibor
Salamonczyk, Miroslaw
Jakli, Antal
Fodor-Csorba, Katatin
Article (Published version)
Metadata
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Abstract
In search of novel photoactive liquid crystals, we have synthesized a series of five-ring pyridine-based bent-core compounds bearing different substituents at the peripheral phenyl rings (CH3O, Cl and NO2). Their mesomorphic behaviour has been investigated by polarizing optical microscopy, differential scanning calorimetry and X-ray scattering, and then compared with the unsubstituted parent compound. The introduction of the methoxy groups at the peripheral phenyl rings of the bent core results in a nonmesomorphic compound, whereas the chloro- and nitro-substituted compounds form enantiotropic B1-like phases. Significant changes in the textures and transition temperatures of the mesophase have been observed under UV tight. The present investigation of the mesomorphic properties of the synthesized compounds, coupled with the analysis of the molecular packing of the related three-ring compounds, will help design self-organized molecules suitable for UV indicators.
Source:
New Journal of Chemistry, 2016, 40, 8, 6977-6985
Publisher:
  • Royal Soc Chemistry, Cambridge
Funding / projects:
  • EUEuropean Union (EU) [OTKA NN 110672]
  • NSFNational Science Foundation (NSF) [DMR-1307674]
  • Office of Science, Office of Basic Energy Sciences, of the U.S. Department of EnergyUnited States Department of Energy (DOE) [DE-AC02-05CH11231]
  • Study of the Synthesis, Structure and Activity of Natural and Synthetic Organic Compounds (RS-172013)
  • Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing (RS-45007)

DOI: 10.1039/c6nj01515h

ISSN: 1144-0546

WoS: 000381717500061

Scopus: 2-s2.0-84982757593
[ Google Scholar ]
2
2
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3243
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Trišović, Nemanja
AU  - Antanasijević, Jelena
AU  - Rogan, Jelena
AU  - Poleti, Dejan
AU  - Toth-Katona, Tibor
AU  - Salamonczyk, Miroslaw
AU  - Jakli, Antal
AU  - Fodor-Csorba, Katatin
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3243
AB  - In search of novel photoactive liquid crystals, we have synthesized a series of five-ring pyridine-based bent-core compounds bearing different substituents at the peripheral phenyl rings (CH3O, Cl and NO2). Their mesomorphic behaviour has been investigated by polarizing optical microscopy, differential scanning calorimetry and X-ray scattering, and then compared with the unsubstituted parent compound. The introduction of the methoxy groups at the peripheral phenyl rings of the bent core results in a nonmesomorphic compound, whereas the chloro- and nitro-substituted compounds form enantiotropic B1-like phases. Significant changes in the textures and transition temperatures of the mesophase have been observed under UV tight. The present investigation of the mesomorphic properties of the synthesized compounds, coupled with the analysis of the molecular packing of the related three-ring compounds, will help design self-organized molecules suitable for UV indicators.
PB  - Royal Soc Chemistry, Cambridge
T2  - New Journal of Chemistry
T1  - Investigation of supramolecular architectures of bent-shaped pyridine derivatives: from a three-ring crystalline compound towards five-ring mesogens
EP  - 6985
IS  - 8
SP  - 6977
VL  - 40
DO  - 10.1039/c6nj01515h
UR  - conv_5075
ER  - 
@article{
author = "Trišović, Nemanja and Antanasijević, Jelena and Rogan, Jelena and Poleti, Dejan and Toth-Katona, Tibor and Salamonczyk, Miroslaw and Jakli, Antal and Fodor-Csorba, Katatin",
year = "2016",
abstract = "In search of novel photoactive liquid crystals, we have synthesized a series of five-ring pyridine-based bent-core compounds bearing different substituents at the peripheral phenyl rings (CH3O, Cl and NO2). Their mesomorphic behaviour has been investigated by polarizing optical microscopy, differential scanning calorimetry and X-ray scattering, and then compared with the unsubstituted parent compound. The introduction of the methoxy groups at the peripheral phenyl rings of the bent core results in a nonmesomorphic compound, whereas the chloro- and nitro-substituted compounds form enantiotropic B1-like phases. Significant changes in the textures and transition temperatures of the mesophase have been observed under UV tight. The present investigation of the mesomorphic properties of the synthesized compounds, coupled with the analysis of the molecular packing of the related three-ring compounds, will help design self-organized molecules suitable for UV indicators.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "New Journal of Chemistry",
title = "Investigation of supramolecular architectures of bent-shaped pyridine derivatives: from a three-ring crystalline compound towards five-ring mesogens",
pages = "6985-6977",
number = "8",
volume = "40",
doi = "10.1039/c6nj01515h",
url = "conv_5075"
}
Trišović, N., Antanasijević, J., Rogan, J., Poleti, D., Toth-Katona, T., Salamonczyk, M., Jakli, A.,& Fodor-Csorba, K.. (2016). Investigation of supramolecular architectures of bent-shaped pyridine derivatives: from a three-ring crystalline compound towards five-ring mesogens. in New Journal of Chemistry
Royal Soc Chemistry, Cambridge., 40(8), 6977-6985.
https://doi.org/10.1039/c6nj01515h
conv_5075
Trišović N, Antanasijević J, Rogan J, Poleti D, Toth-Katona T, Salamonczyk M, Jakli A, Fodor-Csorba K. Investigation of supramolecular architectures of bent-shaped pyridine derivatives: from a three-ring crystalline compound towards five-ring mesogens. in New Journal of Chemistry. 2016;40(8):6977-6985.
doi:10.1039/c6nj01515h
conv_5075 .
Trišović, Nemanja, Antanasijević, Jelena, Rogan, Jelena, Poleti, Dejan, Toth-Katona, Tibor, Salamonczyk, Miroslaw, Jakli, Antal, Fodor-Csorba, Katatin, "Investigation of supramolecular architectures of bent-shaped pyridine derivatives: from a three-ring crystalline compound towards five-ring mesogens" in New Journal of Chemistry, 40, no. 8 (2016):6977-6985,
https://doi.org/10.1039/c6nj01515h .,
conv_5075 .

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