The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate
Alkoholiza 1,2,2-trimetilpropil-metilfluorofosfata
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate (soman) was examined with a series of alkoxides and in corresponding alcohols: methanol, ethanol, 1-propanol, 2-propanol, 2-methoxyethanol and 2-ethoxyethanol. Soman reacts with the used alkoxides in a second order reaction, first order in each reactant. The kinetics of the reaction between 1,2,2-trimethylpropyl-methylfluorophosphonate and ethanol in the presence of diethylenetriamine was also examined. A third order reaction rate constant was calculated, first order in each reactant. The activation energy, frequency factor and activation entropy were determined on the basis of the kinetic data. .
Ispitana je alkoholiza 1,2,2-trimetilpropil-metilfluorofosfonata (soman) sa nizom alkoksida u odgovarajućim alkoholima: metanol, etanol, 1-propanol, 2-propanol, 2-metoksietanol i 2-etoksietanol. Soman reaguje sa ispitivanim alkoksidima u reakciji drugog reda, prvog reda prema svakom reaktantu. Ispitana je i kinetika reakcije između 1,2,2-trimetilpropil-metilfluorofosfonata i dietilentriamina u etanolu. Reakcija je ukupno trećeg reda, prvog prema svakom reaktantu. Za ispitivane reakcije su izračunate: energije aktivacije, faktori frekvencije i entropije aktivacije. .
Кључне речи:
decontamination / alcoholysis / 1,2,2-trimethylpropyl-methylfluorophosphonate / soman / alkoxides and diethylenetriamineИзвор:
Journal of the Serbian Chemical Society, 2000, 65, 12, 857-866Издавач:
- Serbian Chemical Society, Belgrade
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Mićević, Mlađen L. AU - Petrović, Slobodan PY - 2000 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/337 AB - The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate (soman) was examined with a series of alkoxides and in corresponding alcohols: methanol, ethanol, 1-propanol, 2-propanol, 2-methoxyethanol and 2-ethoxyethanol. Soman reacts with the used alkoxides in a second order reaction, first order in each reactant. The kinetics of the reaction between 1,2,2-trimethylpropyl-methylfluorophosphonate and ethanol in the presence of diethylenetriamine was also examined. A third order reaction rate constant was calculated, first order in each reactant. The activation energy, frequency factor and activation entropy were determined on the basis of the kinetic data. . AB - Ispitana je alkoholiza 1,2,2-trimetilpropil-metilfluorofosfonata (soman) sa nizom alkoksida u odgovarajućim alkoholima: metanol, etanol, 1-propanol, 2-propanol, 2-metoksietanol i 2-etoksietanol. Soman reaguje sa ispitivanim alkoksidima u reakciji drugog reda, prvog reda prema svakom reaktantu. Ispitana je i kinetika reakcije između 1,2,2-trimetilpropil-metilfluorofosfonata i dietilentriamina u etanolu. Reakcija je ukupno trećeg reda, prvog prema svakom reaktantu. Za ispitivane reakcije su izračunate: energije aktivacije, faktori frekvencije i entropije aktivacije. . PB - Serbian Chemical Society, Belgrade T2 - Journal of the Serbian Chemical Society T1 - The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate T1 - Alkoholiza 1,2,2-trimetilpropil-metilfluorofosfata EP - 866 IS - 12 SP - 857 VL - 65 UR - https://hdl.handle.net/21.15107/rcub_technorep_337 ER -
@article{ author = "Mićević, Mlađen L. and Petrović, Slobodan", year = "2000", abstract = "The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate (soman) was examined with a series of alkoxides and in corresponding alcohols: methanol, ethanol, 1-propanol, 2-propanol, 2-methoxyethanol and 2-ethoxyethanol. Soman reacts with the used alkoxides in a second order reaction, first order in each reactant. The kinetics of the reaction between 1,2,2-trimethylpropyl-methylfluorophosphonate and ethanol in the presence of diethylenetriamine was also examined. A third order reaction rate constant was calculated, first order in each reactant. The activation energy, frequency factor and activation entropy were determined on the basis of the kinetic data. ., Ispitana je alkoholiza 1,2,2-trimetilpropil-metilfluorofosfonata (soman) sa nizom alkoksida u odgovarajućim alkoholima: metanol, etanol, 1-propanol, 2-propanol, 2-metoksietanol i 2-etoksietanol. Soman reaguje sa ispitivanim alkoksidima u reakciji drugog reda, prvog reda prema svakom reaktantu. Ispitana je i kinetika reakcije između 1,2,2-trimetilpropil-metilfluorofosfonata i dietilentriamina u etanolu. Reakcija je ukupno trećeg reda, prvog prema svakom reaktantu. Za ispitivane reakcije su izračunate: energije aktivacije, faktori frekvencije i entropije aktivacije. .", publisher = "Serbian Chemical Society, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate, Alkoholiza 1,2,2-trimetilpropil-metilfluorofosfata", pages = "866-857", number = "12", volume = "65", url = "https://hdl.handle.net/21.15107/rcub_technorep_337" }
Mićević, M. L.,& Petrović, S.. (2000). The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate. in Journal of the Serbian Chemical Society Serbian Chemical Society, Belgrade., 65(12), 857-866. https://hdl.handle.net/21.15107/rcub_technorep_337
Mićević ML, Petrović S. The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate. in Journal of the Serbian Chemical Society. 2000;65(12):857-866. https://hdl.handle.net/21.15107/rcub_technorep_337 .
Mićević, Mlađen L., Petrović, Slobodan, "The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate" in Journal of the Serbian Chemical Society, 65, no. 12 (2000):857-866, https://hdl.handle.net/21.15107/rcub_technorep_337 .