Viscoelastic properties of poly(e-caprolactone)/clay nanocomposites in solid and in melt state
Само за регистроване кориснике
2016
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Viscoelastic properties in solid and in melt state of poly(epsilon-caprolactone), PCL, nanocomposites with organomodified clays (Cloisite30B and Cloisite15A) are thoroughly investigated. Although WAXD is insensitive to the difference in the nanocomposites structure, the melt rheology reveals pronounced differences between the two series. Melt yield stress values, obtained from fittings by the Carreau-Yasuda model, are used as a measure of partial exfoliation of the clay. Temperature dependence of the shift factors, used for time-temperature superposition of the modulus curves, yields similar values of the flow activation energies for all the samples. Temperature dependences of the dynamic modulus and loss factor of solid nanocomposites were correlated to the structural differences deduced from the melt rheology. The increase in the storage modulus is compared to the theoretical predictions from the Hal-pin-Tsai model. The effective aspect ratio obtained from this comparison agrees reas...onably with the value estimated from the melt rheology.
Кључне речи:
biodegradable / clay / polyesters / viscoelasticity / viscosityИзвор:
Journal of Applied Polymer Science, 2016, 133, 3Издавач:
- Wiley, Hoboken
Финансирање / пројекти:
- Синтеза и карактеризација нових функционалних полимера и полимерних нанокомпозита (RS-MESTD-Basic Research (BR or ON)-172062)
DOI: 10.1002/app.42896
ISSN: 0021-8995
WoS: 000363676200024
Scopus: 2-s2.0-84945457925
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Nikolić, Marija AU - Mitrić, Miodrag AU - Dapčević, Aleksandra AU - Đonlagić, Jasna PY - 2016 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3399 AB - Viscoelastic properties in solid and in melt state of poly(epsilon-caprolactone), PCL, nanocomposites with organomodified clays (Cloisite30B and Cloisite15A) are thoroughly investigated. Although WAXD is insensitive to the difference in the nanocomposites structure, the melt rheology reveals pronounced differences between the two series. Melt yield stress values, obtained from fittings by the Carreau-Yasuda model, are used as a measure of partial exfoliation of the clay. Temperature dependence of the shift factors, used for time-temperature superposition of the modulus curves, yields similar values of the flow activation energies for all the samples. Temperature dependences of the dynamic modulus and loss factor of solid nanocomposites were correlated to the structural differences deduced from the melt rheology. The increase in the storage modulus is compared to the theoretical predictions from the Hal-pin-Tsai model. The effective aspect ratio obtained from this comparison agrees reasonably with the value estimated from the melt rheology. PB - Wiley, Hoboken T2 - Journal of Applied Polymer Science T1 - Viscoelastic properties of poly(e-caprolactone)/clay nanocomposites in solid and in melt state IS - 3 VL - 133 DO - 10.1002/app.42896 ER -
@article{ author = "Nikolić, Marija and Mitrić, Miodrag and Dapčević, Aleksandra and Đonlagić, Jasna", year = "2016", abstract = "Viscoelastic properties in solid and in melt state of poly(epsilon-caprolactone), PCL, nanocomposites with organomodified clays (Cloisite30B and Cloisite15A) are thoroughly investigated. Although WAXD is insensitive to the difference in the nanocomposites structure, the melt rheology reveals pronounced differences between the two series. Melt yield stress values, obtained from fittings by the Carreau-Yasuda model, are used as a measure of partial exfoliation of the clay. Temperature dependence of the shift factors, used for time-temperature superposition of the modulus curves, yields similar values of the flow activation energies for all the samples. Temperature dependences of the dynamic modulus and loss factor of solid nanocomposites were correlated to the structural differences deduced from the melt rheology. The increase in the storage modulus is compared to the theoretical predictions from the Hal-pin-Tsai model. The effective aspect ratio obtained from this comparison agrees reasonably with the value estimated from the melt rheology.", publisher = "Wiley, Hoboken", journal = "Journal of Applied Polymer Science", title = "Viscoelastic properties of poly(e-caprolactone)/clay nanocomposites in solid and in melt state", number = "3", volume = "133", doi = "10.1002/app.42896" }
Nikolić, M., Mitrić, M., Dapčević, A.,& Đonlagić, J.. (2016). Viscoelastic properties of poly(e-caprolactone)/clay nanocomposites in solid and in melt state. in Journal of Applied Polymer Science Wiley, Hoboken., 133(3). https://doi.org/10.1002/app.42896
Nikolić M, Mitrić M, Dapčević A, Đonlagić J. Viscoelastic properties of poly(e-caprolactone)/clay nanocomposites in solid and in melt state. in Journal of Applied Polymer Science. 2016;133(3). doi:10.1002/app.42896 .
Nikolić, Marija, Mitrić, Miodrag, Dapčević, Aleksandra, Đonlagić, Jasna, "Viscoelastic properties of poly(e-caprolactone)/clay nanocomposites in solid and in melt state" in Journal of Applied Polymer Science, 133, no. 3 (2016), https://doi.org/10.1002/app.42896 . .